Determination of the degree of substitution of modified chitosan by cyclic voltammetry at water/dichloroethane interface
- Autores
- Aldana, Ana Agustina; Strumia, Miriam Cristina; Yudi, Lidia Mabel; Martinelli, Marisa; Juárez, Ana Valeria
- Año de publicación
- 2014
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The electrochemical behavior of the cationic polymer chitosan-gtmac (Ch-GTMAC), at the polarized water / 1,2-dichloroethane interface was studied. This polymer was obtained by nucleophilic reaction of chitosan (Ch) with glycidyltrimethylammonium chloride groups (GTMAC). The voltammetric response was found to be dependent on the concentration of the polymer, on pH of the aqueous phase, and on the nature of the organic electrolyte. The results suggest a weak adsorption of the polymer coupled to the transfer towards the organic phase. Desorption process is quasi-reversible, and there is not interaction between adsorbents. From the analysis of desorption charge, it was possible to determine the substitution degree of the polymer
Fil: Aldana, Ana Agustina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); Argentina
Fil: Strumia, Miriam Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); Argentina
Fil: Yudi, Lidia Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Investigaciones En Físicoquímica de Córdoba; Argentina
Fil: Martinelli, Marisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); Argentina
Fil: Juárez, Ana Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Investigaciones En Físicoquímica de Córdoba; Argentina - Materia
-
Liquid/Liquid Interfaces Liquid/Liquid Interfaces
Chitosanchitosan
Quaternized Chitosan Queternized Chitosan
Cationic Polyelectrolytes Cationic Polyelectrolites - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/13833
Ver los metadatos del registro completo
id |
CONICETDig_6719f52068910604b235f1cea9ba441f |
---|---|
oai_identifier_str |
oai:ri.conicet.gov.ar:11336/13833 |
network_acronym_str |
CONICETDig |
repository_id_str |
3498 |
network_name_str |
CONICET Digital (CONICET) |
spelling |
Determination of the degree of substitution of modified chitosan by cyclic voltammetry at water/dichloroethane interfaceAldana, Ana AgustinaStrumia, Miriam CristinaYudi, Lidia MabelMartinelli, MarisaJuárez, Ana ValeriaLiquid/Liquid Interfaces Liquid/Liquid InterfacesChitosanchitosanQuaternized Chitosan Queternized ChitosanCationic Polyelectrolytes Cationic Polyelectroliteshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The electrochemical behavior of the cationic polymer chitosan-gtmac (Ch-GTMAC), at the polarized water / 1,2-dichloroethane interface was studied. This polymer was obtained by nucleophilic reaction of chitosan (Ch) with glycidyltrimethylammonium chloride groups (GTMAC). The voltammetric response was found to be dependent on the concentration of the polymer, on pH of the aqueous phase, and on the nature of the organic electrolyte. The results suggest a weak adsorption of the polymer coupled to the transfer towards the organic phase. Desorption process is quasi-reversible, and there is not interaction between adsorbents. From the analysis of desorption charge, it was possible to determine the substitution degree of the polymerFil: Aldana, Ana Agustina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); ArgentinaFil: Strumia, Miriam Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); ArgentinaFil: Yudi, Lidia Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Investigaciones En Físicoquímica de Córdoba; ArgentinaFil: Martinelli, Marisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); ArgentinaFil: Juárez, Ana Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Investigaciones En Físicoquímica de Córdoba; ArgentinaElsevier2014-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/13833Aldana, Ana Agustina; Strumia, Miriam Cristina; Yudi, Lidia Mabel; Martinelli, Marisa; Juárez, Ana Valeria; Determination of the degree of substitution of modified chitosan by cyclic voltammetry at water/dichloroethane interface; Elsevier; Electrochimica Acta; 117; 12-2014; 534-5400013-4686enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0013468613023815info:eu-repo/semantics/altIdentifier/doi/10.1016/j.electacta.2013.11.146info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:00:38Zoai:ri.conicet.gov.ar:11336/13833instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:00:38.38CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Determination of the degree of substitution of modified chitosan by cyclic voltammetry at water/dichloroethane interface |
title |
Determination of the degree of substitution of modified chitosan by cyclic voltammetry at water/dichloroethane interface |
spellingShingle |
