Solubility of CO2 in three cellulose-dissolving ionic liquids

Autores
Pérez, Eduardo; de Pablo, Laura; Segovia, J. Juan; Moreau, Alejandro; Sánchez, Francisco Adrián; Pereda, Selva; Bermejo, María Dolores
Año de publicación
2020
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The solubility of CO2 in three cellulose-dissolving ionic liquids (1-ethyl-3-methylimidazolium diethylphosphate, [Emim][DEP], 1-allyl-3-methylimidazolium chloride, [Amim][Cl], and 1-butyl-3-methylimidazolium chloride, [Bmim][Cl]) at temperatures within 298 and 356 K and pressures up to 6.5 MPa was determined using a Van Ness-type apparatus (static isochoric). It was demonstrated that this device can work in isothermal and isoplethal modes, being the latter faster and more precise. Moreover, it was possible to determine CO2 solubilities in metastable liquid [Bmim][Cl]. Experimental data were modeled using the Extended Henry's law correlation and the group contribution equation of state. New parameters for the binary interaction of CO2 with ionic liquid groups were calculated.
Fil: Pérez, Eduardo. Universidad de Valladolid; España
Fil: de Pablo, Laura. Universidad de Valladolid; España
Fil: Segovia, J. Juan. Universidad de Valladolid; España
Fil: Moreau, Alejandro. Universidad de Valladolid; España
Fil: Sánchez, Francisco Adrián. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
Fil: Pereda, Selva. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
Fil: Bermejo, María Dolores. Universidad de Valladolid; España
Materia
CO2 SOLUBILITY
EXTENDED HENRY'S LAW CORRELATION
GC-EOS
IMIDAZOLIUM-BASED IONIC LIQUIDS
STATIC ISOCHORIC CELL
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/126856
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/126856
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Solubility of CO2 in three cellulose-dissolving ionic liquidsPérez, Eduardode Pablo, LauraSegovia, J. JuanMoreau, AlejandroSánchez, Francisco AdriánPereda, SelvaBermejo, María DoloresCO2 SOLUBILITYEXTENDED HENRY'S LAW CORRELATIONGC-EOSIMIDAZOLIUM-BASED IONIC LIQUIDSSTATIC ISOCHORIC CELLhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The solubility of CO2 in three cellulose-dissolving ionic liquids (1-ethyl-3-methylimidazolium diethylphosphate, [Emim][DEP], 1-allyl-3-methylimidazolium chloride, [Amim][Cl], and 1-butyl-3-methylimidazolium chloride, [Bmim][Cl]) at temperatures within 298 and 356 K and pressures up to 6.5 MPa was determined using a Van Ness-type apparatus (static isochoric). It was demonstrated that this device can work in isothermal and isoplethal modes, being the latter faster and more precise. Moreover, it was possible to determine CO2 solubilities in metastable liquid [Bmim][Cl]. Experimental data were modeled using the Extended Henry's law correlation and the group contribution equation of state. New parameters for the binary interaction of CO2 with ionic liquid groups were calculated.Fil: Pérez, Eduardo. Universidad de Valladolid; EspañaFil: de Pablo, Laura. Universidad de Valladolid; EspañaFil: Segovia, J. Juan. Universidad de Valladolid; EspañaFil: Moreau, Alejandro. Universidad de Valladolid; EspañaFil: Sánchez, Francisco Adrián. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; ArgentinaFil: Pereda, Selva. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; ArgentinaFil: Bermejo, María Dolores. Universidad de Valladolid; EspañaJohn Wiley & Sons Inc2020-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/126856Pérez, Eduardo; de Pablo, Laura; Segovia, J. Juan; Moreau, Alejandro; Sánchez, Francisco Adrián; et al.; Solubility of CO2 in three cellulose-dissolving ionic liquids; John Wiley & Sons Inc; Aiche Journal; 66; 7; 7-2020; 1-43; e162280001-1541CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/aic.16228info:eu-repo/semantics/altIdentifier/doi/10.1002/aic.16228info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:45:52Zoai:ri.conicet.gov.ar:11336/126856instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:45:53.191CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Solubility of CO2 in three cellulose-dissolving ionic liquids
title Solubility of CO2 in three cellulose-dissolving ionic liquids
spellingShingle Solubility of CO2 in three cellulose-dissolving ionic liquids
Pérez, Eduardo
CO2 SOLUBILITY
