The contribution of order to the phase stability of β-Cu–Zn–Al

Autores
Lanzini, Fernando Gabriel; Romero, R.; Stipcich, Marcelo Fernando
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We report the lower stability temperatures, Tβ, of the bcc β phase for several alloys along the line of compositions Cu0.76-0.5x - Znx – Al0.24-0.5x, corresponding to a constant electron to atom ratio e/a = 1.48. The results have been obtained by means of differential scanning calorimetry (DSC) essays at various heating rates. The influence of atomic ordering on the stability of the bcc structure was evaluated using a mixed approach involving Monte Carlo simulations and the Cluster Variation Method. It was found that the chemical short and long range order contributes to the free energy of the alloy by an amount around 200 kB K.
Fil: Lanzini, Fernando Gabriel. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil; Argentina
Fil: Romero, R.. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; Argentina
Fil: Stipcich, Marcelo Fernando. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil; Argentina
Materia
Metals and alloys
Order-disorder transformations
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/278626

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spelling The contribution of order to the phase stability of β-Cu–Zn–AlLanzini, Fernando GabrielRomero, R.Stipcich, Marcelo FernandoMetals and alloysOrder-disorder transformationshttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1We report the lower stability temperatures, Tβ, of the bcc β phase for several alloys along the line of compositions Cu0.76-0.5x - Znx – Al0.24-0.5x, corresponding to a constant electron to atom ratio e/a = 1.48. The results have been obtained by means of differential scanning calorimetry (DSC) essays at various heating rates. The influence of atomic ordering on the stability of the bcc structure was evaluated using a mixed approach involving Monte Carlo simulations and the Cluster Variation Method. It was found that the chemical short and long range order contributes to the free energy of the alloy by an amount around 200 kB K.Fil: Lanzini, Fernando Gabriel. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil; ArgentinaFil: Romero, R.. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; ArgentinaFil: Stipcich, Marcelo Fernando. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil; ArgentinaIOP Publishing2011-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/278626Lanzini, Fernando Gabriel; Romero, R.; Stipcich, Marcelo Fernando; The contribution of order to the phase stability of β-Cu–Zn–Al; IOP Publishing; Journal of Physics: Condensed Matter; 23; 40; 9-2011; 1-80953-8984CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://iopscience.iop.org/article/10.1088/0953-8984/23/40/405404info:eu-repo/semantics/altIdentifier/doi/10.1088/0953-8984/23/40/405404info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2026-01-14T11:47:01Zoai:ri.conicet.gov.ar:11336/278626instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982026-01-14 11:47:02.002CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv The contribution of order to the phase stability of β-Cu–Zn–Al
title The contribution of order to the phase stability of β-Cu–Zn–Al
spellingShingle The contribution of order to the phase stability of β-Cu–Zn–Al
Lanzini, Fernando Gabriel
Metals and alloys
Order-disorder transformations
title_short The contribution of order to the phase stability of β-Cu–Zn–Al
title_full The contribution of order to the phase stability of β-Cu–Zn–Al
title_fullStr The contribution of order to the phase stability of β-Cu–Zn–Al
title_full_unstemmed The contribution of order to the phase stability of β-Cu–Zn–Al
title_sort The contribution of order to the phase stability of β-Cu–Zn–Al
dc.creator.none.fl_str_mv Lanzini, Fernando Gabriel
Romero, R.
Stipcich, Marcelo Fernando
author Lanzini, Fernando Gabriel
author_facet Lanzini, Fernando Gabriel
Romero, R.
Stipcich, Marcelo Fernando
author_role author
author2 Romero, R.
Stipcich, Marcelo Fernando
author2_role author
author
dc.subject.none.fl_str_mv Metals and alloys
Order-disorder transformations
topic Metals and alloys
Order-disorder transformations
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv We report the lower stability temperatures, Tβ, of the bcc β phase for several alloys along the line of compositions Cu0.76-0.5x - Znx – Al0.24-0.5x, corresponding to a constant electron to atom ratio e/a = 1.48. The results have been obtained by means of differential scanning calorimetry (DSC) essays at various heating rates. The influence of atomic ordering on the stability of the bcc structure was evaluated using a mixed approach involving Monte Carlo simulations and the Cluster Variation Method. It was found that the chemical short and long range order contributes to the free energy of the alloy by an amount around 200 kB K.
Fil: Lanzini, Fernando Gabriel. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil; Argentina
Fil: Romero, R.. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; Argentina
Fil: Stipcich, Marcelo Fernando. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil; Argentina
description We report the lower stability temperatures, Tβ, of the bcc β phase for several alloys along the line of compositions Cu0.76-0.5x - Znx – Al0.24-0.5x, corresponding to a constant electron to atom ratio e/a = 1.48. The results have been obtained by means of differential scanning calorimetry (DSC) essays at various heating rates. The influence of atomic ordering on the stability of the bcc structure was evaluated using a mixed approach involving Monte Carlo simulations and the Cluster Variation Method. It was found that the chemical short and long range order contributes to the free energy of the alloy by an amount around 200 kB K.
publishDate 2011
dc.date.none.fl_str_mv 2011-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/278626
Lanzini, Fernando Gabriel; Romero, R.; Stipcich, Marcelo Fernando; The contribution of order to the phase stability of β-Cu–Zn–Al; IOP Publishing; Journal of Physics: Condensed Matter; 23; 40; 9-2011; 1-8
0953-8984
CONICET Digital
CONICET
url http://hdl.handle.net/11336/278626
identifier_str_mv Lanzini, Fernando Gabriel; Romero, R.; Stipcich, Marcelo Fernando; The contribution of order to the phase stability of β-Cu–Zn–Al; IOP Publishing; Journal of Physics: Condensed Matter; 23; 40; 9-2011; 1-8
0953-8984
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://iopscience.iop.org/article/10.1088/0953-8984/23/40/405404
info:eu-repo/semantics/altIdentifier/doi/10.1088/0953-8984/23/40/405404
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv IOP Publishing
publisher.none.fl_str_mv IOP Publishing
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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