Analysis of photocatalytic reactors employing the photonic efficiency and the removal efficiency parameters: degradation of radiation absorbing and nonabsorbing pollutants.

Autores: Sagawe, Gerd; Satuf, María Lucila; Brandi, Rodolfo Juan; Muschner, Jan P.; Federer, Christian; Alfano, Orlando Mario; Bockenhauer, Detlef; Cassano, Alberto Enrique
Año de publicación: 2010
Idioma: inglés
Tipo de recurso: artículo
Estado: versión publicada
Descripción: The photocatalytic degradation of radiation absorbing and nonabsorbing pollutants in slurry reactors is analyzed in terms of two performance parameters: the observed photonic efficiency (OPE) and the remoVal efficiency (RE) [Sagawe et al. Chem. Eng. Sci. 2003, 58, 2587]. The OPE proposal permits a simpe approach to analyze complex reacting systems. Conversely, to calculate the RE, the modeling of radiation absorption and scattering inside the reactors is necessary, which requires the determination of the optical properties of the catalyst and the modeling of the optical effects of the reactor walls. The degradation of dichloroacetic acid, phenol, and 4-nitrophenol was studied employing aeroxide TiO2 P25 from Evonik-Degussa in well-mixed batch reactors irradiated by UV lamps. 4-Nitrophenol has the particular characteristic to compete with titania for the absorption of photons in the employed wavelength range of irradiation. Two reaction kinetics proposals were considered to interpret experimental data: a ?photocatalytic? Langmuir-Hinshelwood model (the L-HPh model) and a ?photocatalytic? Langmuir-Hinshelwood linear model (the L-HPh/1 model). The good agreement observed between experimental results and model simulations confirms the usefulness of the proposed OPE approximation and the more accurate information provided by the RE performance parameter. The inclusion of 4-nitrophenol allowed inference of the situation that would be encountered when treating real samples contaminated with strong radiation absorbing compounds.
Fil: Sagawe, Gerd. Leibniz Universitat Hannover; Alemania
Fil: Satuf, María Lucila. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Brandi, Rodolfo Juan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Muschner, Jan P.. Leibniz Universitat Hannover; Alemania
Fil: Federer, Christian. Leibniz Universitat Hannover; Alemania
Fil: Alfano, Orlando Mario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Bockenhauer, Detlef. Leibniz Universitat Hannover; Alemania
Fil: Cassano, Alberto Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Materia: Photocatalysis
Titanium dioxide
Dichloroacetic acid
Phenol
4-Nitrophenol
Reaction performance parameters
Nivel de accesibilidad: acceso abierto
Condiciones de uso: https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
Institución: Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador: oai:ri.conicet.gov.ar:11336/246211

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repository_id_str	3498
network_name_str	CONICET Digital (CONICET)
spelling	Analysis of photocatalytic reactors employing the photonic efficiency and the removal efficiency parameters: degradation of radiation absorbing and nonabsorbing pollutants.Sagawe, GerdSatuf, María LucilaBrandi, Rodolfo JuanMuschner, Jan P.Federer, ChristianAlfano, Orlando MarioBockenhauer, DetlefCassano, Alberto EnriquePhotocatalysisTitanium dioxideDichloroacetic acidPhenol4-NitrophenolReaction performance parametershttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The photocatalytic degradation of radiation absorbing and nonabsorbing pollutants in slurry reactors is analyzed in terms of two performance parameters: the observed photonic efficiency (OPE) and the remoVal efficiency (RE) [Sagawe et al. Chem. Eng. Sci. 2003, 58, 2587]. The OPE proposal permits a simpe approach to analyze complex reacting systems. Conversely, to calculate the RE, the modeling of radiation absorption and scattering inside the reactors is necessary, which requires the determination of the optical properties of the catalyst and the modeling of the optical effects of the reactor walls. The degradation of dichloroacetic acid, phenol, and 4-nitrophenol was studied employing aeroxide TiO2 P25 from Evonik-Degussa in well-mixed batch reactors irradiated by UV lamps. 4-Nitrophenol has the particular characteristic to compete with titania for the absorption of photons in the employed wavelength range of irradiation. Two reaction kinetics proposals were considered to interpret experimental data: a ?photocatalytic? Langmuir-Hinshelwood model (the L-HPh model) and a ?photocatalytic? Langmuir-Hinshelwood linear model (the L-HPh/1 model). The good agreement observed between experimental results and model simulations confirms the usefulness of the proposed OPE approximation and the more accurate information provided by the RE performance parameter. The inclusion of 4-nitrophenol allowed inference of the situation that would be encountered when treating real samples contaminated with strong radiation absorbing compounds.Fil: Sagawe, Gerd. Leibniz Universitat Hannover; AlemaniaFil: Satuf, María Lucila. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Brandi, Rodolfo Juan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Muschner, Jan P.. Leibniz Universitat Hannover; AlemaniaFil: Federer, Christian. Leibniz Universitat Hannover; AlemaniaFil: Alfano, Orlando Mario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Bockenhauer, Detlef. Leibniz Universitat Hannover; AlemaniaFil: Cassano, Alberto Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaAmerican Chemical Society2010-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/246211Sagawe, Gerd; Satuf, María Lucila; Brandi, Rodolfo Juan; Muschner, Jan P.; Federer, Christian; et al.; Analysis of photocatalytic reactors employing the photonic efficiency and the removal efficiency parameters: degradation of radiation absorbing and nonabsorbing pollutants.; American Chemical Society; Industrial & Engineering Chemical Research; 49; 15; 3-2010; 6898-69080888-5885CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ie901753kinfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/ie901753kinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:57:21Zoai:ri.conicet.gov.ar:11336/246211instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:57:21.635CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv	Analysis of photocatalytic reactors employing the photonic efficiency and the removal efficiency parameters: degradation of radiation absorbing and nonabsorbing pollutants.
