SBR/BiFeO3 Elastomer Capacitor Films Prepared under Magnetic and Electric Fields Displaying Magnetoelectric Coupling

Autores
Saleh Medina, Leila María; Jorge, Guillermo Antonio; Rubi, Diego; D'accorso, Norma Beatriz; Negri, Ricardo Martin
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The dielectric properties of elastomer composites formed by dispersions of bismuth ferrite (BiFeO3) multiferroic filler particles in styrene-butadiene rubber (SBR) were studied. The SBR/BiFeO3 films (10-100 μm) were prepared in the presence of electric (E) or magnetic fields (H), showing remarkable characteristics in comparison with systems obtained in its absence. The dispersed multiferroic fillers form clusters of much smaller size when prepared under E or H. The dielectric constant, ε (measured up to 1 MHz), increases with BiFeO3 concentration until reaching saturation. The rise of ε was obtained at concentrations much lower for samples prepared in the presence of E or H than in its absence. Saturation is assigned to connectivity between filler clusters at the largest concentrations, increasing leakage currents and limiting the dielectric behavior. The whole dependence of ε with BiFeO3 concentration was described using a proposed model. The dc resistivities, ρ, increase with BiFeO3 concentration but remain high (ρ ≈ 10 Gω·cm), allowing using the films as capacitors with filter action between 100 kHz and 7 MHz. The films prepared in the presence of H present strong dependence of the ferroelectric response with magnetic fields applied after preparation; that is, electromagnetic coupling was observed in those samples.
Fil: Saleh Medina, Leila María. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Jorge, Guillermo Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina
Fil: Rubi, Diego. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina
Fil: D'accorso, Norma Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; Argentina
Fil: Negri, Ricardo Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Materia
CAPACITORS
ELECTROMAGNETIC COUPLING
BISMUTH FERRITES
STYRENE BUTADYENE RUBBER
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/78083
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/78083
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling SBR/BiFeO3 Elastomer Capacitor Films Prepared under Magnetic and Electric Fields Displaying Magnetoelectric CouplingSaleh Medina, Leila MaríaJorge, Guillermo AntonioRubi, DiegoD'accorso, Norma BeatrizNegri, Ricardo MartinCAPACITORSELECTROMAGNETIC COUPLINGBISMUTH FERRITESSTYRENE BUTADYENE RUBBERhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The dielectric properties of elastomer composites formed by dispersions of bismuth ferrite (BiFeO3) multiferroic filler particles in styrene-butadiene rubber (SBR) were studied. The SBR/BiFeO3 films (10-100 μm) were prepared in the presence of electric (E) or magnetic fields (H), showing remarkable characteristics in comparison with systems obtained in its absence. The dispersed multiferroic fillers form clusters of much smaller size when prepared under E or H. The dielectric constant, ε (measured up to 1 MHz), increases with BiFeO3 concentration until reaching saturation. The rise of ε was obtained at concentrations much lower for samples prepared in the presence of E or H than in its absence. Saturation is assigned to connectivity between filler clusters at the largest concentrations, increasing leakage currents and limiting the dielectric behavior. The whole dependence of ε with BiFeO3 concentration was described using a proposed model. The dc resistivities, ρ, increase with BiFeO3 concentration but remain high (ρ ≈ 10 Gω·cm), allowing using the films as capacitors with filter action between 100 kHz and 7 MHz. The films prepared in the presence of H present strong dependence of the ferroelectric response with magnetic fields applied after preparation; that is, electromagnetic coupling was observed in those samples.Fil: Saleh Medina, Leila María. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Jorge, Guillermo Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias; ArgentinaFil: Rubi, Diego. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; ArgentinaFil: D'accorso, Norma Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; ArgentinaFil: Negri, Ricardo Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaAmerican Chemical Society2015-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/78083Saleh Medina, Leila María; Jorge, Guillermo Antonio; Rubi, Diego; D'accorso, Norma Beatriz; Negri, Ricardo Martin; SBR/BiFeO3 Elastomer Capacitor Films Prepared under Magnetic and Electric Fields Displaying Magnetoelectric Coupling; American Chemical Society; Journal of Physical Chemistry C; 119; 41; 10-2015; 23319-233281932-7447CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/10.1021/acs.jpcc.5b06056info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.jpcc.5b06056info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:16:38Zoai:ri.conicet.gov.ar:11336/78083instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:16:38.73CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv SBR/BiFeO3 Elastomer Capacitor Films Prepared under Magnetic and Electric Fields Displaying Magnetoelectric Coupling
title SBR/BiFeO3 Elastomer Capacitor Films Prepared under Magnetic and Electric Fields Displaying Magnetoelectric Coupling
spellingShingle SBR/BiFeO3 Elastomer Capacitor Films Prepared under Magnetic and Electric Fields Displaying Magnetoelectric Coupling
Saleh Medina, Leila María
CAPACITORS
