Searching for suitable catalysts for a passive direct methanol fuel cell cathode

Autores
Asteazaran, Mariano; Cespedes, G.; Moreno, Mario Sergio Jesus; Bengió, Silvina; Castro Luna Berenguer, Ana Maria del Carmen
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Trimetallic PtMRu/C cathode catalysts with M = Co or Fe obtained by an impregnation procedure using ethylene glycol and NaBH4 as reducing agent, with suitable activity for the oxygen reduction reaction (ORR) and improved tolerance to methanol, have been physically characterized by HRTEM, EDS and XPS. The examined nanoparticles have a small particle size and are well spread on the carbon support. Pt is mainly found as Pt(0) and Co, Fe and Ru are mostly oxidized. To study their durability and performance for ORR and methanol tolerance over time, the catalysts were subjected to an electrochemical accelerated stress test (AST), consisting in cycling the potential 2000 times. Polarization curves for ORR with and without methanol were recorded. After the AST the trimetallic PtMRu/C catalysts are able to keep their performance for ORR in the presence of methanol.
Fil: Asteazaran, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Cespedes, G.. Universidad Tecnológica Nacional. Facultad Regional La Plata. Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales; Argentina
Fil: Moreno, Mario Sergio Jesus. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Bengió, Silvina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Castro Luna Berenguer, Ana Maria del Carmen. Universidad Tecnológica Nacional. Facultad Regional La Plata. Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Materia
Methanol Crossover
Methanol Tolerant Catalyst
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/50157
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Searching for suitable catalysts for a passive direct methanol fuel cell cathodeAsteazaran, MarianoCespedes, G.Moreno, Mario Sergio JesusBengió, SilvinaCastro Luna Berenguer, Ana Maria del CarmenMethanol CrossoverMethanol Tolerant Catalysthttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Trimetallic PtMRu/C cathode catalysts with M = Co or Fe obtained by an impregnation procedure using ethylene glycol and NaBH4 as reducing agent, with suitable activity for the oxygen reduction reaction (ORR) and improved tolerance to methanol, have been physically characterized by HRTEM, EDS and XPS. The examined nanoparticles have a small particle size and are well spread on the carbon support. Pt is mainly found as Pt(0) and Co, Fe and Ru are mostly oxidized. To study their durability and performance for ORR and methanol tolerance over time, the catalysts were subjected to an electrochemical accelerated stress test (AST), consisting in cycling the potential 2000 times. Polarization curves for ORR with and without methanol were recorded. After the AST the trimetallic PtMRu/C catalysts are able to keep their performance for ORR in the presence of methanol.Fil: Asteazaran, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Cespedes, G.. Universidad Tecnológica Nacional. Facultad Regional La Plata. Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales; ArgentinaFil: Moreno, Mario Sergio Jesus. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Bengió, Silvina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Castro Luna Berenguer, Ana Maria del Carmen. Universidad Tecnológica Nacional. Facultad Regional La Plata. Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaPergamon-Elsevier Science Ltd2015-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/50157Asteazaran, Mariano; Cespedes, G.; Moreno, Mario Sergio Jesus; Bengió, Silvina; Castro Luna Berenguer, Ana Maria del Carmen; Searching for suitable catalysts for a passive direct methanol fuel cell cathode; Pergamon-Elsevier Science Ltd; International Journal of Hydrogen Energy; 40; 12-2015; 14632-146390360-3199CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2015.05.134info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0360319915013476info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:41:04Zoai:ri.conicet.gov.ar:11336/50157instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:41:04.552CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Searching for suitable catalysts for a passive direct methanol fuel cell cathode
title Searching for suitable catalysts for a passive direct methanol fuel cell cathode
spellingShingle Searching for suitable catalysts for a passive direct methanol fuel cell cathode
Asteazaran, Mariano
Methanol Crossover
Methanol Tolerant Catalyst
title_short Searching for suitable catalysts for a passive direct methanol fuel cell cathode
title_full Searching for suitable catalysts for a passive direct methanol fuel cell cathode
title_fullStr Searching for suitable catalysts for a passive direct methanol fuel cell cathode
title_full_unstemmed Searching for suitable catalysts for a passive direct methanol fuel cell cathode
title_sort Searching for suitable catalysts for a passive direct methanol fuel cell cathode
dc.creator.none.fl_str_mv Asteazaran, Mariano
Cespedes, G.
