Coke from SARA fractions in VGO. Impact on Y zeolite acidity and physical properties

Autores
Fals Guerra, Jayson; García, Juan Rafael; Falco, Marisa Guadalupe; Sedran, Ulises Anselmo
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The impact of the composition of the various hydrocarbon fractions in a conventional VGO (saturated SF, aromatic AF and resin RF) and the whole VGO on the coke formed in their catalytic cracking was evaluated over two Y zeolites with different degree of mesoporosity. The parent zeolite was in its protonic form, Si/Al relationship of 30 and the modified sample was desilicated by alkaline treatment. The fractions were separated from the VGO by means of ASTM D2007-11 method. The catalytic conversion experiments were performed in a batch, fluidized bed laboratory Riser Simulator reactor at 500 °C in the 0.7–3.0 s reaction time range, with a zeolite mass of 0.2 g and a zeolite/reactant mass of 1. Independent of zeolite, fraction SF was the easiest to crack. In the case of the AF fraction, the modified zeolite, with the highest intracrystalline mesoporosity, was more active than the parent zeolite. Gasoline was always the main product, with selectivities from 60 to 70%. All the feedstocks produced more coke on the modified zeolite; however, in spite of the higher coke yields, this zeolite suffered a lower loss of total acidity. As expected, a negative change in both acidity and textural properties (specific surface area and pore volume) were observed as a consequence of the formation of coke. The reactivity of VGO over both zeolites differed from that of fraction SF, even though it was the major fraction (68%). This behavior could be the consequence of interactions between the various fractions composing VGO.
Fil: Fals Guerra, Jayson. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: García, Juan Rafael. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Falco, Marisa Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Materia
Catalyst Deactivation
Catalytic Cracking
Coke
Intracrystalline Mesoporosity
Sara Fractions
Y Zeolite
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/63489
Acceder
id CONICETDig_6e1561bd7ceb8be5c53ac9b4c773b2d9
oai_identifier_str oai:ri.conicet.gov.ar:11336/63489
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Coke from SARA fractions in VGO. Impact on Y zeolite acidity and physical propertiesFals Guerra, JaysonGarcía, Juan RafaelFalco, Marisa GuadalupeSedran, Ulises AnselmoCatalyst DeactivationCatalytic CrackingCokeIntracrystalline MesoporositySara FractionsY Zeolitehttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The impact of the composition of the various hydrocarbon fractions in a conventional VGO (saturated SF, aromatic AF and resin RF) and the whole VGO on the coke formed in their catalytic cracking was evaluated over two Y zeolites with different degree of mesoporosity. The parent zeolite was in its protonic form, Si/Al relationship of 30 and the modified sample was desilicated by alkaline treatment. The fractions were separated from the VGO by means of ASTM D2007-11 method. The catalytic conversion experiments were performed in a batch, fluidized bed laboratory Riser Simulator reactor at 500 °C in the 0.7–3.0 s reaction time range, with a zeolite mass of 0.2 g and a zeolite/reactant mass of 1. Independent of zeolite, fraction SF was the easiest to crack. In the case of the AF fraction, the modified zeolite, with the highest intracrystalline mesoporosity, was more active than the parent zeolite. Gasoline was always the main product, with selectivities from 60 to 70%. All the feedstocks produced more coke on the modified zeolite; however, in spite of the higher coke yields, this zeolite suffered a lower loss of total acidity. As expected, a negative change in both acidity and textural properties (specific surface area and pore volume) were observed as a consequence of the formation of coke. The reactivity of VGO over both zeolites differed from that of fraction SF, even though it was the major fraction (68%). This behavior could be the consequence of interactions between the various fractions composing VGO.Fil: Fals Guerra, Jayson. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: García, Juan Rafael. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Falco, Marisa Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaElsevier2018-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/63489Fals Guerra, Jayson; García, Juan Rafael; Falco, Marisa Guadalupe; Sedran, Ulises Anselmo; Coke from SARA fractions in VGO. Impact on Y zeolite acidity and physical properties; Elsevier; Fuel; 225; 8-2018; 26-340016-2361CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.fuel.2018.02.180info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:47:32Zoai:ri.conicet.gov.ar:11336/63489instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:47:32.963CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Coke from SARA fractions in VGO. Impact on Y zeolite acidity and physical properties
title Coke from SARA fractions in VGO. Impact on Y zeolite acidity and physical properties
spellingShingle Coke from SARA fractions in VGO. Impact on Y zeolite acidity and physical properties
Fals Guerra, Jayson
Catalyst Deactivation
Catalytic Cracking
