Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications

Autores
Games, Lucas Aloia; Gomez Sanchez, Andrea Valeria; Jimenez Piqué, Emilio; Schreiner, Wido H.; Cere, Silvia; Ballarre, Josefina
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Potentiostatic anodizing of commercially pure titanium, using ammonium phosphate and ammonium fluoride solution as electrolyte is studied. The objective is to generate titanium oxides on the surface and phosphor compounds presenting good protective and mechanical properties, and proper adhesion to the metal substrate to remain during surgical orthopedic procedures (implants). Two different applied potentials were used to obtain different surface oxides morphologies (20 and 30V). The characterization and quantification of the generated deposits is presented as a starting point for the future application of these composite types of materials. X-ray Photoelectron Spectroscopy (XPS) and Raman spectroscopy techniques showed the presence of phosphor compounds and anatase (TiO2) as the main constitutive phases. Anodized samples presented less passivity current density with respect to the bare substrate, showing that the film formed by anodizing acts as an effective barrier to the electrolyte entrance to reach the metallic surface. Besides, mechanical properties of bare substrate were improved with the formation of anodic films: hardness value was increased in the oxide zones and the Young’s elastic modulus was decreased in the phosphor-compounds zones in the sample anodized with 30V, generating an interface with different elastic properties that could be able to enhance the prosthesis performance. Nano-scratch tests showed a very ductile behavior and good adhesion of anodic films, without any apparent signs of cracks or delamination.
Fil: Games, Lucas Aloia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Gomez Sanchez, Andrea Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Jimenez Piqué, Emilio. Universitat Politècnica de Catalunya; España
Fil: Schreiner, Wido H.. Universidade Federal do Paraná; Brasil
Fil: Cere, Silvia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Ballarre, Josefina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Materia
Anodizing
Titanium
Phosphor-Compounds
Adhesion
Nanoindentation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/6474
Acceder
id CONICETDig_60d7dc0d34c4becf02167e8992cd9a3b
oai_identifier_str oai:ri.conicet.gov.ar:11336/6474
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applicationsGames, Lucas AloiaGomez Sanchez, Andrea ValeriaJimenez Piqué, EmilioSchreiner, Wido H.Cere, SilviaBallarre, JosefinaAnodizingTitaniumPhosphor-CompoundsAdhesionNanoindentationhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Potentiostatic anodizing of commercially pure titanium, using ammonium phosphate and ammonium fluoride solution as electrolyte is studied. The objective is to generate titanium oxides on the surface and phosphor compounds presenting good protective and mechanical properties, and proper adhesion to the metal substrate to remain during surgical orthopedic procedures (implants). Two different applied potentials were used to obtain different surface oxides morphologies (20 and 30V). The characterization and quantification of the generated deposits is presented as a starting point for the future application of these composite types of materials. X-ray Photoelectron Spectroscopy (XPS) and Raman spectroscopy techniques showed the presence of phosphor compounds and anatase (TiO2) as the main constitutive phases. Anodized samples presented less passivity current density with respect to the bare substrate, showing that the film formed by anodizing acts as an effective barrier to the electrolyte entrance to reach the metallic surface. Besides, mechanical properties of bare substrate were improved with the formation of anodic films: hardness value was increased in the oxide zones and the Young’s elastic modulus was decreased in the phosphor-compounds zones in the sample anodized with 30V, generating an interface with different elastic properties that could be able to enhance the prosthesis performance. Nano-scratch tests showed a very ductile behavior and good adhesion of anodic films, without any apparent signs of cracks or delamination.Fil: Games, Lucas Aloia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Gomez Sanchez, Andrea Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Jimenez Piqué, Emilio. Universitat Politècnica de Catalunya; EspañaFil: Schreiner, Wido H.. Universidade Federal do Paraná; BrasilFil: Cere, Silvia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Ballarre, Josefina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaElsevier2012-04-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/6474Games, Lucas Aloia; Gomez Sanchez, Andrea Valeria; Jimenez Piqué, Emilio; Schreiner, Wido H.; Cere, Silvia; et al.; Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications; Elsevier; Surface and Coatings Technology; 206; 23; 9-4-2012; 4791-47980257-8972enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0257897212002812info:eu-repo/semantics/altIdentifier/doi/10.1016/j.surfcoat.2012.03.092info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:14:06Zoai:ri.conicet.gov.ar:11336/6474instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:14:06.911CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications
title Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications
spellingShingle Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications
Games, Lucas Aloia
Anodizing
Titanium
Phosphor-Compounds
Adhesion
Nanoindentation
title_short Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications
title_full Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications
title_fullStr Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications
title_full_unstemmed Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications
title_sort Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications
dc.creator.none.fl_str_mv Games, Lucas Aloia
Gomez Sanchez, Andrea Valeria
Jimenez Piqué, Emilio
Schreiner, Wido H.
