Mass transfer of cadmium ions in a hollow-fiber module by pertraction

Autores
Marchese, Jose; Campderrós, Mercedes Edith
Año de publicación
2004
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The facilitated transport of Cd(II) ions through a hollow-fiber-supported liquid membrane with bis-2-ethylhexyl phosphoric acid as carrier was studied. The mass transfer rate, expressed as permeability P, was measured as a function of mean aqueous solution velocity and carrier concentration. Characteristic ion permeabilities of 10-26×10-7m/s were measured at feed velocities between 1×10-2-19×10-2 m/s at stripping velocities between 0.22×10-2-7×10-2 m/s with constant feed flow. The measured permeabilities were compared to generally accepted mass transfer correlations. The predicted permeabilities adequately fit the experimental data, indicating that the rate limiting step in the transport of the ion was the diffusion through both aqueous films, feed and stripping, whereas the organic resistance of the membrane was negligible. Furthermore, the proposed model allowed the prediction of the permeability of cadmium for different experimental conditions, which is useful to perform experiments to reduce metal levels in water or other effluents.
Fil: Marchese, Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; Argentina
Fil: Campderrós, Mercedes Edith. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; Argentina
Materia
BIS-2-ETHYL HEXYL PHOSPHORIC ACID
CADMIUM
COUPLED COUNTER TRANSPORT
HOLLOW FIBER
LIQUID MEMBRANE
MASS TRANSFER
MOBILE CARRIER
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/212073
Acceder
id CONICETDig_6eca25e07454605700373d05811f152b
oai_identifier_str oai:ri.conicet.gov.ar:11336/212073
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Mass transfer of cadmium ions in a hollow-fiber module by pertractionMarchese, JoseCampderrós, Mercedes EdithBIS-2-ETHYL HEXYL PHOSPHORIC ACIDCADMIUMCOUPLED COUNTER TRANSPORTHOLLOW FIBERLIQUID MEMBRANEMASS TRANSFERMOBILE CARRIERThe facilitated transport of Cd(II) ions through a hollow-fiber-supported liquid membrane with bis-2-ethylhexyl phosphoric acid as carrier was studied. The mass transfer rate, expressed as permeability P, was measured as a function of mean aqueous solution velocity and carrier concentration. Characteristic ion permeabilities of 10-26×10-7m/s were measured at feed velocities between 1×10-2-19×10-2 m/s at stripping velocities between 0.22×10-2-7×10-2 m/s with constant feed flow. The measured permeabilities were compared to generally accepted mass transfer correlations. The predicted permeabilities adequately fit the experimental data, indicating that the rate limiting step in the transport of the ion was the diffusion through both aqueous films, feed and stripping, whereas the organic resistance of the membrane was negligible. Furthermore, the proposed model allowed the prediction of the permeability of cadmium for different experimental conditions, which is useful to perform experiments to reduce metal levels in water or other effluents.Fil: Marchese, Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; ArgentinaFil: Campderrós, Mercedes Edith. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; ArgentinaElsevier Science2004-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/212073Marchese, Jose; Campderrós, Mercedes Edith; Mass transfer of cadmium ions in a hollow-fiber module by pertraction; Elsevier Science; Desalination; 164; 2; 4-2004; 141-1490011-9164CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0011916404001730info:eu-repo/semantics/altIdentifier/doi/10.1016/S0011-9164(04)00173-0info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:38:17Zoai:ri.conicet.gov.ar:11336/212073instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:38:18.022CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Mass transfer of cadmium ions in a hollow-fiber module by pertraction
title Mass transfer of cadmium ions in a hollow-fiber module by pertraction
spellingShingle Mass transfer of cadmium ions in a hollow-fiber module by pertraction
Marchese, Jose
BIS-2-ETHYL HEXYL PHOSPHORIC ACID
