Co3(SO4)3(OH)2[enH 2]: A New S = 3/2 kagome-type layered sulfate with a unique connectivity

Autores
Powell, Anthony V.; Leyva-Bailen, Patricia; Vaqueiro, Paz; Sanchez, Rodolfo Daniel
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The versatile method of structure-directed synthesis in a sulfuric acid system for the preparation of novel metal sulfates including those with structures comprising vertex-linked M(O,F)6 octahedra with a Kagome topology was explored. Terminal atoms of the sulfate anions are directed above and below the layers into the inter-layer space, where diprotonated ethylenediamine cations, which further balance the anionic charges of the layers and provide linkage between layers through an extensive network of hydrogen bonds between amino cations. The effective magnetic moment per cobalt ion decreases on cooling from 300 to 12 K, owing to a combination of a reduction in the orbital contribution and anti-ferromagnetic correlations. Interaction between clusters which are geometrically frustrated Interaction introduced the considerable complexity into the macroscopic magnetic behavior, where the degree of complexity in the material will necessitate detailed neutron measurements as a function of temperature.
Fil: Powell, Anthony V.. Heriot-watt University; Reino Unido
Fil: Leyva-Bailen, Patricia. Heriot-watt University; Reino Unido
Fil: Vaqueiro, Paz. Heriot-watt University; Reino Unido
Fil: Sanchez, Rodolfo Daniel. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
Geometrically Frustrated
Cobaltites
Magnetism
Kagome Layered
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/68572
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Co3(SO4)3(OH)2[enH 2]: A New S = 3/2 kagome-type layered sulfate with a unique connectivityPowell, Anthony V.Leyva-Bailen, PatriciaVaqueiro, PazSanchez, Rodolfo DanielGeometrically FrustratedCobaltitesMagnetismKagome Layeredhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1The versatile method of structure-directed synthesis in a sulfuric acid system for the preparation of novel metal sulfates including those with structures comprising vertex-linked M(O,F)6 octahedra with a Kagome topology was explored. Terminal atoms of the sulfate anions are directed above and below the layers into the inter-layer space, where diprotonated ethylenediamine cations, which further balance the anionic charges of the layers and provide linkage between layers through an extensive network of hydrogen bonds between amino cations. The effective magnetic moment per cobalt ion decreases on cooling from 300 to 12 K, owing to a combination of a reduction in the orbital contribution and anti-ferromagnetic correlations. Interaction between clusters which are geometrically frustrated Interaction introduced the considerable complexity into the macroscopic magnetic behavior, where the degree of complexity in the material will necessitate detailed neutron measurements as a function of temperature.Fil: Powell, Anthony V.. Heriot-watt University; Reino UnidoFil: Leyva-Bailen, Patricia. Heriot-watt University; Reino UnidoFil: Vaqueiro, Paz. Heriot-watt University; Reino UnidoFil: Sanchez, Rodolfo Daniel. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaAmerican Chemical Society2009-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/68572Powell, Anthony V.; Leyva-Bailen, Patricia; Vaqueiro, Paz; Sanchez, Rodolfo Daniel; Co3(SO4)3(OH)2[enH 2]: A New S = 3/2 kagome-type layered sulfate with a unique connectivity; American Chemical Society; Chemistry Of Materials; 21; 18; 9-2009; 4102-41040897-4756CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/cm901765ninfo:eu-repo/semantics/altIdentifier/doi/10.1021/cm901765ninfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:07:12Zoai:ri.conicet.gov.ar:11336/68572instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:07:13.002CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Co3(SO4)3(OH)2[enH 2]: A New S = 3/2 kagome-type layered sulfate with a unique connectivity
title Co3(SO4)3(OH)2[enH 2]: A New S = 3/2 kagome-type layered sulfate with a unique connectivity
spellingShingle Co3(SO4)3(OH)2[enH 2]: A New S = 3/2 kagome-type layered sulfate with a unique connectivity
Powell, Anthony V.
