Magnetic composites of CoFe2O4 nanoparticles in a poly(aniline) matrix: Enhancement of remanence ratio and coercivity

Autores
Antonel, Paula Soledad; Berhó, F. M.; Jorge, Guillermo Antonio; Molina, Fernando Víctor
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Magnetic composites of cobalt ferrite nanoparticles and poly(aniline) have been synthesized in acid media and characterized by X-ray diffraction studies, scanning and transmission electron microscopy observation, thermogravimetric analysis, conductivity and infrared spectroscopy measurements. The magnetic behavior was studied through DC magnetization measurements; hysteresis loops were observed, showing ferromagnetic behavior for particles and composites. The remanence ratio increases as the polymer contents increases, the coercivity decreases first and then increases, and the saturation magnetization does not follow the ferrite mass fraction in the composite. It is proposed that an indirect exchange mechanism (RKKY-like) between the nanoparticles and PANI localized spins mediated by the conduction electrons is responsible for the observed magnetic behavior. The results suggest the presence of particle-matrix interactions related to the amount of polymer present, thus, in turn suggesting that the material magnetic properties could be controlled through the nanoparticles to polymer ratio.
Fil: Antonel, Paula Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Berhó, F. M.. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Jorge, Guillermo Antonio. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina
Fil: Molina, Fernando Víctor. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Materia
Magnetic Properties
Nanostructures
Oxides
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
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oai:ri.conicet.gov.ar:11336/38541
Acceder
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spelling Magnetic composites of CoFe2O4 nanoparticles in a poly(aniline) matrix: Enhancement of remanence ratio and coercivityAntonel, Paula SoledadBerhó, F. M.Jorge, Guillermo AntonioMolina, Fernando VíctorMagnetic PropertiesNanostructuresOxideshttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2Magnetic composites of cobalt ferrite nanoparticles and poly(aniline) have been synthesized in acid media and characterized by X-ray diffraction studies, scanning and transmission electron microscopy observation, thermogravimetric analysis, conductivity and infrared spectroscopy measurements. The magnetic behavior was studied through DC magnetization measurements; hysteresis loops were observed, showing ferromagnetic behavior for particles and composites. The remanence ratio increases as the polymer contents increases, the coercivity decreases first and then increases, and the saturation magnetization does not follow the ferrite mass fraction in the composite. It is proposed that an indirect exchange mechanism (RKKY-like) between the nanoparticles and PANI localized spins mediated by the conduction electrons is responsible for the observed magnetic behavior. The results suggest the presence of particle-matrix interactions related to the amount of polymer present, thus, in turn suggesting that the material magnetic properties could be controlled through the nanoparticles to polymer ratio.Fil: Antonel, Paula Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Berhó, F. M.. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Jorge, Guillermo Antonio. Universidad Nacional de General Sarmiento. Instituto de Ciencias; ArgentinaFil: Molina, Fernando Víctor. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaElsevier Science Sa2015-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/38541Antonel, Paula Soledad; Berhó, F. M.; Jorge, Guillermo Antonio; Molina, Fernando Víctor; Magnetic composites of CoFe2O4 nanoparticles in a poly(aniline) matrix: Enhancement of remanence ratio and coercivity; Elsevier Science Sa; Synthetic Metals; 199; 1-2015; 292-3020379-6779CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0379677914004378info:eu-repo/semantics/altIdentifier/doi/10.1016/j.synthmet.2014.12.003info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:06:14Zoai:ri.conicet.gov.ar:11336/38541instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:06:14.443CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Magnetic composites of CoFe2O4 nanoparticles in a poly(aniline) matrix: Enhancement of remanence ratio and coercivity
title Magnetic composites of CoFe2O4 nanoparticles in a poly(aniline) matrix: Enhancement of remanence ratio and coercivity
spellingShingle Magnetic composites of CoFe2O4 nanoparticles in a poly(aniline) matrix: Enhancement of remanence ratio and coercivity
Antonel, Paula Soledad
Magnetic Properties
Nanostructures
Oxides
title_short Magnetic composites of CoFe2O4 nanoparticles in a poly(aniline) matrix: Enhancement of remanence ratio and coercivity
title_full Magnetic composites of CoFe2O4 nanoparticles in a poly(aniline) matrix: Enhancement of remanence ratio and coercivity
title_fullStr Magnetic composites of CoFe2O4 nanoparticles in a poly(aniline) matrix: Enhancement of remanence ratio and coercivity
title_full_unstemmed Magnetic composites of CoFe2O4 nanoparticles in a poly(aniline) matrix: Enhancement of remanence ratio and coercivity
title_sort Magnetic composites of CoFe2O4 nanoparticles in a poly(aniline) matrix: Enhancement of remanence ratio and coercivity
dc.creator.none.fl_str_mv Antonel, Paula Soledad
Berhó, F. M.
