Experimental evidence of the oxidation state through resonant Raman scattering
- Autores
- Valentinuzzi, Maria Cecilia; Sánchez, Héctor José; Pérez, C. A.; Leani, Juan Jose
- Año de publicación
- 2008
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- When atoms are irradiated by x-ray photons different kinds of interactions take place: the photn can be absorbed by the photoelectric effect or can suffer a Rayleigh or Compton scattering. However, under resonant conditions other low probability interactions can occur. One of these interactions is the resonant Raman scattering (RRS) [1]. The x-ray resonant Raman scattering is an inelastic process which presents fundamental differences compared to other scattering interactions between x-rays and atoms; when the energy of the incident photon approaches from below to the absorption edge of the target elemet, a strong resonant behavior takes place contributing to the attenuation of x-rays in matter. According to the absorption-emission model the RRS process can be represented by three steps [2]: 1) the initial state consists of an incident photon with an energy below, for example, the K threshold 2) a hole is produced in the K shell and the excited electron is ejected to an unoccupied state; an electron from a higher shell fills the vacancy and a photon is emitted 3) the final state consists of a hole in a higher shell, a scattered photon and an excited electron in the continnum or in a bound excited state.
Fil: Valentinuzzi, Maria Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomia y Física. Grupo de Espectroscopia Atomica y Nuclear; Argentina
Fil: Sánchez, Héctor José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomia y Física. Grupo de Espectroscopia Atomica y Nuclear; Argentina
Fil: Pérez, C. A.. Laboratorio Nacional de Luz Sincrotron; Brasil
Fil: Leani, Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomia y Física. Grupo de Espectroscopia Atomica y Nuclear; Argentina - Materia
-
OXIDATION STATE
RESONANT RAMAN SCATTERING
RRS
RIXS - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/241599
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Experimental evidence of the oxidation state through resonant Raman scatteringValentinuzzi, Maria CeciliaSánchez, Héctor JoséPérez, C. A.Leani, Juan JoseOXIDATION STATERESONANT RAMAN SCATTERINGRRSRIXShttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1When atoms are irradiated by x-ray photons different kinds of interactions take place: the photn can be absorbed by the photoelectric effect or can suffer a Rayleigh or Compton scattering. However, under resonant conditions other low probability interactions can occur. One of these interactions is the resonant Raman scattering (RRS) [1]. The x-ray resonant Raman scattering is an inelastic process which presents fundamental differences compared to other scattering interactions between x-rays and atoms; when the energy of the incident photon approaches from below to the absorption edge of the target elemet, a strong resonant behavior takes place contributing to the attenuation of x-rays in matter. According to the absorption-emission model the RRS process can be represented by three steps [2]: 1) the initial state consists of an incident photon with an energy below, for example, the K threshold 2) a hole is produced in the K shell and the excited electron is ejected to an unoccupied state; an electron from a higher shell fills the vacancy and a photon is emitted 3) the final state consists of a hole in a higher shell, a scattered photon and an excited electron in the continnum or in a bound excited state.Fil: Valentinuzzi, Maria Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomia y Física. Grupo de Espectroscopia Atomica y Nuclear; ArgentinaFil: Sánchez, Héctor José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomia y Física. Grupo de Espectroscopia Atomica y Nuclear; ArgentinaFil: Pérez, C. A.. Laboratorio Nacional de Luz Sincrotron; BrasilFil: Leani, Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomia y Física. Grupo de Espectroscopia Atomica y Nuclear; ArgentinaBrazilian Synchrotron Light Laboratory2008-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/241599Valentinuzzi, Maria Cecilia; Sánchez, Héctor José; Pérez, C. A.; Leani, Juan Jose; Experimental evidence of the oxidation state through resonant Raman scattering; Brazilian Synchrotron Light Laboratory; Activity Report; 2007; 6-2008; 1-21518-0204CONICET DigitalCONICETenginfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:43:25Zoai:ri.conicet.gov.ar:11336/241599instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:43:25.593CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Experimental evidence of the oxidation state through resonant Raman scattering |
title |
Experimental evidence of the oxidation state through resonant Raman scattering |
spellingShingle |
Experimental evidence of the oxidation state through resonant Raman scattering Valentinuzzi, Maria Cecilia OXIDATION STATE RESONANT RAMAN SCATTERING RRS RIXS |