Determination of the degree of substitution of modified chitosan by cyclic voltammetry at water/dichloroethane interface Aldana, Ana Agustina Liquid/Liquid Interfaces Liquid/Liquid Interfaces Chitosanchitosan Quaternized Chitosan Queternized Chitosan Cationic Polyelectrolytes Cationic Polyelectrolites |
title_short |
Determination of the degree of substitution of modified chitosan by cyclic voltammetry at water/dichloroethane interface |
title_full |
Determination of the degree of substitution of modified chitosan by cyclic voltammetry at water/dichloroethane interface |
title_fullStr |
Determination of the degree of substitution of modified chitosan by cyclic voltammetry at water/dichloroethane interface |
title_full_unstemmed |
Determination of the degree of substitution of modified chitosan by cyclic voltammetry at water/dichloroethane interface |
title_sort |
Determination of the degree of substitution of modified chitosan by cyclic voltammetry at water/dichloroethane interface |
dc.creator.none.fl_str_mv |
Aldana, Ana Agustina Strumia, Miriam Cristina Yudi, Lidia Mabel Martinelli, Marisa Juárez, Ana Valeria |
author |
Aldana, Ana Agustina |
author_facet |
Aldana, Ana Agustina Strumia, Miriam Cristina Yudi, Lidia Mabel Martinelli, Marisa Juárez, Ana Valeria |
author_role |
author |
author2 |
Strumia, Miriam Cristina Yudi, Lidia Mabel Martinelli, Marisa Juárez, Ana Valeria |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
Liquid/Liquid Interfaces Liquid/Liquid Interfaces Chitosanchitosan Quaternized Chitosan Queternized Chitosan Cationic Polyelectrolytes Cationic Polyelectrolites |
topic |
Liquid/Liquid Interfaces Liquid/Liquid Interfaces Chitosanchitosan Quaternized Chitosan Queternized Chitosan Cationic Polyelectrolytes Cationic Polyelectrolites |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The electrochemical behavior of the cationic polymer chitosan-gtmac (Ch-GTMAC), at the polarized water / 1,2-dichloroethane interface was studied. This polymer was obtained by nucleophilic reaction of chitosan (Ch) with glycidyltrimethylammonium chloride groups (GTMAC). The voltammetric response was found to be dependent on the concentration of the polymer, on pH of the aqueous phase, and on the nature of the organic electrolyte. The results suggest a weak adsorption of the polymer coupled to the transfer towards the organic phase. Desorption process is quasi-reversible, and there is not interaction between adsorbents. From the analysis of desorption charge, it was possible to determine the substitution degree of the polymer Fil: Aldana, Ana Agustina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); Argentina Fil: Strumia, Miriam Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); Argentina Fil: Yudi, Lidia Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Investigaciones En Físicoquímica de Córdoba; Argentina Fil: Martinelli, Marisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); Argentina Fil: Juárez, Ana Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Investigaciones En Físicoquímica de Córdoba; Argentina |
description |
The electrochemical behavior of the cationic polymer chitosan-gtmac (Ch-GTMAC), at the polarized water / 1,2-dichloroethane interface was studied. This polymer was obtained by nucleophilic reaction of chitosan (Ch) with glycidyltrimethylammonium chloride groups (GTMAC). The voltammetric response was found to be dependent on the concentration of the polymer, on pH of the aqueous phase, and on the nature of the organic electrolyte. The results suggest a weak adsorption of the polymer coupled to the transfer towards the organic phase. Desorption process is quasi-reversible, and there is not interaction between adsorbents. From the analysis of desorption charge, it was possible to determine the substitution degree of the polymer |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/13833 Aldana, Ana Agustina; Strumia, Miriam Cristina; Yudi, Lidia Mabel; Martinelli, Marisa; Juárez, Ana Valeria; Determination of the degree of substitution of modified chitosan by cyclic voltammetry at water/dichloroethane interface; Elsevier; Electrochimica Acta; 117; 12-2014; 534-540 0013-4686 |
url |
http://hdl.handle.net/11336/13833 |
identifier_str_mv |
Aldana, Ana Agustina; Strumia, Miriam Cristina; Yudi, Lidia Mabel; Martinelli, Marisa; Juárez, Ana Valeria; Determination of the degree of substitution of modified chitosan by cyclic voltammetry at water/dichloroethane interface; Elsevier; Electrochimica Acta; 117; 12-2014; 534-540 0013-4686 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0013468613023815 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.electacta.2013.11.146 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1842269650286542848 |
score |
13.13397 |