Synthesis and characterization of bistropolonato oxovanadium(IV and V) complexes

Autores
Parajón Costa, Beatriz Susana; Baran, Enrique José; Romero, Julio; Saez Puche, Regino; Arrambide, Gabriel; Gambino, Dinorah
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Oxovanadium(IV) and oxovanadium(V) complexes of tropolone (Htrp, 2-hydroxi-2,4,6-cycloheptatrien-1-one), of stoichiometry VO(trp)2 and VO(trp)2Cl, were characterized by electronic, infrared and Raman spectroscopy. Their electrochemical behavior was investigated by cyclic voltamperommetry in dimethylsulfoxide solutions. The magnetic susceptibility of VO(trp)2 was investigated in the temperature range between 2 and 300 K. The vibrational spectra of the related Co(trp)2, Cu(trp)2 and Zn(trp)2 complexes were also analyzed for comparative purposes. 
Fil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Romero, Julio. Universidad Complutense de Madrid; España
Fil: Saez Puche, Regino. Universidad Complutense de Madrid; España
Fil: Arrambide, Gabriel. Universidad de la República; Uruguay
Fil: Gambino, Dinorah. Universidad de la República; Uruguay
Materia
Tropolone
Oxovanadium complexes
Electronic spectra
IR and Raman spectra
Cyclic voltamperommetry
Magnetic susceptibility
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/124954
Acceder
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network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Synthesis and characterization of bistropolonato oxovanadium(IV and V) complexesParajón Costa, Beatriz SusanaBaran, Enrique JoséRomero, JulioSaez Puche, ReginoArrambide, GabrielGambino, DinorahTropoloneOxovanadium complexesElectronic spectraIR and Raman spectraCyclic voltamperommetryMagnetic susceptibilityhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Oxovanadium(IV) and oxovanadium(V) complexes of tropolone (Htrp, 2-hydroxi-2,4,6-cycloheptatrien-1-one), of stoichiometry VO(trp)2 and VO(trp)2Cl, were characterized by electronic, infrared and Raman spectroscopy. Their electrochemical behavior was investigated by cyclic voltamperommetry in dimethylsulfoxide solutions. The magnetic susceptibility of VO(trp)2 was investigated in the temperature range between 2 and 300 K. The vibrational spectra of the related Co(trp)2, Cu(trp)2 and Zn(trp)2 complexes were also analyzed for comparative purposes. Fil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Romero, Julio. Universidad Complutense de Madrid; EspañaFil: Saez Puche, Regino. Universidad Complutense de Madrid; EspañaFil: Arrambide, Gabriel. Universidad de la República; UruguayFil: Gambino, Dinorah. Universidad de la República; UruguayTaylor & Francis Ltd2011-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/124954Parajón Costa, Beatriz Susana; Baran, Enrique José; Romero, Julio; Saez Puche, Regino; Arrambide, Gabriel; et al.; Synthesis and characterization of bistropolonato oxovanadium(IV and V) complexes; Taylor & Francis Ltd; Journal of Coordination Chemistry; 64; 1; 1-2011; 57-700095-8972CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1080/00958972.2010.531131info:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/full/10.1080/00958972.2010.531131info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:48:30Zoai:ri.conicet.gov.ar:11336/124954instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:48:31.249CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis and characterization of bistropolonato oxovanadium(IV and V) complexes
title Synthesis and characterization of bistropolonato oxovanadium(IV and V) complexes
spellingShingle Synthesis and characterization of bistropolonato oxovanadium(IV and V) complexes
Parajón Costa, Beatriz Susana
Tropolone
Oxovanadium complexes
Electronic spectra
IR and Raman spectra
Cyclic voltamperommetry
Magnetic susceptibility
title_short Synthesis and characterization of bistropolonato oxovanadium(IV and V) complexes
title_full Synthesis and characterization of bistropolonato oxovanadium(IV and V) complexes
title_fullStr Synthesis and characterization of bistropolonato oxovanadium(IV and V) complexes
title_full_unstemmed Synthesis and characterization of bistropolonato oxovanadium(IV and V) complexes
title_sort Synthesis and characterization of bistropolonato oxovanadium(IV and V) complexes
dc.creator.none.fl_str_mv Parajón Costa, Beatriz Susana
Baran, Enrique José
Romero, Julio
Saez Puche, Regino
Arrambide, Gabriel
Gambino, Dinorah
author Parajón Costa, Beatriz Susana
author_facet Parajón Costa, Beatriz Susana
Baran, Enrique José
Romero, Julio
Saez Puche, Regino
Arrambide, Gabriel
Gambino, Dinorah
author_role author
author2 Baran, Enrique José
Romero, Julio
Saez Puche, Regino
Arrambide, Gabriel
Gambino, Dinorah
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Tropolone
Oxovanadium complexes
Electronic spectra
IR and Raman spectra
Cyclic voltamperommetry
Magnetic susceptibility
topic Tropolone
Oxovanadium complexes
Electronic spectra
IR and Raman spectra
Cyclic voltamperommetry
Magnetic susceptibility
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Oxovanadium(IV) and oxovanadium(V) complexes of tropolone (Htrp, 2-hydroxi-2,4,6-cycloheptatrien-1-one), of stoichiometry VO(trp)2 and VO(trp)2Cl, were characterized by electronic, infrared and Raman spectroscopy. Their electrochemical behavior was investigated by cyclic voltamperommetry in dimethylsulfoxide solutions. The magnetic susceptibility of VO(trp)2 was investigated in the temperature range between 2 and 300 K. The vibrational spectra of the related Co(trp)2, Cu(trp)2 and Zn(trp)2 complexes were also analyzed for comparative purposes. 
Fil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Romero, Julio. Universidad Complutense de Madrid; España
Fil: Saez Puche, Regino. Universidad Complutense de Madrid; España
Fil: Arrambide, Gabriel. Universidad de la República; Uruguay
Fil: Gambino, Dinorah. Universidad de la República; Uruguay
description Oxovanadium(IV) and oxovanadium(V) complexes of tropolone (Htrp, 2-hydroxi-2,4,6-cycloheptatrien-1-one), of stoichiometry VO(trp)2 and VO(trp)2Cl, were characterized by electronic, infrared and Raman spectroscopy. Their electrochemical behavior was investigated by cyclic voltamperommetry in dimethylsulfoxide solutions. The magnetic susceptibility of VO(trp)2 was investigated in the temperature range between 2 and 300 K. The vibrational spectra of the related Co(trp)2, Cu(trp)2 and Zn(trp)2 complexes were also analyzed for comparative purposes. 
publishDate 2011
dc.date.none.fl_str_mv 2011-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/124954
Parajón Costa, Beatriz Susana; Baran, Enrique José; Romero, Julio; Saez Puche, Regino; Arrambide, Gabriel; et al.; Synthesis and characterization of bistropolonato oxovanadium(IV and V) complexes; Taylor & Francis Ltd; Journal of Coordination Chemistry; 64; 1; 1-2011; 57-70
0095-8972
CONICET Digital
CONICET
url http://hdl.handle.net/11336/124954
identifier_str_mv Parajón Costa, Beatriz Susana; Baran, Enrique José; Romero, Julio; Saez Puche, Regino; Arrambide, Gabriel; et al.; Synthesis and characterization of bistropolonato oxovanadium(IV and V) complexes; Taylor & Francis Ltd; Journal of Coordination Chemistry; 64; 1; 1-2011; 57-70
0095-8972
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1080/00958972.2010.531131
info:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/full/10.1080/00958972.2010.531131
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Taylor & Francis Ltd
publisher.none.fl_str_mv Taylor & Francis Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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