Moreno, Mario Sergio Jesus
Bengió, Silvina
Castro Luna Berenguer, Ana Maria del Carmen
author Asteazaran, Mariano
author_facet Asteazaran, Mariano
Cespedes, G.
Moreno, Mario Sergio Jesus
Bengió, Silvina
Castro Luna Berenguer, Ana Maria del Carmen
author_role author
author2 Cespedes, G.
Moreno, Mario Sergio Jesus
Bengió, Silvina
Castro Luna Berenguer, Ana Maria del Carmen
author2_role author
author
author
author
dc.subject.none.fl_str_mv Methanol Crossover
Methanol Tolerant Catalyst
topic Methanol Crossover
Methanol Tolerant Catalyst
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Trimetallic PtMRu/C cathode catalysts with M = Co or Fe obtained by an impregnation procedure using ethylene glycol and NaBH4 as reducing agent, with suitable activity for the oxygen reduction reaction (ORR) and improved tolerance to methanol, have been physically characterized by HRTEM, EDS and XPS. The examined nanoparticles have a small particle size and are well spread on the carbon support. Pt is mainly found as Pt(0) and Co, Fe and Ru are mostly oxidized. To study their durability and performance for ORR and methanol tolerance over time, the catalysts were subjected to an electrochemical accelerated stress test (AST), consisting in cycling the potential 2000 times. Polarization curves for ORR with and without methanol were recorded. After the AST the trimetallic PtMRu/C catalysts are able to keep their performance for ORR in the presence of methanol.
Fil: Asteazaran, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Cespedes, G.. Universidad Tecnológica Nacional. Facultad Regional La Plata. Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales; Argentina
Fil: Moreno, Mario Sergio Jesus. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Bengió, Silvina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Castro Luna Berenguer, Ana Maria del Carmen. Universidad Tecnológica Nacional. Facultad Regional La Plata. Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
description Trimetallic PtMRu/C cathode catalysts with M = Co or Fe obtained by an impregnation procedure using ethylene glycol and NaBH4 as reducing agent, with suitable activity for the oxygen reduction reaction (ORR) and improved tolerance to methanol, have been physically characterized by HRTEM, EDS and XPS. The examined nanoparticles have a small particle size and are well spread on the carbon support. Pt is mainly found as Pt(0) and Co, Fe and Ru are mostly oxidized. To study their durability and performance for ORR and methanol tolerance over time, the catalysts were subjected to an electrochemical accelerated stress test (AST), consisting in cycling the potential 2000 times. Polarization curves for ORR with and without methanol were recorded. After the AST the trimetallic PtMRu/C catalysts are able to keep their performance for ORR in the presence of methanol.
publishDate 2015
dc.date.none.fl_str_mv 2015-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/50157
Asteazaran, Mariano; Cespedes, G.; Moreno, Mario Sergio Jesus; Bengió, Silvina; Castro Luna Berenguer, Ana Maria del Carmen; Searching for suitable catalysts for a passive direct methanol fuel cell cathode; Pergamon-Elsevier Science Ltd; International Journal of Hydrogen Energy; 40; 12-2015; 14632-14639
0360-3199
CONICET Digital
CONICET
url http://hdl.handle.net/11336/50157
identifier_str_mv Asteazaran, Mariano; Cespedes, G.; Moreno, Mario Sergio Jesus; Bengió, Silvina; Castro Luna Berenguer, Ana Maria del Carmen; Searching for suitable catalysts for a passive direct methanol fuel cell cathode; Pergamon-Elsevier Science Ltd; International Journal of Hydrogen Energy; 40; 12-2015; 14632-14639
0360-3199
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2015.05.134
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0360319915013476
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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