Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications
- Autores
- Games, Lucas Aloia; Gomez Sanchez, Andrea Valeria; Jimenez Piqué, Emilio; Schreiner, Wido H.; Cere, Silvia; Ballarre, Josefina
- Año de publicación
- 2012
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Potentiostatic anodizing of commercially pure titanium, using ammonium phosphate and ammonium fluoride solution as electrolyte is studied. The objective is to generate titanium oxides on the surface and phosphor compounds presenting good protective and mechanical properties, and proper adhesion to the metal substrate to remain during surgical orthopedic procedures (implants). Two different applied potentials were used to obtain different surface oxides morphologies (20 and 30V). The characterization and quantification of the generated deposits is presented as a starting point for the future application of these composite types of materials. X-ray Photoelectron Spectroscopy (XPS) and Raman spectroscopy techniques showed the presence of phosphor compounds and anatase (TiO2) as the main constitutive phases. Anodized samples presented less passivity current density with respect to the bare substrate, showing that the film formed by anodizing acts as an effective barrier to the electrolyte entrance to reach the metallic surface. Besides, mechanical properties of bare substrate were improved with the formation of anodic films: hardness value was increased in the oxide zones and the Young’s elastic modulus was decreased in the phosphor-compounds zones in the sample anodized with 30V, generating an interface with different elastic properties that could be able to enhance the prosthesis performance. Nano-scratch tests showed a very ductile behavior and good adhesion of anodic films, without any apparent signs of cracks or delamination.
Fil: Games, Lucas Aloia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Gomez Sanchez, Andrea Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Jimenez Piqué, Emilio. Universitat Politècnica de Catalunya; España
Fil: Schreiner, Wido H.. Universidade Federal do Paraná; Brasil
Fil: Cere, Silvia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Ballarre, Josefina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina - Materia
-
Anodizing
Titanium
Phosphor-Compounds
Adhesion
Nanoindentation - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/6474
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Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applicationsGames, Lucas AloiaGomez Sanchez, Andrea ValeriaJimenez Piqué, EmilioSchreiner, Wido H.Cere, SilviaBallarre, JosefinaAnodizingTitaniumPhosphor-CompoundsAdhesionNanoindentationhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Potentiostatic anodizing of commercially pure titanium, using ammonium phosphate and ammonium fluoride solution as electrolyte is studied. The objective is to generate titanium oxides on the surface and phosphor compounds presenting good protective and mechanical properties, and proper adhesion to the metal substrate to remain during surgical orthopedic procedures (implants). Two different applied potentials were used to obtain different surface oxides morphologies (20 and 30V). The characterization and quantification of the generated deposits is presented as a starting point for the future application of these composite types of materials. X-ray Photoelectron Spectroscopy (XPS) and Raman spectroscopy techniques showed the presence of phosphor compounds and anatase (TiO2) as the main constitutive phases. Anodized samples presented less passivity current density with respect to the bare substrate, showing that the film formed by anodizing acts as an effective barrier to the electrolyte entrance to reach the metallic surface. Besides, mechanical properties of bare substrate were improved with the formation of anodic films: hardness value was increased in the oxide zones and the Young’s elastic modulus was decreased in the phosphor-compounds zones in the sample anodized with 30V, generating an interface with different elastic properties that could be able to enhance the prosthesis performance. Nano-scratch tests showed a very ductile behavior and good adhesion of anodic films, without any apparent signs of cracks or delamination.Fil: Games, Lucas Aloia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Gomez Sanchez, Andrea Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Jimenez Piqué, Emilio. Universitat Politècnica de Catalunya; EspañaFil: Schreiner, Wido H.. Universidade Federal do Paraná; BrasilFil: Cere, Silvia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Ballarre, Josefina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaElsevier2012-04-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/6474Games, Lucas Aloia; Gomez Sanchez, Andrea Valeria; Jimenez Piqué, Emilio; Schreiner, Wido H.; Cere, Silvia; et al.; Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications; Elsevier; Surface and Coatings Technology; 206; 23; 9-4-2012; 4791-47980257-8972enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0257897212002812info:eu-repo/semantics/altIdentifier/doi/10.1016/j.surfcoat.2012.03.092info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:45:13Zoai:ri.conicet.gov.ar:11336/6474instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:45:14.072CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications |
title |
Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications |
spellingShingle |
Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications Games, Lucas Aloia Anodizing Titanium Phosphor-Compounds Adhesion Nanoindentation |
title_short |
Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications |
title_full |
Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications |
title_fullStr |
Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications |
title_full_unstemmed |
Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications |
title_sort |
Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications |
dc.creator.none.fl_str_mv |
Games, Lucas Aloia Gomez Sanchez, Andrea Valeria Jimenez Piqué, Emilio Schreiner, Wido H. Cere, Silvia Ballarre, Josefina |
author |
Games, Lucas Aloia |
author_facet |
Games, Lucas Aloia Gomez Sanchez, Andrea Valeria Jimenez Piqué, Emilio Schreiner, Wido H. Cere, Silvia Ballarre, Josefina |
author_role |
author |
author2 |
Gomez Sanchez, Andrea Valeria Jimenez Piqué, Emilio Schreiner, Wido H. Cere, Silvia Ballarre, Josefina |
author2_role |
author author author author author |
dc.subject.none.fl_str_mv |
Anodizing Titanium Phosphor-Compounds Adhesion Nanoindentation |
topic |
Anodizing Titanium Phosphor-Compounds Adhesion Nanoindentation |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Potentiostatic anodizing of commercially pure titanium, using ammonium phosphate and ammonium fluoride solution as electrolyte is studied. The objective is to generate titanium oxides on the surface and phosphor compounds presenting good protective and mechanical properties, and proper adhesion to the metal substrate to remain during surgical orthopedic procedures (implants). Two different applied potentials were used to obtain different surface oxides morphologies (20 and 30V). The characterization and quantification of the generated deposits is presented as a starting point for the future application of these composite types of materials. X-ray Photoelectron Spectroscopy (XPS) and Raman spectroscopy techniques showed the presence of phosphor compounds and anatase (TiO2) as the main constitutive phases. Anodized samples presented less passivity current density with respect to the bare substrate, showing that the film formed by anodizing acts as an effective barrier to the electrolyte entrance to reach the metallic surface. Besides, mechanical properties of bare substrate were improved with the formation of anodic films: hardness value was increased in the oxide zones and the Young’s elastic modulus was decreased in the phosphor-compounds zones in the sample anodized with 30V, generating an interface with different elastic properties that could be able to enhance the prosthesis performance. Nano-scratch tests showed a very ductile behavior and good adhesion of anodic films, without any apparent signs of cracks or delamination. Fil: Games, Lucas Aloia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina Fil: Gomez Sanchez, Andrea Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina Fil: Jimenez Piqué, Emilio. Universitat Politècnica de Catalunya; España Fil: Schreiner, Wido H.. Universidade Federal do Paraná; Brasil Fil: Cere, Silvia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina Fil: Ballarre, Josefina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina |
description |
Potentiostatic anodizing of commercially pure titanium, using ammonium phosphate and ammonium fluoride solution as electrolyte is studied. The objective is to generate titanium oxides on the surface and phosphor compounds presenting good protective and mechanical properties, and proper adhesion to the metal substrate to remain during surgical orthopedic procedures (implants). Two different applied potentials were used to obtain different surface oxides morphologies (20 and 30V). The characterization and quantification of the generated deposits is presented as a starting point for the future application of these composite types of materials. X-ray Photoelectron Spectroscopy (XPS) and Raman spectroscopy techniques showed the presence of phosphor compounds and anatase (TiO2) as the main constitutive phases. Anodized samples presented less passivity current density with respect to the bare substrate, showing that the film formed by anodizing acts as an effective barrier to the electrolyte entrance to reach the metallic surface. Besides, mechanical properties of bare substrate were improved with the formation of anodic films: hardness value was increased in the oxide zones and the Young’s elastic modulus was decreased in the phosphor-compounds zones in the sample anodized with 30V, generating an interface with different elastic properties that could be able to enhance the prosthesis performance. Nano-scratch tests showed a very ductile behavior and good adhesion of anodic films, without any apparent signs of cracks or delamination. |
publishDate |
2012 |
dc.date.none.fl_str_mv |
2012-04-09 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/6474 Games, Lucas Aloia; Gomez Sanchez, Andrea Valeria; Jimenez Piqué, Emilio; Schreiner, Wido H.; Cere, Silvia; et al.; Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications; Elsevier; Surface and Coatings Technology; 206; 23; 9-4-2012; 4791-4798 0257-8972 |
url |
http://hdl.handle.net/11336/6474 |
identifier_str_mv |
Games, Lucas Aloia; Gomez Sanchez, Andrea Valeria; Jimenez Piqué, Emilio; Schreiner, Wido H.; Cere, Silvia; et al.; Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications; Elsevier; Surface and Coatings Technology; 206; 23; 9-4-2012; 4791-4798 0257-8972 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0257897212002812 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.surfcoat.2012.03.092 info:eu-repo/semantics/altIdentifier/doi/ |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844613420489375744 |
score |
13.070432 |