Coke
Intracrystalline Mesoporosity
Sara Fractions
Y Zeolite
title_short Coke from SARA fractions in VGO. Impact on Y zeolite acidity and physical properties
title_full Coke from SARA fractions in VGO. Impact on Y zeolite acidity and physical properties
title_fullStr Coke from SARA fractions in VGO. Impact on Y zeolite acidity and physical properties
title_full_unstemmed Coke from SARA fractions in VGO. Impact on Y zeolite acidity and physical properties
title_sort Coke from SARA fractions in VGO. Impact on Y zeolite acidity and physical properties
dc.creator.none.fl_str_mv Fals Guerra, Jayson
García, Juan Rafael
Falco, Marisa Guadalupe
Sedran, Ulises Anselmo
author Fals Guerra, Jayson
author_facet Fals Guerra, Jayson
García, Juan Rafael
Falco, Marisa Guadalupe
Sedran, Ulises Anselmo
author_role author
author2 García, Juan Rafael
Falco, Marisa Guadalupe
Sedran, Ulises Anselmo
author2_role author
author
author
dc.subject.none.fl_str_mv Catalyst Deactivation
Catalytic Cracking
Coke
Intracrystalline Mesoporosity
Sara Fractions
Y Zeolite
topic Catalyst Deactivation
Catalytic Cracking
Coke
Intracrystalline Mesoporosity
Sara Fractions
Y Zeolite
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The impact of the composition of the various hydrocarbon fractions in a conventional VGO (saturated SF, aromatic AF and resin RF) and the whole VGO on the coke formed in their catalytic cracking was evaluated over two Y zeolites with different degree of mesoporosity. The parent zeolite was in its protonic form, Si/Al relationship of 30 and the modified sample was desilicated by alkaline treatment. The fractions were separated from the VGO by means of ASTM D2007-11 method. The catalytic conversion experiments were performed in a batch, fluidized bed laboratory Riser Simulator reactor at 500 °C in the 0.7–3.0 s reaction time range, with a zeolite mass of 0.2 g and a zeolite/reactant mass of 1. Independent of zeolite, fraction SF was the easiest to crack. In the case of the AF fraction, the modified zeolite, with the highest intracrystalline mesoporosity, was more active than the parent zeolite. Gasoline was always the main product, with selectivities from 60 to 70%. All the feedstocks produced more coke on the modified zeolite; however, in spite of the higher coke yields, this zeolite suffered a lower loss of total acidity. As expected, a negative change in both acidity and textural properties (specific surface area and pore volume) were observed as a consequence of the formation of coke. The reactivity of VGO over both zeolites differed from that of fraction SF, even though it was the major fraction (68%). This behavior could be the consequence of interactions between the various fractions composing VGO.
Fil: Fals Guerra, Jayson. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: García, Juan Rafael. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Falco, Marisa Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
description The impact of the composition of the various hydrocarbon fractions in a conventional VGO (saturated SF, aromatic AF and resin RF) and the whole VGO on the coke formed in their catalytic cracking was evaluated over two Y zeolites with different degree of mesoporosity. The parent zeolite was in its protonic form, Si/Al relationship of 30 and the modified sample was desilicated by alkaline treatment. The fractions were separated from the VGO by means of ASTM D2007-11 method. The catalytic conversion experiments were performed in a batch, fluidized bed laboratory Riser Simulator reactor at 500 °C in the 0.7–3.0 s reaction time range, with a zeolite mass of 0.2 g and a zeolite/reactant mass of 1. Independent of zeolite, fraction SF was the easiest to crack. In the case of the AF fraction, the modified zeolite, with the highest intracrystalline mesoporosity, was more active than the parent zeolite. Gasoline was always the main product, with selectivities from 60 to 70%. All the feedstocks produced more coke on the modified zeolite; however, in spite of the higher coke yields, this zeolite suffered a lower loss of total acidity. As expected, a negative change in both acidity and textural properties (specific surface area and pore volume) were observed as a consequence of the formation of coke. The reactivity of VGO over both zeolites differed from that of fraction SF, even though it was the major fraction (68%). This behavior could be the consequence of interactions between the various fractions composing VGO.
publishDate 2018
dc.date.none.fl_str_mv 2018-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/63489
Fals Guerra, Jayson; García, Juan Rafael; Falco, Marisa Guadalupe; Sedran, Ulises Anselmo; Coke from SARA fractions in VGO. Impact on Y zeolite acidity and physical properties; Elsevier; Fuel; 225; 8-2018; 26-34
0016-2361
CONICET Digital
CONICET
url http://hdl.handle.net/11336/63489
identifier_str_mv Fals Guerra, Jayson; García, Juan Rafael; Falco, Marisa Guadalupe; Sedran, Ulises Anselmo; Coke from SARA fractions in VGO. Impact on Y zeolite acidity and physical properties; Elsevier; Fuel; 225; 8-2018; 26-34
0016-2361
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.fuel.2018.02.180
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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