Geometrically Frustrated
Cobaltites
Magnetism
Kagome Layered
title_short Co3(SO4)3(OH)2[enH 2]: A New S = 3/2 kagome-type layered sulfate with a unique connectivity
title_full Co3(SO4)3(OH)2[enH 2]: A New S = 3/2 kagome-type layered sulfate with a unique connectivity
title_fullStr Co3(SO4)3(OH)2[enH 2]: A New S = 3/2 kagome-type layered sulfate with a unique connectivity
title_full_unstemmed Co3(SO4)3(OH)2[enH 2]: A New S = 3/2 kagome-type layered sulfate with a unique connectivity
title_sort Co3(SO4)3(OH)2[enH 2]: A New S = 3/2 kagome-type layered sulfate with a unique connectivity
dc.creator.none.fl_str_mv Powell, Anthony V.
Leyva-Bailen, Patricia
Vaqueiro, Paz
Sanchez, Rodolfo Daniel
author Powell, Anthony V.
author_facet Powell, Anthony V.
Leyva-Bailen, Patricia
Vaqueiro, Paz
Sanchez, Rodolfo Daniel
author_role author
author2 Leyva-Bailen, Patricia
Vaqueiro, Paz
Sanchez, Rodolfo Daniel
author2_role author
author
author
dc.subject.none.fl_str_mv Geometrically Frustrated
Cobaltites
Magnetism
Kagome Layered
topic Geometrically Frustrated
Cobaltites
Magnetism
Kagome Layered
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The versatile method of structure-directed synthesis in a sulfuric acid system for the preparation of novel metal sulfates including those with structures comprising vertex-linked M(O,F)6 octahedra with a Kagome topology was explored. Terminal atoms of the sulfate anions are directed above and below the layers into the inter-layer space, where diprotonated ethylenediamine cations, which further balance the anionic charges of the layers and provide linkage between layers through an extensive network of hydrogen bonds between amino cations. The effective magnetic moment per cobalt ion decreases on cooling from 300 to 12 K, owing to a combination of a reduction in the orbital contribution and anti-ferromagnetic correlations. Interaction between clusters which are geometrically frustrated Interaction introduced the considerable complexity into the macroscopic magnetic behavior, where the degree of complexity in the material will necessitate detailed neutron measurements as a function of temperature.
Fil: Powell, Anthony V.. Heriot-watt University; Reino Unido
Fil: Leyva-Bailen, Patricia. Heriot-watt University; Reino Unido
Fil: Vaqueiro, Paz. Heriot-watt University; Reino Unido
Fil: Sanchez, Rodolfo Daniel. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description The versatile method of structure-directed synthesis in a sulfuric acid system for the preparation of novel metal sulfates including those with structures comprising vertex-linked M(O,F)6 octahedra with a Kagome topology was explored. Terminal atoms of the sulfate anions are directed above and below the layers into the inter-layer space, where diprotonated ethylenediamine cations, which further balance the anionic charges of the layers and provide linkage between layers through an extensive network of hydrogen bonds between amino cations. The effective magnetic moment per cobalt ion decreases on cooling from 300 to 12 K, owing to a combination of a reduction in the orbital contribution and anti-ferromagnetic correlations. Interaction between clusters which are geometrically frustrated Interaction introduced the considerable complexity into the macroscopic magnetic behavior, where the degree of complexity in the material will necessitate detailed neutron measurements as a function of temperature.
publishDate 2009
dc.date.none.fl_str_mv 2009-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/68572
Powell, Anthony V.; Leyva-Bailen, Patricia; Vaqueiro, Paz; Sanchez, Rodolfo Daniel; Co3(SO4)3(OH)2[enH 2]: A New S = 3/2 kagome-type layered sulfate with a unique connectivity; American Chemical Society; Chemistry Of Materials; 21; 18; 9-2009; 4102-4104
0897-4756
CONICET Digital
CONICET
url http://hdl.handle.net/11336/68572
identifier_str_mv Powell, Anthony V.; Leyva-Bailen, Patricia; Vaqueiro, Paz; Sanchez, Rodolfo Daniel; Co3(SO4)3(OH)2[enH 2]: A New S = 3/2 kagome-type layered sulfate with a unique connectivity; American Chemical Society; Chemistry Of Materials; 21; 18; 9-2009; 4102-4104
0897-4756
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/cm901765n
info:eu-repo/semantics/altIdentifier/doi/10.1021/cm901765n
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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