Experimental evidence of the oxidation state through resonant Raman scattering

Autores
Valentinuzzi, Maria Cecilia; Sánchez, Héctor José; Pérez, C. A.; Leani, Juan Jose
Año de publicación
2008
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
When atoms are irradiated by x-ray photons different kinds of interactions take place: the photn can be absorbed by the photoelectric effect or can suffer a Rayleigh or Compton scattering. However, under resonant conditions other low probability interactions can occur. One of these interactions is the resonant Raman scattering (RRS) [1]. The x-ray resonant Raman scattering is an inelastic process which presents fundamental differences compared to other scattering interactions between x-rays and atoms; when the energy of the incident photon approaches from below to the absorption edge of the target elemet, a strong resonant behavior takes place contributing to the attenuation of x-rays in matter. According to the absorption-emission model the RRS process can be represented by three steps [2]: 1) the initial state consists of an incident photon with an energy below, for example, the K threshold 2) a hole is produced in the K shell and the excited electron is ejected to an unoccupied state; an electron from a higher shell fills the vacancy and a photon is emitted 3) the final state consists of a hole in a higher shell, a scattered photon and an excited electron in the continnum or in a bound excited state.
Fil: Valentinuzzi, Maria Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomia y Física. Grupo de Espectroscopia Atomica y Nuclear; Argentina
Fil: Sánchez, Héctor José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomia y Física. Grupo de Espectroscopia Atomica y Nuclear; Argentina
Fil: Pérez, C. A.. Laboratorio Nacional de Luz Sincrotron; Brasil
Fil: Leani, Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomia y Física. Grupo de Espectroscopia Atomica y Nuclear; Argentina
Materia
OXIDATION STATE
RESONANT RAMAN SCATTERING
RRS
RIXS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/241599

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network_name_str CONICET Digital (CONICET)
spelling Experimental evidence of the oxidation state through resonant Raman scatteringValentinuzzi, Maria CeciliaSánchez, Héctor JoséPérez, C. A.Leani, Juan JoseOXIDATION STATERESONANT RAMAN SCATTERINGRRSRIXShttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1When atoms are irradiated by x-ray photons different kinds of interactions take place: the photn can be absorbed by the photoelectric effect or can suffer a Rayleigh or Compton scattering. However, under resonant conditions other low probability interactions can occur. One of these interactions is the resonant Raman scattering (RRS) [1]. The x-ray resonant Raman scattering is an inelastic process which presents fundamental differences compared to other scattering interactions between x-rays and atoms; when the energy of the incident photon approaches from below to the absorption edge of the target elemet, a strong resonant behavior takes place contributing to the attenuation of x-rays in matter. According to the absorption-emission model the RRS process can be represented by three steps [2]: 1) the initial state consists of an incident photon with an energy below, for example, the K threshold 2) a hole is produced in the K shell and the excited electron is ejected to an unoccupied state; an electron from a higher shell fills the vacancy and a photon is emitted 3) the final state consists of a hole in a higher shell, a scattered photon and an excited electron in the continnum or in a bound excited state.Fil: Valentinuzzi, Maria Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomia y Física. Grupo de Espectroscopia Atomica y Nuclear; ArgentinaFil: Sánchez, Héctor José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomia y Física. Grupo de Espectroscopia Atomica y Nuclear; ArgentinaFil: Pérez, C. A.. Laboratorio Nacional de Luz Sincrotron; BrasilFil: Leani, Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomia y Física. Grupo de Espectroscopia Atomica y Nuclear; ArgentinaBrazilian Synchrotron Light Laboratory2008-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/241599Valentinuzzi, Maria Cecilia; Sánchez, Héctor José; Pérez, C. A.; Leani, Juan Jose; Experimental evidence of the oxidation state through resonant Raman scattering; Brazilian Synchrotron Light Laboratory; Activity Report; 2007; 6-2008; 1-21518-0204CONICET DigitalCONICETenginfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:43:25Zoai:ri.conicet.gov.ar:11336/241599instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:43:25.593CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Experimental evidence of the oxidation state through resonant Raman scattering
title Experimental evidence of the oxidation state through resonant Raman scattering
spellingShingle Experimental evidence of the oxidation state through resonant Raman scattering
Valentinuzzi, Maria Cecilia
OXIDATION STATE
RESONANT RAMAN SCATTERING
RRS
RIXS
title_short Experimental evidence of the oxidation state through resonant Raman scattering
title_full Experimental evidence of the oxidation state through resonant Raman scattering
title_fullStr Experimental evidence of the oxidation state through resonant Raman scattering
title_full_unstemmed Experimental evidence of the oxidation state through resonant Raman scattering
title_sort Experimental evidence of the oxidation state through resonant Raman scattering
dc.creator.none.fl_str_mv Valentinuzzi, Maria Cecilia
Sánchez, Héctor José
Pérez, C. A.
