Oxidation of ethyl acetate on Fe-Mn oxides from nitrates deposited by impregnation on monoliths of AISI 304 stainless steel

Autores
Duran, Flavia Graciela del Carmen; Barbero, Bibiana Patricia; Cadus, Luis Eduardo
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The iron-manganese mixed monolithic catalysts were obtained by impregnation from nitrates as precursors. A monolithic support was studied with and without alumina as surface generator. The characterization consisted in XRD, SEM, Adherence test, SBET and TPR. The monolith was evaluated in the combustion of ethyl acetate. The preparation method was very satisfactory in terms of reproducibility and adherence of the deposited phase. The higher activity of IFeMnx with respect to Al3FeMnx may be attributed for the formation of the solid solution where the Fe is introduced to the bixbyite structure. However, the presence of defective MnOx species in monoliths without alumina which might help to improve their performance is observed.
Fil: Duran, Flavia Graciela del Carmen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Barbero, Bibiana Patricia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Cadus, Luis Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Materia
MONOLITHS
AISI 304
OXIDATION
ETHYL ACETATE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/66946
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Oxidation of ethyl acetate on Fe-Mn oxides from nitrates deposited by impregnation on monoliths of AISI 304 stainless steelDuran, Flavia Graciela del CarmenBarbero, Bibiana PatriciaCadus, Luis EduardoMONOLITHSAISI 304OXIDATIONETHYL ACETATEhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The iron-manganese mixed monolithic catalysts were obtained by impregnation from nitrates as precursors. A monolithic support was studied with and without alumina as surface generator. The characterization consisted in XRD, SEM, Adherence test, SBET and TPR. The monolith was evaluated in the combustion of ethyl acetate. The preparation method was very satisfactory in terms of reproducibility and adherence of the deposited phase. The higher activity of IFeMnx with respect to Al3FeMnx may be attributed for the formation of the solid solution where the Fe is introduced to the bixbyite structure. However, the presence of defective MnOx species in monoliths without alumina which might help to improve their performance is observed.Fil: Duran, Flavia Graciela del Carmen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Barbero, Bibiana Patricia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Cadus, Luis Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaSociedad Chilena de Química2017-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/66946Duran, Flavia Graciela del Carmen; Barbero, Bibiana Patricia; Cadus, Luis Eduardo; Oxidation of ethyl acetate on Fe-Mn oxides from nitrates deposited by impregnation on monoliths of AISI 304 stainless steel; Sociedad Chilena de Química; Journal of the Chilean Chemical Society; 62; 4; 12-2017; 3708-37150717-93240717-9707CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.4067/s0717-97072017000403708info:eu-repo/semantics/altIdentifier/url/https://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0717-97072017000403708&lng=en&nrm=iso&tlng=eninfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:11:22Zoai:ri.conicet.gov.ar:11336/66946instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:11:22.982CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Oxidation of ethyl acetate on Fe-Mn oxides from nitrates deposited by impregnation on monoliths of AISI 304 stainless steel
title Oxidation of ethyl acetate on Fe-Mn oxides from nitrates deposited by impregnation on monoliths of AISI 304 stainless steel
spellingShingle Oxidation of ethyl acetate on Fe-Mn oxides from nitrates deposited by impregnation on monoliths of AISI 304 stainless steel
Duran, Flavia Graciela del Carmen
MONOLITHS
AISI 304
OXIDATION
ETHYL ACETATE
title_short Oxidation of ethyl acetate on Fe-Mn oxides from nitrates deposited by impregnation on monoliths of AISI 304 stainless steel
title_full Oxidation of ethyl acetate on Fe-Mn oxides from nitrates deposited by impregnation on monoliths of AISI 304 stainless steel
title_fullStr Oxidation of ethyl acetate on Fe-Mn oxides from nitrates deposited by impregnation on monoliths of AISI 304 stainless steel
title_full_unstemmed Oxidation of ethyl acetate on Fe-Mn oxides from nitrates deposited by impregnation on monoliths of AISI 304 stainless steel
title_sort Oxidation of ethyl acetate on Fe-Mn oxides from nitrates deposited by impregnation on monoliths of AISI 304 stainless steel
dc.creator.none.fl_str_mv Duran, Flavia Graciela del Carmen
Barbero, Bibiana Patricia
Cadus, Luis Eduardo
author Duran, Flavia Graciela del Carmen
author_facet Duran, Flavia Graciela del Carmen
Barbero, Bibiana Patricia
Cadus, Luis Eduardo
author_role author
author2 Barbero, Bibiana Patricia
Cadus, Luis Eduardo
author2_role author
author
dc.subject.none.fl_str_mv MONOLITHS
AISI 304
OXIDATION
ETHYL ACETATE
topic MONOLITHS
AISI 304
OXIDATION
ETHYL ACETATE
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The iron-manganese mixed monolithic catalysts were obtained by impregnation from nitrates as precursors. A monolithic support was studied with and without alumina as surface generator. The characterization consisted in XRD, SEM, Adherence test, SBET and TPR. The monolith was evaluated in the combustion of ethyl acetate. The preparation method was very satisfactory in terms of reproducibility and adherence of the deposited phase. The higher activity of IFeMnx with respect to Al3FeMnx may be attributed for the formation of the solid solution where the Fe is introduced to the bixbyite structure. However, the presence of defective MnOx species in monoliths without alumina which might help to improve their performance is observed.
Fil: Duran, Flavia Graciela del Carmen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Barbero, Bibiana Patricia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Cadus, Luis Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
description The iron-manganese mixed monolithic catalysts were obtained by impregnation from nitrates as precursors. A monolithic support was studied with and without alumina as surface generator. The characterization consisted in XRD, SEM, Adherence test, SBET and TPR. The monolith was evaluated in the combustion of ethyl acetate. The preparation method was very satisfactory in terms of reproducibility and adherence of the deposited phase. The higher activity of IFeMnx with respect to Al3FeMnx may be attributed for the formation of the solid solution where the Fe is introduced to the bixbyite structure. However, the presence of defective MnOx species in monoliths without alumina which might help to improve their performance is observed.
publishDate 2017
dc.date.none.fl_str_mv 2017-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/66946
Duran, Flavia Graciela del Carmen; Barbero, Bibiana Patricia; Cadus, Luis Eduardo; Oxidation of ethyl acetate on Fe-Mn oxides from nitrates deposited by impregnation on monoliths of AISI 304 stainless steel; Sociedad Chilena de Química; Journal of the Chilean Chemical Society; 62; 4; 12-2017; 3708-3715
0717-9324
0717-9707
CONICET Digital
CONICET
url http://hdl.handle.net/11336/66946
identifier_str_mv Duran, Flavia Graciela del Carmen; Barbero, Bibiana Patricia; Cadus, Luis Eduardo; Oxidation of ethyl acetate on Fe-Mn oxides from nitrates deposited by impregnation on monoliths of AISI 304 stainless steel; Sociedad Chilena de Química; Journal of the Chilean Chemical Society; 62; 4; 12-2017; 3708-3715
0717-9324
0717-9707
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.4067/s0717-97072017000403708
info:eu-repo/semantics/altIdentifier/url/https://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0717-97072017000403708&lng=en&nrm=iso&tlng=en
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Sociedad Chilena de Química
publisher.none.fl_str_mv Sociedad Chilena de Química
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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