Steel Corrosion in Highly Carbonated Solutions Mitigated Using Biphosphate Ions as Inhibiting Agents
- Autores
- Tolosa, E.; Frontini, María Alejandra; Yohai del Cerro, Lucía; Vazquez, Marcela Vivian; Valcarce, María Beatriz
- Año de publicación
- 2023
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The effect of biphosphate ions as potential inhibiting agents for constructed steel is analyzed in heavily carbonated solution (HCS) simulating concrete ([HCO3-] +[CO3=]) = 0.315 mol L-1). Three conditions are analyzed, always keeping pH=9: 1) a highly carbonated pore simulating solution (HCS), 2) HCS contaminated with NaCl 0.1 mol/L, and 3) HCS contaminated with NaCl 0.1 mol/L and incorporating biphosphate ions as inhibiting agent. In this last condition, three inhibitor dosages are tested, where the ratio [HPO42-] /[Cl-] is 0.2, 0.6, and 1. The results are compared to previous studies in solutions containing ten times less carbonate content. Several electrochemical and surface techniques are used to correlate inhibiting efficiency of biphosphate ions to dosage. The incorporation of biphosphate ions as inhibitors improves the resistance against localized corrosion. The passivating film is composed of a mixture of phosphates and oxides, mainly Fe(III) species. The inhibition efficiency is sensible to the content of biphosphate and carbonate ions in solution. The optimal dosage of Na2HPO4 is 0.06 mol L-1, where the inhibition efficiency evaluated over 6 weeks is higher than 99%. The benefit of using Na2HPO4 in proper concentrations as an efficient corrosion inhibitor is demonstrated for the experimental conditions under study.
Fil: Tolosa, E.. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Frontini, María Alejandra. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Yohai del Cerro, Lucía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Vazquez, Marcela Vivian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Valcarce, María Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina - Materia
-
corrosion
corrosion inhibition
corrosion protection
passivity - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/233345
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Steel Corrosion in Highly Carbonated Solutions Mitigated Using Biphosphate Ions as Inhibiting AgentsTolosa, E.Frontini, María AlejandraYohai del Cerro, LucíaVazquez, Marcela VivianValcarce, María Beatrizcorrosioncorrosion inhibitioncorrosion protectionpassivityhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The effect of biphosphate ions as potential inhibiting agents for constructed steel is analyzed in heavily carbonated solution (HCS) simulating concrete ([HCO3-] +[CO3=]) = 0.315 mol L-1). Three conditions are analyzed, always keeping pH=9: 1) a highly carbonated pore simulating solution (HCS), 2) HCS contaminated with NaCl 0.1 mol/L, and 3) HCS contaminated with NaCl 0.1 mol/L and incorporating biphosphate ions as inhibiting agent. In this last condition, three inhibitor dosages are tested, where the ratio [HPO42-] /[Cl-] is 0.2, 0.6, and 1. The results are compared to previous studies in solutions containing ten times less carbonate content. Several electrochemical and surface techniques are used to correlate inhibiting efficiency of biphosphate ions to dosage. The incorporation of biphosphate ions as inhibitors improves the resistance against localized corrosion. The passivating film is composed of a mixture of phosphates and oxides, mainly Fe(III) species. The inhibition efficiency is sensible to the content of biphosphate and carbonate ions in solution. The optimal dosage of Na2HPO4 is 0.06 mol L-1, where the inhibition efficiency evaluated over 6 weeks is higher than 99%. The benefit of using Na2HPO4 in proper concentrations as an efficient corrosion inhibitor is demonstrated for the experimental conditions under study.Fil: Tolosa, E.. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Frontini, María Alejandra. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Yohai del Cerro, Lucía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Vazquez, Marcela Vivian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Valcarce, María Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaIOP Publishing2023-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/233345Tolosa, E.; Frontini, María Alejandra; Yohai del Cerro, Lucía; Vazquez, Marcela Vivian; Valcarce, María Beatriz; Steel Corrosion in Highly Carbonated Solutions Mitigated Using Biphosphate Ions as Inhibiting Agents; IOP Publishing; Journal of the Electrochemical Society; 170; 3; 2-2023; 1-410013-46511945-7111CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://iopscience.iop.org/article/10.1149/1945-7111/acbc4einfo:eu-repo/semantics/altIdentifier/doi/10.1149/1945-7111/acbc4einfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:24:47Zoai:ri.conicet.gov.ar:11336/233345instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:24:47.313CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Steel Corrosion in Highly Carbonated Solutions Mitigated Using Biphosphate Ions as Inhibiting Agents |
title |
Steel Corrosion in Highly Carbonated Solutions Mitigated Using Biphosphate Ions as Inhibiting Agents |
spellingShingle |
Steel Corrosion in Highly Carbonated Solutions Mitigated Using Biphosphate Ions as Inhibiting Agents Tolosa, E. corrosion corrosion inhibition corrosion protection passivity |
title_short |
Steel Corrosion in Highly Carbonated Solutions Mitigated Using Biphosphate Ions as Inhibiting Agents |