title	Analysis of photocatalytic reactors employing the photonic efficiency and the removal efficiency parameters: degradation of radiation absorbing and nonabsorbing pollutants.
spellingShingle	Analysis of photocatalytic reactors employing the photonic efficiency and the removal efficiency parameters: degradation of radiation absorbing and nonabsorbing pollutants. Sagawe, Gerd Photocatalysis Titanium dioxide Dichloroacetic acid Phenol 4-Nitrophenol Reaction performance parameters
title_short	Analysis of photocatalytic reactors employing the photonic efficiency and the removal efficiency parameters: degradation of radiation absorbing and nonabsorbing pollutants.
title_full	Analysis of photocatalytic reactors employing the photonic efficiency and the removal efficiency parameters: degradation of radiation absorbing and nonabsorbing pollutants.
title_fullStr	Analysis of photocatalytic reactors employing the photonic efficiency and the removal efficiency parameters: degradation of radiation absorbing and nonabsorbing pollutants.
title_full_unstemmed	Analysis of photocatalytic reactors employing the photonic efficiency and the removal efficiency parameters: degradation of radiation absorbing and nonabsorbing pollutants.
title_sort	Analysis of photocatalytic reactors employing the photonic efficiency and the removal efficiency parameters: degradation of radiation absorbing and nonabsorbing pollutants.
dc.creator.none.fl_str_mv	Sagawe, Gerd Satuf, María Lucila Brandi, Rodolfo Juan Muschner, Jan P. Federer, Christian Alfano, Orlando Mario Bockenhauer, Detlef Cassano, Alberto Enrique
author	Sagawe, Gerd
author_facet	Sagawe, Gerd Satuf, María Lucila Brandi, Rodolfo Juan Muschner, Jan P. Federer, Christian Alfano, Orlando Mario Bockenhauer, Detlef Cassano, Alberto Enrique
author_role	author
author2	Satuf, María Lucila Brandi, Rodolfo Juan Muschner, Jan P. Federer, Christian Alfano, Orlando Mario Bockenhauer, Detlef Cassano, Alberto Enrique
author2_role	author author author author author author author
dc.subject.none.fl_str_mv	Photocatalysis Titanium dioxide Dichloroacetic acid Phenol 4-Nitrophenol Reaction performance parameters
topic	Photocatalysis Titanium dioxide Dichloroacetic acid Phenol 4-Nitrophenol Reaction performance parameters
purl_subject.fl_str_mv	https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv	The photocatalytic degradation of radiation absorbing and nonabsorbing pollutants in slurry reactors is analyzed in terms of two performance parameters: the observed photonic efficiency (OPE) and the remoVal efficiency (RE) [Sagawe et al. Chem. Eng. Sci. 2003, 58, 2587]. The OPE proposal permits a simpe approach to analyze complex reacting systems. Conversely, to calculate the RE, the modeling of radiation absorption and scattering inside the reactors is necessary, which requires the determination of the optical properties of the catalyst and the modeling of the optical effects of the reactor walls. The degradation of dichloroacetic acid, phenol, and 4-nitrophenol was studied employing aeroxide TiO2 P25 from Evonik-Degussa in well-mixed batch reactors irradiated by UV lamps. 4-Nitrophenol has the particular characteristic to compete with titania for the absorption of photons in the employed wavelength range of irradiation. Two reaction kinetics proposals were considered to interpret experimental data: a ?photocatalytic? Langmuir-Hinshelwood model (the L-HPh model) and a ?photocatalytic? Langmuir-Hinshelwood linear model (the L-HPh/1 model). The good agreement observed between experimental results and model simulations confirms the usefulness of the proposed OPE approximation and the more accurate information provided by the RE performance parameter. The inclusion of 4-nitrophenol allowed inference of the situation that would be encountered when treating real samples contaminated with strong radiation absorbing compounds. Fil: Sagawe, Gerd. Leibniz Universitat Hannover; Alemania Fil: Satuf, María Lucila. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina Fil: Brandi, Rodolfo Juan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina Fil: Muschner, Jan P.. Leibniz Universitat Hannover; Alemania Fil: Federer, Christian. Leibniz Universitat Hannover; Alemania Fil: Alfano, Orlando Mario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina Fil: Bockenhauer, Detlef. Leibniz Universitat Hannover; Alemania Fil: Cassano, Alberto Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
