Why Silver Deposition is so Fast: Solving the Enigma of Metal Deposition

Autores
Pinto, Leandro M. C.; Spohr, Eckhard; Quaino, Paola Monica; Santos, Elizabeth del Carmen; Schmickler, Wolfgang
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A perfect match: Silver deposition is one of the fastest electrochemical reactions, even though the Ag+ ion loses more than 5 eV solvation energy in the process. This phenomenon, an example of the enigma of metal deposition, was investigated by a combination of MD simulations, DFT, and specially developed theory. At the surface, the Ag+ ion experiences a strong interaction with the sp band of silver, which catalyzes the reaction.
Fil: Pinto, Leandro M. C.. Universidade Estadual Paulista Julio de Mesquita Filho. Facultad de Filosofia E Ciencias-campus de Marilia; Brasil. Universitat Ulm; Alemania
Fil: Spohr, Eckhard. Universitat Duisburg - Essen; Alemania
Fil: Quaino, Paola Monica. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada E Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; Argentina
Fil: Santos, Elizabeth del Carmen. Universitat Ulm; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Física "Enrique Gaviola"; Argentina
Fil: Schmickler, Wolfgang. Institute Of Theoretical Chemistry; Alemania. Universitat Ulm; Alemania
Materia
Silver
Deposition
Electron Transfer
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/7613
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Why Silver Deposition is so Fast: Solving the Enigma of Metal DepositionPinto, Leandro M. C.Spohr, EckhardQuaino, Paola MonicaSantos, Elizabeth del CarmenSchmickler, WolfgangSilverDepositionElectron Transferhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A perfect match: Silver deposition is one of the fastest electrochemical reactions, even though the Ag+ ion loses more than 5 eV solvation energy in the process. This phenomenon, an example of the enigma of metal deposition, was investigated by a combination of MD simulations, DFT, and specially developed theory. At the surface, the Ag+ ion experiences a strong interaction with the sp band of silver, which catalyzes the reaction.Fil: Pinto, Leandro M. C.. Universidade Estadual Paulista Julio de Mesquita Filho. Facultad de Filosofia E Ciencias-campus de Marilia; Brasil. Universitat Ulm; AlemaniaFil: Spohr, Eckhard. Universitat Duisburg - Essen; AlemaniaFil: Quaino, Paola Monica. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada E Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; ArgentinaFil: Santos, Elizabeth del Carmen. Universitat Ulm; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Física "Enrique Gaviola"; ArgentinaFil: Schmickler, Wolfgang. Institute Of Theoretical Chemistry; Alemania. Universitat Ulm; AlemaniaWiley2013-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/7613Pinto, Leandro M. C.; Spohr, Eckhard; Quaino, Paola Monica; Santos, Elizabeth del Carmen; Schmickler, Wolfgang; Why Silver Deposition is so Fast: Solving the Enigma of Metal Deposition; Wiley; Angewandte Chemie International Edition; 52; 30; 6-2013; 7883–78851521-3773enginfo:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/anie.201301998/abstractinfo:eu-repo/semantics/altIdentifier/doi/10.1002/anie.201301998info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:19:38Zoai:ri.conicet.gov.ar:11336/7613instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:19:39.179CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Why Silver Deposition is so Fast: Solving the Enigma of Metal Deposition
title Why Silver Deposition is so Fast: Solving the Enigma of Metal Deposition
spellingShingle Why Silver Deposition is so Fast: Solving the Enigma of Metal Deposition
Pinto, Leandro M. C.
Silver
Deposition
Electron Transfer
title_short Why Silver Deposition is so Fast: Solving the Enigma of Metal Deposition
title_full Why Silver Deposition is so Fast: Solving the Enigma of Metal Deposition
title_fullStr Why Silver Deposition is so Fast: Solving the Enigma of Metal Deposition
title_full_unstemmed Why Silver Deposition is so Fast: Solving the Enigma of Metal Deposition
title_sort Why Silver Deposition is so Fast: Solving the Enigma of Metal Deposition
dc.creator.none.fl_str_mv Pinto, Leandro M. C.
Spohr, Eckhard
Quaino, Paola Monica
Santos, Elizabeth del Carmen
Schmickler, Wolfgang
author Pinto, Leandro M. C.
author_facet Pinto, Leandro M. C.
Spohr, Eckhard
Quaino, Paola Monica
Santos, Elizabeth del Carmen
Schmickler, Wolfgang
author_role author
author2 Spohr, Eckhard
Quaino, Paola Monica
Santos, Elizabeth del Carmen
Schmickler, Wolfgang
author2_role author
author
author
author
dc.subject.none.fl_str_mv Silver
Deposition
Electron Transfer
topic Silver
Deposition
Electron Transfer
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A perfect match: Silver deposition is one of the fastest electrochemical reactions, even though the Ag+ ion loses more than 5 eV solvation energy in the process. This phenomenon, an example of the enigma of metal deposition, was investigated by a combination of MD simulations, DFT, and specially developed theory. At the surface, the Ag+ ion experiences a strong interaction with the sp band of silver, which catalyzes the reaction.
Fil: Pinto, Leandro M. C.. Universidade Estadual Paulista Julio de Mesquita Filho. Facultad de Filosofia E Ciencias-campus de Marilia; Brasil. Universitat Ulm; Alemania
Fil: Spohr, Eckhard. Universitat Duisburg - Essen; Alemania
Fil: Quaino, Paola Monica. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada E Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; Argentina
Fil: Santos, Elizabeth del Carmen. Universitat Ulm; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Física "Enrique Gaviola"; Argentina
Fil: Schmickler, Wolfgang. Institute Of Theoretical Chemistry; Alemania. Universitat Ulm; Alemania
description A perfect match: Silver deposition is one of the fastest electrochemical reactions, even though the Ag+ ion loses more than 5 eV solvation energy in the process. This phenomenon, an example of the enigma of metal deposition, was investigated by a combination of MD simulations, DFT, and specially developed theory. At the surface, the Ag+ ion experiences a strong interaction with the sp band of silver, which catalyzes the reaction.
publishDate 2013
dc.date.none.fl_str_mv 2013-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/7613
Pinto, Leandro M. C.; Spohr, Eckhard; Quaino, Paola Monica; Santos, Elizabeth del Carmen; Schmickler, Wolfgang; Why Silver Deposition is so Fast: Solving the Enigma of Metal Deposition; Wiley; Angewandte Chemie International Edition; 52; 30; 6-2013; 7883–7885
1521-3773
url http://hdl.handle.net/11336/7613
identifier_str_mv Pinto, Leandro M. C.; Spohr, Eckhard; Quaino, Paola Monica; Santos, Elizabeth del Carmen; Schmickler, Wolfgang; Why Silver Deposition is so Fast: Solving the Enigma of Metal Deposition; Wiley; Angewandte Chemie International Edition; 52; 30; 6-2013; 7883–7885
1521-3773
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/anie.201301998/abstract
info:eu-repo/semantics/altIdentifier/doi/10.1002/anie.201301998
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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