Reactivity of Thiyl Radicals Generated from Thiomethoxide and Dimethyldisulfide in Microheterogeneous Media

Autores
Barata Vallejo, Sebastian; Yerien, Damián Emilio; Postigo, Jose Alberto
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Sodium thiomethoxide and dimethyldisulfide will be shown to beconvenient sources of methyl thiyl radicals for effecting thecis-trans double bond isomerization of oleic acid to elaidic acidresidues arranged in phospholipid bilayers of the microheterogeneousaqueous environment of liposomes. The methods used for methyl thiylradical generation encompass radiolytic and photochemical methods. Theconvenience of these methyl thiyl radical sources will be interpretedin terms of the turn-over numbers in the radical chain cis-transisomerization reaction of unsaturated lipids.
Fil: Barata Vallejo, Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica. Cátedra de Química Orgánica I; Argentina
Fil: Yerien, Damián Emilio. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica. Cátedra de Química Orgánica I; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Postigo, Jose Alberto. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica. Cátedra de Química Orgánica I; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
thiyl radicals
lipid isomerization
radiolysis
cis-trans isomerization
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/273469
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Reactivity of Thiyl Radicals Generated from Thiomethoxide and Dimethyldisulfide in Microheterogeneous MediaBarata Vallejo, SebastianYerien, Damián EmilioPostigo, Jose Albertothiyl radicalslipid isomerizationradiolysiscis-trans isomerizationhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Sodium thiomethoxide and dimethyldisulfide will be shown to beconvenient sources of methyl thiyl radicals for effecting thecis-trans double bond isomerization of oleic acid to elaidic acidresidues arranged in phospholipid bilayers of the microheterogeneousaqueous environment of liposomes. The methods used for methyl thiylradical generation encompass radiolytic and photochemical methods. Theconvenience of these methyl thiyl radical sources will be interpretedin terms of the turn-over numbers in the radical chain cis-transisomerization reaction of unsaturated lipids.Fil: Barata Vallejo, Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica. Cátedra de Química Orgánica I; ArgentinaFil: Yerien, Damián Emilio. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica. Cátedra de Química Orgánica I; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Postigo, Jose Alberto. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica. Cátedra de Química Orgánica I; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaBentham Science Publishers2012-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/273469Barata Vallejo, Sebastian; Yerien, Damián Emilio; Postigo, Jose Alberto; Reactivity of Thiyl Radicals Generated from Thiomethoxide and Dimethyldisulfide in Microheterogeneous Media; Bentham Science Publishers; Current Organic Chemistry; 16; 20; 10-2012; 2423-24291385-2728CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.2174/138527212803520065info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:37:11Zoai:ri.conicet.gov.ar:11336/273469instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:37:11.359CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Reactivity of Thiyl Radicals Generated from Thiomethoxide and Dimethyldisulfide in Microheterogeneous Media
title Reactivity of Thiyl Radicals Generated from Thiomethoxide and Dimethyldisulfide in Microheterogeneous Media
spellingShingle Reactivity of Thiyl Radicals Generated from Thiomethoxide and Dimethyldisulfide in Microheterogeneous Media
Barata Vallejo, Sebastian
thiyl radicals
lipid isomerization
radiolysis
cis-trans isomerization
title_short Reactivity of Thiyl Radicals Generated from Thiomethoxide and Dimethyldisulfide in Microheterogeneous Media
title_full Reactivity of Thiyl Radicals Generated from Thiomethoxide and Dimethyldisulfide in Microheterogeneous Media
title_fullStr Reactivity of Thiyl Radicals Generated from Thiomethoxide and Dimethyldisulfide in Microheterogeneous Media
title_full_unstemmed Reactivity of Thiyl Radicals Generated from Thiomethoxide and Dimethyldisulfide in Microheterogeneous Media
title_sort Reactivity of Thiyl Radicals Generated from Thiomethoxide and Dimethyldisulfide in Microheterogeneous Media
dc.creator.none.fl_str_mv Barata Vallejo, Sebastian
Yerien, Damián Emilio
Postigo, Jose Alberto
author Barata Vallejo, Sebastian
author_facet Barata Vallejo, Sebastian
Yerien, Damián Emilio
Postigo, Jose Alberto
author_role author
author2 Yerien, Damián Emilio
Postigo, Jose Alberto
author2_role author
author
dc.subject.none.fl_str_mv thiyl radicals
lipid isomerization
radiolysis
cis-trans isomerization
topic thiyl radicals
lipid isomerization
radiolysis
cis-trans isomerization
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Sodium thiomethoxide and dimethyldisulfide will be shown to beconvenient sources of methyl thiyl radicals for effecting thecis-trans double bond isomerization of oleic acid to elaidic acidresidues arranged in phospholipid bilayers of the microheterogeneousaqueous environment of liposomes. The methods used for methyl thiylradical generation encompass radiolytic and photochemical methods. Theconvenience of these methyl thiyl radical sources will be interpretedin terms of the turn-over numbers in the radical chain cis-transisomerization reaction of unsaturated lipids.
Fil: Barata Vallejo, Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica. Cátedra de Química Orgánica I; Argentina
Fil: Yerien, Damián Emilio. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica. Cátedra de Química Orgánica I; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Postigo, Jose Alberto. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica. Cátedra de Química Orgánica I; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description Sodium thiomethoxide and dimethyldisulfide will be shown to beconvenient sources of methyl thiyl radicals for effecting thecis-trans double bond isomerization of oleic acid to elaidic acidresidues arranged in phospholipid bilayers of the microheterogeneousaqueous environment of liposomes. The methods used for methyl thiylradical generation encompass radiolytic and photochemical methods. Theconvenience of these methyl thiyl radical sources will be interpretedin terms of the turn-over numbers in the radical chain cis-transisomerization reaction of unsaturated lipids.
publishDate 2012
dc.date.none.fl_str_mv 2012-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/273469
Barata Vallejo, Sebastian; Yerien, Damián Emilio; Postigo, Jose Alberto; Reactivity of Thiyl Radicals Generated from Thiomethoxide and Dimethyldisulfide in Microheterogeneous Media; Bentham Science Publishers; Current Organic Chemistry; 16; 20; 10-2012; 2423-2429
1385-2728
CONICET Digital
CONICET
url http://hdl.handle.net/11336/273469
identifier_str_mv Barata Vallejo, Sebastian; Yerien, Damián Emilio; Postigo, Jose Alberto; Reactivity of Thiyl Radicals Generated from Thiomethoxide and Dimethyldisulfide in Microheterogeneous Media; Bentham Science Publishers; Current Organic Chemistry; 16; 20; 10-2012; 2423-2429
1385-2728
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.2174/138527212803520065
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Bentham Science Publishers
publisher.none.fl_str_mv Bentham Science Publishers
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846782018120056832
score 12.982451

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