Leani, Juan Jose
author Valentinuzzi, Maria Cecilia
author_facet Valentinuzzi, Maria Cecilia
Sánchez, Héctor José
Pérez, C. A.
Leani, Juan Jose
author_role author
author2 Sánchez, Héctor José
Pérez, C. A.
Leani, Juan Jose
author2_role author
author
author
dc.subject.none.fl_str_mv OXIDATION STATE
RESONANT RAMAN SCATTERING
RRS
RIXS
topic OXIDATION STATE
RESONANT RAMAN SCATTERING
RRS
RIXS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv When atoms are irradiated by x-ray photons different kinds of interactions take place: the photn can be absorbed by the photoelectric effect or can suffer a Rayleigh or Compton scattering. However, under resonant conditions other low probability interactions can occur. One of these interactions is the resonant Raman scattering (RRS) [1]. The x-ray resonant Raman scattering is an inelastic process which presents fundamental differences compared to other scattering interactions between x-rays and atoms; when the energy of the incident photon approaches from below to the absorption edge of the target elemet, a strong resonant behavior takes place contributing to the attenuation of x-rays in matter. According to the absorption-emission model the RRS process can be represented by three steps [2]: 1) the initial state consists of an incident photon with an energy below, for example, the K threshold 2) a hole is produced in the K shell and the excited electron is ejected to an unoccupied state; an electron from a higher shell fills the vacancy and a photon is emitted 3) the final state consists of a hole in a higher shell, a scattered photon and an excited electron in the continnum or in a bound excited state.
Fil: Valentinuzzi, Maria Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomia y Física. Grupo de Espectroscopia Atomica y Nuclear; Argentina
Fil: Sánchez, Héctor José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomia y Física. Grupo de Espectroscopia Atomica y Nuclear; Argentina
Fil: Pérez, C. A.. Laboratorio Nacional de Luz Sincrotron; Brasil
Fil: Leani, Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomia y Física. Grupo de Espectroscopia Atomica y Nuclear; Argentina
description When atoms are irradiated by x-ray photons different kinds of interactions take place: the photn can be absorbed by the photoelectric effect or can suffer a Rayleigh or Compton scattering. However, under resonant conditions other low probability interactions can occur. One of these interactions is the resonant Raman scattering (RRS) [1]. The x-ray resonant Raman scattering is an inelastic process which presents fundamental differences compared to other scattering interactions between x-rays and atoms; when the energy of the incident photon approaches from below to the absorption edge of the target elemet, a strong resonant behavior takes place contributing to the attenuation of x-rays in matter. According to the absorption-emission model the RRS process can be represented by three steps [2]: 1) the initial state consists of an incident photon with an energy below, for example, the K threshold 2) a hole is produced in the K shell and the excited electron is ejected to an unoccupied state; an electron from a higher shell fills the vacancy and a photon is emitted 3) the final state consists of a hole in a higher shell, a scattered photon and an excited electron in the continnum or in a bound excited state.
publishDate 2008
dc.date.none.fl_str_mv 2008-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/241599
Valentinuzzi, Maria Cecilia; Sánchez, Héctor José; Pérez, C. A.; Leani, Juan Jose; Experimental evidence of the oxidation state through resonant Raman scattering; Brazilian Synchrotron Light Laboratory; Activity Report; 2007; 6-2008; 1-2
1518-0204
CONICET Digital
CONICET
url http://hdl.handle.net/11336/241599
identifier_str_mv Valentinuzzi, Maria Cecilia; Sánchez, Héctor José; Pérez, C. A.; Leani, Juan Jose; Experimental evidence of the oxidation state through resonant Raman scattering; Brazilian Synchrotron Light Laboratory; Activity Report; 2007; 6-2008; 1-2
1518-0204
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Brazilian Synchrotron Light Laboratory
publisher.none.fl_str_mv Brazilian Synchrotron Light Laboratory
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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