title_full |
Steel Corrosion in Highly Carbonated Solutions Mitigated Using Biphosphate Ions as Inhibiting Agents |
title_fullStr |
Steel Corrosion in Highly Carbonated Solutions Mitigated Using Biphosphate Ions as Inhibiting Agents |
title_full_unstemmed |
Steel Corrosion in Highly Carbonated Solutions Mitigated Using Biphosphate Ions as Inhibiting Agents |
title_sort |
Steel Corrosion in Highly Carbonated Solutions Mitigated Using Biphosphate Ions as Inhibiting Agents |
dc.creator.none.fl_str_mv |
Tolosa, E. Frontini, María Alejandra Yohai del Cerro, Lucía Vazquez, Marcela Vivian Valcarce, María Beatriz |
author |
Tolosa, E. |
author_facet |
Tolosa, E. Frontini, María Alejandra Yohai del Cerro, Lucía Vazquez, Marcela Vivian Valcarce, María Beatriz |
author_role |
author |
author2 |
Frontini, María Alejandra Yohai del Cerro, Lucía Vazquez, Marcela Vivian Valcarce, María Beatriz |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
corrosion corrosion inhibition corrosion protection passivity |
topic |
corrosion corrosion inhibition corrosion protection passivity |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The effect of biphosphate ions as potential inhibiting agents for constructed steel is analyzed in heavily carbonated solution (HCS) simulating concrete ([HCO3-] +[CO3=]) = 0.315 mol L-1). Three conditions are analyzed, always keeping pH=9: 1) a highly carbonated pore simulating solution (HCS), 2) HCS contaminated with NaCl 0.1 mol/L, and 3) HCS contaminated with NaCl 0.1 mol/L and incorporating biphosphate ions as inhibiting agent. In this last condition, three inhibitor dosages are tested, where the ratio [HPO42-] /[Cl-] is 0.2, 0.6, and 1. The results are compared to previous studies in solutions containing ten times less carbonate content. Several electrochemical and surface techniques are used to correlate inhibiting efficiency of biphosphate ions to dosage. The incorporation of biphosphate ions as inhibitors improves the resistance against localized corrosion. The passivating film is composed of a mixture of phosphates and oxides, mainly Fe(III) species. The inhibition efficiency is sensible to the content of biphosphate and carbonate ions in solution. The optimal dosage of Na2HPO4 is 0.06 mol L-1, where the inhibition efficiency evaluated over 6 weeks is higher than 99%. The benefit of using Na2HPO4 in proper concentrations as an efficient corrosion inhibitor is demonstrated for the experimental conditions under study. Fil: Tolosa, E.. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina Fil: Frontini, María Alejandra. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina Fil: Yohai del Cerro, Lucía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Vazquez, Marcela Vivian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Valcarce, María Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina |
description |
The effect of biphosphate ions as potential inhibiting agents for constructed steel is analyzed in heavily carbonated solution (HCS) simulating concrete ([HCO3-] +[CO3=]) = 0.315 mol L-1). Three conditions are analyzed, always keeping pH=9: 1) a highly carbonated pore simulating solution (HCS), 2) HCS contaminated with NaCl 0.1 mol/L, and 3) HCS contaminated with NaCl 0.1 mol/L and incorporating biphosphate ions as inhibiting agent. In this last condition, three inhibitor dosages are tested, where the ratio [HPO42-] /[Cl-] is 0.2, 0.6, and 1. The results are compared to previous studies in solutions containing ten times less carbonate content. Several electrochemical and surface techniques are used to correlate inhibiting efficiency of biphosphate ions to dosage. The incorporation of biphosphate ions as inhibitors improves the resistance against localized corrosion. The passivating film is composed of a mixture of phosphates and oxides, mainly Fe(III) species. The inhibition efficiency is sensible to the content of biphosphate and carbonate ions in solution. The optimal dosage of Na2HPO4 is 0.06 mol L-1, where the inhibition efficiency evaluated over 6 weeks is higher than 99%. The benefit of using Na2HPO4 in proper concentrations as an efficient corrosion inhibitor is demonstrated for the experimental conditions under study. |
publishDate |
2023 |
dc.date.none.fl_str_mv |
2023-02 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/233345 Tolosa, E.; Frontini, María Alejandra; Yohai del Cerro, Lucía; Vazquez, Marcela Vivian; Valcarce, María Beatriz; Steel Corrosion in Highly Carbonated Solutions Mitigated Using Biphosphate Ions as Inhibiting Agents; IOP Publishing; Journal of the Electrochemical Society; 170; 3; 2-2023; 1-41 0013-4651 1945-7111 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/233345 |
identifier_str_mv |
Tolosa, E.; Frontini, María Alejandra; Yohai del Cerro, Lucía; Vazquez, Marcela Vivian; Valcarce, María Beatriz; Steel Corrosion in Highly Carbonated Solutions Mitigated Using Biphosphate Ions as Inhibiting Agents; IOP Publishing; Journal of the Electrochemical Society; 170; 3; 2-2023; 1-41 0013-4651 1945-7111 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://iopscience.iop.org/article/10.1149/1945-7111/acbc4e info:eu-repo/semantics/altIdentifier/doi/10.1149/1945-7111/acbc4e |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
IOP Publishing |
publisher.none.fl_str_mv |
IOP Publishing |
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reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844614244955324416 |
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13.070432 |