description	The photocatalytic degradation of radiation absorbing and nonabsorbing pollutants in slurry reactors is analyzed in terms of two performance parameters: the observed photonic efficiency (OPE) and the remoVal efficiency (RE) [Sagawe et al. Chem. Eng. Sci. 2003, 58, 2587]. The OPE proposal permits a simpe approach to analyze complex reacting systems. Conversely, to calculate the RE, the modeling of radiation absorption and scattering inside the reactors is necessary, which requires the determination of the optical properties of the catalyst and the modeling of the optical effects of the reactor walls. The degradation of dichloroacetic acid, phenol, and 4-nitrophenol was studied employing aeroxide TiO2 P25 from Evonik-Degussa in well-mixed batch reactors irradiated by UV lamps. 4-Nitrophenol has the particular characteristic to compete with titania for the absorption of photons in the employed wavelength range of irradiation. Two reaction kinetics proposals were considered to interpret experimental data: a ?photocatalytic? Langmuir-Hinshelwood model (the L-HPh model) and a ?photocatalytic? Langmuir-Hinshelwood linear model (the L-HPh/1 model). The good agreement observed between experimental results and model simulations confirms the usefulness of the proposed OPE approximation and the more accurate information provided by the RE performance parameter. The inclusion of 4-nitrophenol allowed inference of the situation that would be encountered when treating real samples contaminated with strong radiation absorbing compounds.
publishDate	2010
dc.date.none.fl_str_mv	2010-03
dc.type.none.fl_str_mv	info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo
format	article
status_str	publishedVersion
dc.identifier.none.fl_str_mv	http://hdl.handle.net/11336/246211 Sagawe, Gerd; Satuf, María Lucila; Brandi, Rodolfo Juan; Muschner, Jan P.; Federer, Christian; et al.; Analysis of photocatalytic reactors employing the photonic efficiency and the removal efficiency parameters: degradation of radiation absorbing and nonabsorbing pollutants.; American Chemical Society; Industrial & Engineering Chemical Research; 49; 15; 3-2010; 6898-6908 0888-5885 CONICET Digital CONICET
url	http://hdl.handle.net/11336/246211
identifier_str_mv	Sagawe, Gerd; Satuf, María Lucila; Brandi, Rodolfo Juan; Muschner, Jan P.; Federer, Christian; et al.; Analysis of photocatalytic reactors employing the photonic efficiency and the removal efficiency parameters: degradation of radiation absorbing and nonabsorbing pollutants.; American Chemical Society; Industrial & Engineering Chemical Research; 49; 15; 3-2010; 6898-6908 0888-5885 CONICET Digital CONICET
dc.language.none.fl_str_mv	eng
language	eng
dc.relation.none.fl_str_mv	info:eu-repo/semantics/altIdentifier/doi/10.1021/ie901753k info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/ie901753k
dc.rights.none.fl_str_mv	info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
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rights_invalid_str_mv	https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv	application/pdf application/pdf application/pdf application/pdf application/pdf
dc.publisher.none.fl_str_mv	American Chemical Society
publisher.none.fl_str_mv	American Chemical Society
dc.source.none.fl_str_mv	reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str	CONICET Digital (CONICET)
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instname_str	Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv	CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv	dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score	12.982451

Analysis of photocatalytic reactors employing the photonic efficiency and the removal efficiency parameters: degradation of radiation absorbing and nonabsorbing pollutants.

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