EXTENDED HENRY'S LAW CORRELATION
GC-EOS
IMIDAZOLIUM-BASED IONIC LIQUIDS
STATIC ISOCHORIC CELL
title_short Solubility of CO2 in three cellulose-dissolving ionic liquids
title_full Solubility of CO2 in three cellulose-dissolving ionic liquids
title_fullStr Solubility of CO2 in three cellulose-dissolving ionic liquids
title_full_unstemmed Solubility of CO2 in three cellulose-dissolving ionic liquids
title_sort Solubility of CO2 in three cellulose-dissolving ionic liquids
dc.creator.none.fl_str_mv Pérez, Eduardo
de Pablo, Laura
Segovia, J. Juan
Moreau, Alejandro
Sánchez, Francisco Adrián
Pereda, Selva
Bermejo, María Dolores
author Pérez, Eduardo
author_facet Pérez, Eduardo
de Pablo, Laura
Segovia, J. Juan
Moreau, Alejandro
Sánchez, Francisco Adrián
Pereda, Selva
Bermejo, María Dolores
author_role author
author2 de Pablo, Laura
Segovia, J. Juan
Moreau, Alejandro
Sánchez, Francisco Adrián
Pereda, Selva
Bermejo, María Dolores
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv CO2 SOLUBILITY
EXTENDED HENRY'S LAW CORRELATION
GC-EOS
IMIDAZOLIUM-BASED IONIC LIQUIDS
STATIC ISOCHORIC CELL
topic CO2 SOLUBILITY
EXTENDED HENRY'S LAW CORRELATION
GC-EOS
IMIDAZOLIUM-BASED IONIC LIQUIDS
STATIC ISOCHORIC CELL
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The solubility of CO2 in three cellulose-dissolving ionic liquids (1-ethyl-3-methylimidazolium diethylphosphate, [Emim][DEP], 1-allyl-3-methylimidazolium chloride, [Amim][Cl], and 1-butyl-3-methylimidazolium chloride, [Bmim][Cl]) at temperatures within 298 and 356 K and pressures up to 6.5 MPa was determined using a Van Ness-type apparatus (static isochoric). It was demonstrated that this device can work in isothermal and isoplethal modes, being the latter faster and more precise. Moreover, it was possible to determine CO2 solubilities in metastable liquid [Bmim][Cl]. Experimental data were modeled using the Extended Henry's law correlation and the group contribution equation of state. New parameters for the binary interaction of CO2 with ionic liquid groups were calculated.
Fil: Pérez, Eduardo. Universidad de Valladolid; España
Fil: de Pablo, Laura. Universidad de Valladolid; España
Fil: Segovia, J. Juan. Universidad de Valladolid; España
Fil: Moreau, Alejandro. Universidad de Valladolid; España
Fil: Sánchez, Francisco Adrián. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
Fil: Pereda, Selva. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
Fil: Bermejo, María Dolores. Universidad de Valladolid; España
description The solubility of CO2 in three cellulose-dissolving ionic liquids (1-ethyl-3-methylimidazolium diethylphosphate, [Emim][DEP], 1-allyl-3-methylimidazolium chloride, [Amim][Cl], and 1-butyl-3-methylimidazolium chloride, [Bmim][Cl]) at temperatures within 298 and 356 K and pressures up to 6.5 MPa was determined using a Van Ness-type apparatus (static isochoric). It was demonstrated that this device can work in isothermal and isoplethal modes, being the latter faster and more precise. Moreover, it was possible to determine CO2 solubilities in metastable liquid [Bmim][Cl]. Experimental data were modeled using the Extended Henry's law correlation and the group contribution equation of state. New parameters for the binary interaction of CO2 with ionic liquid groups were calculated.
publishDate 2020
dc.date.none.fl_str_mv 2020-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/126856
Pérez, Eduardo; de Pablo, Laura; Segovia, J. Juan; Moreau, Alejandro; Sánchez, Francisco Adrián; et al.; Solubility of CO2 in three cellulose-dissolving ionic liquids; John Wiley & Sons Inc; Aiche Journal; 66; 7; 7-2020; 1-43; e16228
0001-1541
CONICET Digital
CONICET
url http://hdl.handle.net/11336/126856
identifier_str_mv Pérez, Eduardo; de Pablo, Laura; Segovia, J. Juan; Moreau, Alejandro; Sánchez, Francisco Adrián; et al.; Solubility of CO2 in three cellulose-dissolving ionic liquids; John Wiley & Sons Inc; Aiche Journal; 66; 7; 7-2020; 1-43; e16228
0001-1541
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/aic.16228
info:eu-repo/semantics/altIdentifier/doi/10.1002/aic.16228
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Inc
publisher.none.fl_str_mv John Wiley & Sons Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844614499319939072
score 13.070432

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