CADMIUM
COUPLED COUNTER TRANSPORT
HOLLOW FIBER
LIQUID MEMBRANE
MASS TRANSFER
MOBILE CARRIER
title_short Mass transfer of cadmium ions in a hollow-fiber module by pertraction
title_full Mass transfer of cadmium ions in a hollow-fiber module by pertraction
title_fullStr Mass transfer of cadmium ions in a hollow-fiber module by pertraction
title_full_unstemmed Mass transfer of cadmium ions in a hollow-fiber module by pertraction
title_sort Mass transfer of cadmium ions in a hollow-fiber module by pertraction
dc.creator.none.fl_str_mv Marchese, Jose
Campderrós, Mercedes Edith
author Marchese, Jose
author_facet Marchese, Jose
Campderrós, Mercedes Edith
author_role author
author2 Campderrós, Mercedes Edith
author2_role author
dc.subject.none.fl_str_mv BIS-2-ETHYL HEXYL PHOSPHORIC ACID
CADMIUM
COUPLED COUNTER TRANSPORT
HOLLOW FIBER
LIQUID MEMBRANE
MASS TRANSFER
MOBILE CARRIER
topic BIS-2-ETHYL HEXYL PHOSPHORIC ACID
CADMIUM
COUPLED COUNTER TRANSPORT
HOLLOW FIBER
LIQUID MEMBRANE
MASS TRANSFER
MOBILE CARRIER
dc.description.none.fl_txt_mv The facilitated transport of Cd(II) ions through a hollow-fiber-supported liquid membrane with bis-2-ethylhexyl phosphoric acid as carrier was studied. The mass transfer rate, expressed as permeability P, was measured as a function of mean aqueous solution velocity and carrier concentration. Characteristic ion permeabilities of 10-26×10-7m/s were measured at feed velocities between 1×10-2-19×10-2 m/s at stripping velocities between 0.22×10-2-7×10-2 m/s with constant feed flow. The measured permeabilities were compared to generally accepted mass transfer correlations. The predicted permeabilities adequately fit the experimental data, indicating that the rate limiting step in the transport of the ion was the diffusion through both aqueous films, feed and stripping, whereas the organic resistance of the membrane was negligible. Furthermore, the proposed model allowed the prediction of the permeability of cadmium for different experimental conditions, which is useful to perform experiments to reduce metal levels in water or other effluents.
Fil: Marchese, Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; Argentina
Fil: Campderrós, Mercedes Edith. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; Argentina
description The facilitated transport of Cd(II) ions through a hollow-fiber-supported liquid membrane with bis-2-ethylhexyl phosphoric acid as carrier was studied. The mass transfer rate, expressed as permeability P, was measured as a function of mean aqueous solution velocity and carrier concentration. Characteristic ion permeabilities of 10-26×10-7m/s were measured at feed velocities between 1×10-2-19×10-2 m/s at stripping velocities between 0.22×10-2-7×10-2 m/s with constant feed flow. The measured permeabilities were compared to generally accepted mass transfer correlations. The predicted permeabilities adequately fit the experimental data, indicating that the rate limiting step in the transport of the ion was the diffusion through both aqueous films, feed and stripping, whereas the organic resistance of the membrane was negligible. Furthermore, the proposed model allowed the prediction of the permeability of cadmium for different experimental conditions, which is useful to perform experiments to reduce metal levels in water or other effluents.
publishDate 2004
dc.date.none.fl_str_mv 2004-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/212073
Marchese, Jose; Campderrós, Mercedes Edith; Mass transfer of cadmium ions in a hollow-fiber module by pertraction; Elsevier Science; Desalination; 164; 2; 4-2004; 141-149
0011-9164
CONICET Digital
CONICET
url http://hdl.handle.net/11336/212073
identifier_str_mv Marchese, Jose; Campderrós, Mercedes Edith; Mass transfer of cadmium ions in a hollow-fiber module by pertraction; Elsevier Science; Desalination; 164; 2; 4-2004; 141-149
0011-9164
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0011916404001730
info:eu-repo/semantics/altIdentifier/doi/10.1016/S0011-9164(04)00173-0
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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