Electrocatalytic degradation of phenol on Pt- and Ru-doped Ti/SnO2-Sb anodes in an alkaline medium

Autores
Berenguer Rodríguez, José; Sieben, Juan Manuel; Quijada, C.; Morallón, E.
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work, the electrocatalytic performance of Ti/SnO2-Sb(13-x)-Pt-Ru(x) anodes (x = 0.0, 3.25 and 9.75 at.%) towards phenolate elimination has been analyzed and compared to those of conventional Ti/RuO2 and Ti/Co3O4 anodes, to evaluate their application for decontamination of concentrated alkaline phenolic wastewaters. The effects of the applied current density and the nature of the anode on the activity, kinetics and current efficiency for phenolate elimination, COD removal and benzoquinone by-product formation/degradation have been thoroughly examined. The Ti/SnO2-Sb-Pt anode exhibits the best electroactivity, fastest kinetics and highest current efficiency among the studied anodes, but poor electrochemical stability. The introduction of small amounts of Ru (3.25?9.75 at.%) brings about a slight loss of the electrocatalyticperformance, but it causes a remarkable increase in the stability of the electrode. In terms of energy consumption and stability, the Ti/SnO2-Sb(9.75)-Pt-Ru(3.25) electrode seems to be the most promising anode material for the electrochemical treatment of alkaline phenolic wastewaters. The increase in current density generally leads to significantly faster phenolate, benzoquinone and COD degradations, but with lower efficiency because of an increasing selectivity to water oxidation. A correction of the ideal kinetic model has been proposed to predict the oxidation of organics on non-active metal oxide anodes.
Fil: Berenguer Rodríguez, José. Universidad de Alicante; España
Fil: Sieben, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina
Fil: Quijada, C.. Universidad Politécnica de Valencia; España
Fil: Morallón, E.. Universidad de Alicante; España
Materia
Electrocatalysis
Electrochemical Treatment
Phenol Removal
Tin Dioxide Electrodes
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/48404
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/48404
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Electrocatalytic degradation of phenol on Pt- and Ru-doped Ti/SnO2-Sb anodes in an alkaline mediumBerenguer Rodríguez, JoséSieben, Juan ManuelQuijada, C.Morallón, E.ElectrocatalysisElectrochemical TreatmentPhenol RemovalTin Dioxide Electrodeshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In this work, the electrocatalytic performance of Ti/SnO2-Sb(13-x)-Pt-Ru(x) anodes (x = 0.0, 3.25 and 9.75 at.%) towards phenolate elimination has been analyzed and compared to those of conventional Ti/RuO2 and Ti/Co3O4 anodes, to evaluate their application for decontamination of concentrated alkaline phenolic wastewaters. The effects of the applied current density and the nature of the anode on the activity, kinetics and current efficiency for phenolate elimination, COD removal and benzoquinone by-product formation/degradation have been thoroughly examined. The Ti/SnO2-Sb-Pt anode exhibits the best electroactivity, fastest kinetics and highest current efficiency among the studied anodes, but poor electrochemical stability. The introduction of small amounts of Ru (3.25?9.75 at.%) brings about a slight loss of the electrocatalyticperformance, but it causes a remarkable increase in the stability of the electrode. In terms of energy consumption and stability, the Ti/SnO2-Sb(9.75)-Pt-Ru(3.25) electrode seems to be the most promising anode material for the electrochemical treatment of alkaline phenolic wastewaters. The increase in current density generally leads to significantly faster phenolate, benzoquinone and COD degradations, but with lower efficiency because of an increasing selectivity to water oxidation. A correction of the ideal kinetic model has been proposed to predict the oxidation of organics on non-active metal oxide anodes.Fil: Berenguer Rodríguez, José. Universidad de Alicante; EspañaFil: Sieben, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; ArgentinaFil: Quijada, C.. Universidad Politécnica de Valencia; EspañaFil: Morallón, E.. Universidad de Alicante; EspañaElsevier Science2016-12-15info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/48404Berenguer Rodríguez, José; Sieben, Juan Manuel; Quijada, C.; Morallón, E.; Electrocatalytic degradation of phenol on Pt- and Ru-doped Ti/SnO2-Sb anodes in an alkaline medium; Elsevier Science; Applied Catalysis B: Environmental; 199; 15-12-2016; 394-4040926-3373CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcatb.2016.06.038info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926337316304763info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T12:08:52Zoai:ri.conicet.gov.ar:11336/48404instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 12:08:52.489CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Electrocatalytic degradation of phenol on Pt- and Ru-doped Ti/SnO2-Sb anodes in an alkaline medium
title Electrocatalytic degradation of phenol on Pt- and Ru-doped Ti/SnO2-Sb anodes in an alkaline medium
spellingShingle Electrocatalytic degradation of phenol on Pt- and Ru-doped Ti/SnO2-Sb anodes in an alkaline medium
Berenguer Rodríguez, José
Electrocatalysis
Electrochemical Treatment
Phenol Removal
Tin Dioxide Electrodes
title_short Electrocatalytic degradation of phenol on Pt- and Ru-doped Ti/SnO2-Sb anodes in an alkaline medium
title_full Electrocatalytic degradation of phenol on Pt- and Ru-doped Ti/SnO2-Sb anodes in an alkaline medium
title_fullStr Electrocatalytic degradation of phenol on Pt- and Ru-doped Ti/SnO2-Sb anodes in an alkaline medium
title_full_unstemmed Electrocatalytic degradation of phenol on Pt- and Ru-doped Ti/SnO2-Sb anodes in an alkaline medium
title_sort Electrocatalytic degradation of phenol on Pt- and Ru-doped Ti/SnO2-Sb anodes in an alkaline medium
dc.creator.none.fl_str_mv Berenguer Rodríguez, José
Sieben, Juan Manuel
Quijada, C.