Jorge, Guillermo Antonio
Molina, Fernando Víctor
author Antonel, Paula Soledad
author_facet Antonel, Paula Soledad
Berhó, F. M.
Jorge, Guillermo Antonio
Molina, Fernando Víctor
author_role author
author2 Berhó, F. M.
Jorge, Guillermo Antonio
Molina, Fernando Víctor
author2_role author
author
author
dc.subject.none.fl_str_mv Magnetic Properties
Nanostructures
Oxides
topic Magnetic Properties
Nanostructures
Oxides
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Magnetic composites of cobalt ferrite nanoparticles and poly(aniline) have been synthesized in acid media and characterized by X-ray diffraction studies, scanning and transmission electron microscopy observation, thermogravimetric analysis, conductivity and infrared spectroscopy measurements. The magnetic behavior was studied through DC magnetization measurements; hysteresis loops were observed, showing ferromagnetic behavior for particles and composites. The remanence ratio increases as the polymer contents increases, the coercivity decreases first and then increases, and the saturation magnetization does not follow the ferrite mass fraction in the composite. It is proposed that an indirect exchange mechanism (RKKY-like) between the nanoparticles and PANI localized spins mediated by the conduction electrons is responsible for the observed magnetic behavior. The results suggest the presence of particle-matrix interactions related to the amount of polymer present, thus, in turn suggesting that the material magnetic properties could be controlled through the nanoparticles to polymer ratio.
Fil: Antonel, Paula Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Berhó, F. M.. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Jorge, Guillermo Antonio. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina
Fil: Molina, Fernando Víctor. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
description Magnetic composites of cobalt ferrite nanoparticles and poly(aniline) have been synthesized in acid media and characterized by X-ray diffraction studies, scanning and transmission electron microscopy observation, thermogravimetric analysis, conductivity and infrared spectroscopy measurements. The magnetic behavior was studied through DC magnetization measurements; hysteresis loops were observed, showing ferromagnetic behavior for particles and composites. The remanence ratio increases as the polymer contents increases, the coercivity decreases first and then increases, and the saturation magnetization does not follow the ferrite mass fraction in the composite. It is proposed that an indirect exchange mechanism (RKKY-like) between the nanoparticles and PANI localized spins mediated by the conduction electrons is responsible for the observed magnetic behavior. The results suggest the presence of particle-matrix interactions related to the amount of polymer present, thus, in turn suggesting that the material magnetic properties could be controlled through the nanoparticles to polymer ratio.
publishDate 2015
dc.date.none.fl_str_mv 2015-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/38541
Antonel, Paula Soledad; Berhó, F. M.; Jorge, Guillermo Antonio; Molina, Fernando Víctor; Magnetic composites of CoFe2O4 nanoparticles in a poly(aniline) matrix: Enhancement of remanence ratio and coercivity; Elsevier Science Sa; Synthetic Metals; 199; 1-2015; 292-302
0379-6779
CONICET Digital
CONICET
url http://hdl.handle.net/11336/38541
identifier_str_mv Antonel, Paula Soledad; Berhó, F. M.; Jorge, Guillermo Antonio; Molina, Fernando Víctor; Magnetic composites of CoFe2O4 nanoparticles in a poly(aniline) matrix: Enhancement of remanence ratio and coercivity; Elsevier Science Sa; Synthetic Metals; 199; 1-2015; 292-302
0379-6779
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0379677914004378
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.synthmet.2014.12.003
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science Sa
publisher.none.fl_str_mv Elsevier Science Sa
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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