Cere, Silvia
Ballarre, Josefina
author Games, Lucas Aloia
author_facet Games, Lucas Aloia
Gomez Sanchez, Andrea Valeria
Jimenez Piqué, Emilio
Schreiner, Wido H.
Cere, Silvia
Ballarre, Josefina
author_role author
author2 Gomez Sanchez, Andrea Valeria
Jimenez Piqué, Emilio
Schreiner, Wido H.
Cere, Silvia
Ballarre, Josefina
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Anodizing
Titanium
Phosphor-Compounds
Adhesion
Nanoindentation
topic Anodizing
Titanium
Phosphor-Compounds
Adhesion
Nanoindentation
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Potentiostatic anodizing of commercially pure titanium, using ammonium phosphate and ammonium fluoride solution as electrolyte is studied. The objective is to generate titanium oxides on the surface and phosphor compounds presenting good protective and mechanical properties, and proper adhesion to the metal substrate to remain during surgical orthopedic procedures (implants). Two different applied potentials were used to obtain different surface oxides morphologies (20 and 30V). The characterization and quantification of the generated deposits is presented as a starting point for the future application of these composite types of materials. X-ray Photoelectron Spectroscopy (XPS) and Raman spectroscopy techniques showed the presence of phosphor compounds and anatase (TiO2) as the main constitutive phases. Anodized samples presented less passivity current density with respect to the bare substrate, showing that the film formed by anodizing acts as an effective barrier to the electrolyte entrance to reach the metallic surface. Besides, mechanical properties of bare substrate were improved with the formation of anodic films: hardness value was increased in the oxide zones and the Young’s elastic modulus was decreased in the phosphor-compounds zones in the sample anodized with 30V, generating an interface with different elastic properties that could be able to enhance the prosthesis performance. Nano-scratch tests showed a very ductile behavior and good adhesion of anodic films, without any apparent signs of cracks or delamination.
Fil: Games, Lucas Aloia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Gomez Sanchez, Andrea Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Jimenez Piqué, Emilio. Universitat Politècnica de Catalunya; España
Fil: Schreiner, Wido H.. Universidade Federal do Paraná; Brasil
Fil: Cere, Silvia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Ballarre, Josefina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
description Potentiostatic anodizing of commercially pure titanium, using ammonium phosphate and ammonium fluoride solution as electrolyte is studied. The objective is to generate titanium oxides on the surface and phosphor compounds presenting good protective and mechanical properties, and proper adhesion to the metal substrate to remain during surgical orthopedic procedures (implants). Two different applied potentials were used to obtain different surface oxides morphologies (20 and 30V). The characterization and quantification of the generated deposits is presented as a starting point for the future application of these composite types of materials. X-ray Photoelectron Spectroscopy (XPS) and Raman spectroscopy techniques showed the presence of phosphor compounds and anatase (TiO2) as the main constitutive phases. Anodized samples presented less passivity current density with respect to the bare substrate, showing that the film formed by anodizing acts as an effective barrier to the electrolyte entrance to reach the metallic surface. Besides, mechanical properties of bare substrate were improved with the formation of anodic films: hardness value was increased in the oxide zones and the Young’s elastic modulus was decreased in the phosphor-compounds zones in the sample anodized with 30V, generating an interface with different elastic properties that could be able to enhance the prosthesis performance. Nano-scratch tests showed a very ductile behavior and good adhesion of anodic films, without any apparent signs of cracks or delamination.
publishDate 2012
dc.date.none.fl_str_mv 2012-04-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/6474
Games, Lucas Aloia; Gomez Sanchez, Andrea Valeria; Jimenez Piqué, Emilio; Schreiner, Wido H.; Cere, Silvia; et al.; Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications; Elsevier; Surface and Coatings Technology; 206; 23; 9-4-2012; 4791-4798
0257-8972
url http://hdl.handle.net/11336/6474
identifier_str_mv Games, Lucas Aloia; Gomez Sanchez, Andrea Valeria; Jimenez Piqué, Emilio; Schreiner, Wido H.; Cere, Silvia; et al.; Chemical and mechanical properties of anodized cp-titanium in NH4 H2PO4/NH4F media for biomedical applications; Elsevier; Surface and Coatings Technology; 206; 23; 9-4-2012; 4791-4798
0257-8972
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0257897212002812
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.surfcoat.2012.03.092
info:eu-repo/semantics/altIdentifier/doi/
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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