Morallón, E.
author Berenguer Rodríguez, José
author_facet Berenguer Rodríguez, José
Sieben, Juan Manuel
Quijada, C.
Morallón, E.
author_role author
author2 Sieben, Juan Manuel
Quijada, C.
Morallón, E.
author2_role author
author
author
dc.subject.none.fl_str_mv Electrocatalysis
Electrochemical Treatment
Phenol Removal
Tin Dioxide Electrodes
topic Electrocatalysis
Electrochemical Treatment
Phenol Removal
Tin Dioxide Electrodes
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In this work, the electrocatalytic performance of Ti/SnO2-Sb(13-x)-Pt-Ru(x) anodes (x = 0.0, 3.25 and 9.75 at.%) towards phenolate elimination has been analyzed and compared to those of conventional Ti/RuO2 and Ti/Co3O4 anodes, to evaluate their application for decontamination of concentrated alkaline phenolic wastewaters. The effects of the applied current density and the nature of the anode on the activity, kinetics and current efficiency for phenolate elimination, COD removal and benzoquinone by-product formation/degradation have been thoroughly examined. The Ti/SnO2-Sb-Pt anode exhibits the best electroactivity, fastest kinetics and highest current efficiency among the studied anodes, but poor electrochemical stability. The introduction of small amounts of Ru (3.25?9.75 at.%) brings about a slight loss of the electrocatalyticperformance, but it causes a remarkable increase in the stability of the electrode. In terms of energy consumption and stability, the Ti/SnO2-Sb(9.75)-Pt-Ru(3.25) electrode seems to be the most promising anode material for the electrochemical treatment of alkaline phenolic wastewaters. The increase in current density generally leads to significantly faster phenolate, benzoquinone and COD degradations, but with lower efficiency because of an increasing selectivity to water oxidation. A correction of the ideal kinetic model has been proposed to predict the oxidation of organics on non-active metal oxide anodes.
Fil: Berenguer Rodríguez, José. Universidad de Alicante; España
Fil: Sieben, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina
Fil: Quijada, C.. Universidad Politécnica de Valencia; España
Fil: Morallón, E.. Universidad de Alicante; España
description In this work, the electrocatalytic performance of Ti/SnO2-Sb(13-x)-Pt-Ru(x) anodes (x = 0.0, 3.25 and 9.75 at.%) towards phenolate elimination has been analyzed and compared to those of conventional Ti/RuO2 and Ti/Co3O4 anodes, to evaluate their application for decontamination of concentrated alkaline phenolic wastewaters. The effects of the applied current density and the nature of the anode on the activity, kinetics and current efficiency for phenolate elimination, COD removal and benzoquinone by-product formation/degradation have been thoroughly examined. The Ti/SnO2-Sb-Pt anode exhibits the best electroactivity, fastest kinetics and highest current efficiency among the studied anodes, but poor electrochemical stability. The introduction of small amounts of Ru (3.25?9.75 at.%) brings about a slight loss of the electrocatalyticperformance, but it causes a remarkable increase in the stability of the electrode. In terms of energy consumption and stability, the Ti/SnO2-Sb(9.75)-Pt-Ru(3.25) electrode seems to be the most promising anode material for the electrochemical treatment of alkaline phenolic wastewaters. The increase in current density generally leads to significantly faster phenolate, benzoquinone and COD degradations, but with lower efficiency because of an increasing selectivity to water oxidation. A correction of the ideal kinetic model has been proposed to predict the oxidation of organics on non-active metal oxide anodes.
publishDate 2016
dc.date.none.fl_str_mv 2016-12-15
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/48404
Berenguer Rodríguez, José; Sieben, Juan Manuel; Quijada, C.; Morallón, E.; Electrocatalytic degradation of phenol on Pt- and Ru-doped Ti/SnO2-Sb anodes in an alkaline medium; Elsevier Science; Applied Catalysis B: Environmental; 199; 15-12-2016; 394-404
0926-3373
CONICET Digital
CONICET
url http://hdl.handle.net/11336/48404
identifier_str_mv Berenguer Rodríguez, José; Sieben, Juan Manuel; Quijada, C.; Morallón, E.; Electrocatalytic degradation of phenol on Pt- and Ru-doped Ti/SnO2-Sb anodes in an alkaline medium; Elsevier Science; Applied Catalysis B: Environmental; 199; 15-12-2016; 394-404
0926-3373
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcatb.2016.06.038
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926337316304763
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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