ELECTROMAGNETIC COUPLING
BISMUTH FERRITES
STYRENE BUTADYENE RUBBER
title_short SBR/BiFeO3 Elastomer Capacitor Films Prepared under Magnetic and Electric Fields Displaying Magnetoelectric Coupling
title_full SBR/BiFeO3 Elastomer Capacitor Films Prepared under Magnetic and Electric Fields Displaying Magnetoelectric Coupling
title_fullStr SBR/BiFeO3 Elastomer Capacitor Films Prepared under Magnetic and Electric Fields Displaying Magnetoelectric Coupling
title_full_unstemmed SBR/BiFeO3 Elastomer Capacitor Films Prepared under Magnetic and Electric Fields Displaying Magnetoelectric Coupling
title_sort SBR/BiFeO3 Elastomer Capacitor Films Prepared under Magnetic and Electric Fields Displaying Magnetoelectric Coupling
dc.creator.none.fl_str_mv Saleh Medina, Leila María
Jorge, Guillermo Antonio
Rubi, Diego
D'accorso, Norma Beatriz
Negri, Ricardo Martin
author Saleh Medina, Leila María
author_facet Saleh Medina, Leila María
Jorge, Guillermo Antonio
Rubi, Diego
D'accorso, Norma Beatriz
Negri, Ricardo Martin
author_role author
author2 Jorge, Guillermo Antonio
Rubi, Diego
D'accorso, Norma Beatriz
Negri, Ricardo Martin
author2_role author
author
author
author
dc.subject.none.fl_str_mv CAPACITORS
ELECTROMAGNETIC COUPLING
BISMUTH FERRITES
STYRENE BUTADYENE RUBBER
topic CAPACITORS
ELECTROMAGNETIC COUPLING
BISMUTH FERRITES
STYRENE BUTADYENE RUBBER
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The dielectric properties of elastomer composites formed by dispersions of bismuth ferrite (BiFeO3) multiferroic filler particles in styrene-butadiene rubber (SBR) were studied. The SBR/BiFeO3 films (10-100 μm) were prepared in the presence of electric (E) or magnetic fields (H), showing remarkable characteristics in comparison with systems obtained in its absence. The dispersed multiferroic fillers form clusters of much smaller size when prepared under E or H. The dielectric constant, ε (measured up to 1 MHz), increases with BiFeO3 concentration until reaching saturation. The rise of ε was obtained at concentrations much lower for samples prepared in the presence of E or H than in its absence. Saturation is assigned to connectivity between filler clusters at the largest concentrations, increasing leakage currents and limiting the dielectric behavior. The whole dependence of ε with BiFeO3 concentration was described using a proposed model. The dc resistivities, ρ, increase with BiFeO3 concentration but remain high (ρ ≈ 10 Gω·cm), allowing using the films as capacitors with filter action between 100 kHz and 7 MHz. The films prepared in the presence of H present strong dependence of the ferroelectric response with magnetic fields applied after preparation; that is, electromagnetic coupling was observed in those samples.
Fil: Saleh Medina, Leila María. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Jorge, Guillermo Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina
Fil: Rubi, Diego. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina
Fil: D'accorso, Norma Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; Argentina
Fil: Negri, Ricardo Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
description The dielectric properties of elastomer composites formed by dispersions of bismuth ferrite (BiFeO3) multiferroic filler particles in styrene-butadiene rubber (SBR) were studied. The SBR/BiFeO3 films (10-100 μm) were prepared in the presence of electric (E) or magnetic fields (H), showing remarkable characteristics in comparison with systems obtained in its absence. The dispersed multiferroic fillers form clusters of much smaller size when prepared under E or H. The dielectric constant, ε (measured up to 1 MHz), increases with BiFeO3 concentration until reaching saturation. The rise of ε was obtained at concentrations much lower for samples prepared in the presence of E or H than in its absence. Saturation is assigned to connectivity between filler clusters at the largest concentrations, increasing leakage currents and limiting the dielectric behavior. The whole dependence of ε with BiFeO3 concentration was described using a proposed model. The dc resistivities, ρ, increase with BiFeO3 concentration but remain high (ρ ≈ 10 Gω·cm), allowing using the films as capacitors with filter action between 100 kHz and 7 MHz. The films prepared in the presence of H present strong dependence of the ferroelectric response with magnetic fields applied after preparation; that is, electromagnetic coupling was observed in those samples.
publishDate 2015
dc.date.none.fl_str_mv 2015-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/78083
Saleh Medina, Leila María; Jorge, Guillermo Antonio; Rubi, Diego; D'accorso, Norma Beatriz; Negri, Ricardo Martin; SBR/BiFeO3 Elastomer Capacitor Films Prepared under Magnetic and Electric Fields Displaying Magnetoelectric Coupling; American Chemical Society; Journal of Physical Chemistry C; 119; 41; 10-2015; 23319-23328
1932-7447
CONICET Digital
CONICET
url http://hdl.handle.net/11336/78083
identifier_str_mv Saleh Medina, Leila María; Jorge, Guillermo Antonio; Rubi, Diego; D'accorso, Norma Beatriz; Negri, Ricardo Martin; SBR/BiFeO3 Elastomer Capacitor Films Prepared under Magnetic and Electric Fields Displaying Magnetoelectric Coupling; American Chemical Society; Journal of Physical Chemistry C; 119; 41; 10-2015; 23319-23328
1932-7447
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/10.1021/acs.jpcc.5b06056
info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.jpcc.5b06056
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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