title_short |
Experimental evidence of the oxidation state through resonant Raman scattering |
title_full |
Experimental evidence of the oxidation state through resonant Raman scattering |
title_fullStr |
Experimental evidence of the oxidation state through resonant Raman scattering |
title_full_unstemmed |
Experimental evidence of the oxidation state through resonant Raman scattering |
title_sort |
Experimental evidence of the oxidation state through resonant Raman scattering |
dc.creator.none.fl_str_mv |
Valentinuzzi, Maria Cecilia Sánchez, Héctor José Pérez, C. A. Leani, Juan Jose |
author |
Valentinuzzi, Maria Cecilia |
author_facet |
Valentinuzzi, Maria Cecilia Sánchez, Héctor José Pérez, C. A. Leani, Juan Jose |
author_role |
author |
author2 |
Sánchez, Héctor José Pérez, C. A. Leani, Juan Jose |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
OXIDATION STATE RESONANT RAMAN SCATTERING RRS RIXS |
topic |
OXIDATION STATE RESONANT RAMAN SCATTERING RRS RIXS |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.3 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
When atoms are irradiated by x-ray photons different kinds of interactions take place: the photn can be absorbed by the photoelectric effect or can suffer a Rayleigh or Compton scattering. However, under resonant conditions other low probability interactions can occur. One of these interactions is the resonant Raman scattering (RRS) [1]. The x-ray resonant Raman scattering is an inelastic process which presents fundamental differences compared to other scattering interactions between x-rays and atoms; when the energy of the incident photon approaches from below to the absorption edge of the target elemet, a strong resonant behavior takes place contributing to the attenuation of x-rays in matter. According to the absorption-emission model the RRS process can be represented by three steps [2]: 1) the initial state consists of an incident photon with an energy below, for example, the K threshold 2) a hole is produced in the K shell and the excited electron is ejected to an unoccupied state; an electron from a higher shell fills the vacancy and a photon is emitted 3) the final state consists of a hole in a higher shell, a scattered photon and an excited electron in the continnum or in a bound excited state. Fil: Valentinuzzi, Maria Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomia y Física. Grupo de Espectroscopia Atomica y Nuclear; Argentina Fil: Sánchez, Héctor José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomia y Física. Grupo de Espectroscopia Atomica y Nuclear; Argentina Fil: Pérez, C. A.. Laboratorio Nacional de Luz Sincrotron; Brasil Fil: Leani, Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomia y Física. Grupo de Espectroscopia Atomica y Nuclear; Argentina |
description |
When atoms are irradiated by x-ray photons different kinds of interactions take place: the photn can be absorbed by the photoelectric effect or can suffer a Rayleigh or Compton scattering. However, under resonant conditions other low probability interactions can occur. One of these interactions is the resonant Raman scattering (RRS) [1]. The x-ray resonant Raman scattering is an inelastic process which presents fundamental differences compared to other scattering interactions between x-rays and atoms; when the energy of the incident photon approaches from below to the absorption edge of the target elemet, a strong resonant behavior takes place contributing to the attenuation of x-rays in matter. According to the absorption-emission model the RRS process can be represented by three steps [2]: 1) the initial state consists of an incident photon with an energy below, for example, the K threshold 2) a hole is produced in the K shell and the excited electron is ejected to an unoccupied state; an electron from a higher shell fills the vacancy and a photon is emitted 3) the final state consists of a hole in a higher shell, a scattered photon and an excited electron in the continnum or in a bound excited state. |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008-06 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/241599 Valentinuzzi, Maria Cecilia; Sánchez, Héctor José; Pérez, C. A.; Leani, Juan Jose; Experimental evidence of the oxidation state through resonant Raman scattering; Brazilian Synchrotron Light Laboratory; Activity Report; 2007; 6-2008; 1-2 1518-0204 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/241599 |
identifier_str_mv |
Valentinuzzi, Maria Cecilia; Sánchez, Héctor José; Pérez, C. A.; Leani, Juan Jose; Experimental evidence of the oxidation state through resonant Raman scattering; Brazilian Synchrotron Light Laboratory; Activity Report; 2007; 6-2008; 1-2 1518-0204 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Brazilian Synchrotron Light Laboratory |
publisher.none.fl_str_mv |
Brazilian Synchrotron Light Laboratory |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613366469885952 |
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13.070432 |