Structure determination of the intermediate tin oxide Sn304 by precession electron diffraction

Autores
White, Thomas A.; Moreno, Mario Sergio Jesus; Midgley, Paul A.
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The structure of an intermediate form of tin oxide was investigated by precession electron diffraction. The results support a revised version of a layered, vacancy-ordered structure for Sn304 proposed in the preceding literature. The lattice parameters were found to be consistent with a monoclinic cell which is a distorted superlattice of the cassiterite structure. Zero-order Laue zone (ZOLZ) Patterson maps, phased projections and phases measured from a [001] first-order Laue zone (FOLZ) conditional Patterson map all support the proposed modification to the tin coordinates over the unmodified form. The results of kinematical refinement were not satisfactory, although weak features found in the Patterson maps were consistent with the oxygen atoms being located close to the previously proposed positions.
Fil: White, Thomas A.. University of Cambridge; Reino Unido
Fil: Moreno, Mario Sergio Jesus. Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. - Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología; Argentina
Fil: Midgley, Paul A.. University of Cambridge; Reino Unido
Materia
precession electron diffraction
tin oxide
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/125007
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/125007
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Structure determination of the intermediate tin oxide Sn304 by precession electron diffractionWhite, Thomas A.Moreno, Mario Sergio JesusMidgley, Paul A.precession electron diffractiontin oxidehttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1The structure of an intermediate form of tin oxide was investigated by precession electron diffraction. The results support a revised version of a layered, vacancy-ordered structure for Sn304 proposed in the preceding literature. The lattice parameters were found to be consistent with a monoclinic cell which is a distorted superlattice of the cassiterite structure. Zero-order Laue zone (ZOLZ) Patterson maps, phased projections and phases measured from a [001] first-order Laue zone (FOLZ) conditional Patterson map all support the proposed modification to the tin coordinates over the unmodified form. The results of kinematical refinement were not satisfactory, although weak features found in the Patterson maps were consistent with the oxygen atoms being located close to the previously proposed positions.Fil: White, Thomas A.. University of Cambridge; Reino UnidoFil: Moreno, Mario Sergio Jesus. Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. - Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología; ArgentinaFil: Midgley, Paul A.. University of Cambridge; Reino UnidoOldenbourg Verlag2010-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/125007White, Thomas A.; Moreno, Mario Sergio Jesus; Midgley, Paul A.; Structure determination of the intermediate tin oxide Sn304 by precession electron diffraction; Oldenbourg Verlag; Zeitschrift Fur Kristallographie; 225; 2-3; 3-2010; 56-660044-2968CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/document/doi/10.1524/zkri.2010.1210/htmlinfo:eu-repo/semantics/altIdentifier/doi/10.1524/zkri.2010.1210info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:27:38Zoai:ri.conicet.gov.ar:11336/125007instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:27:38.7CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Structure determination of the intermediate tin oxide Sn304 by precession electron diffraction
title Structure determination of the intermediate tin oxide Sn304 by precession electron diffraction
spellingShingle Structure determination of the intermediate tin oxide Sn304 by precession electron diffraction
White, Thomas A.
precession electron diffraction
tin oxide
title_short Structure determination of the intermediate tin oxide Sn304 by precession electron diffraction
title_full Structure determination of the intermediate tin oxide Sn304 by precession electron diffraction
title_fullStr Structure determination of the intermediate tin oxide Sn304 by precession electron diffraction
title_full_unstemmed Structure determination of the intermediate tin oxide Sn304 by precession electron diffraction
title_sort Structure determination of the intermediate tin oxide Sn304 by precession electron diffraction
dc.creator.none.fl_str_mv White, Thomas A.
Moreno, Mario Sergio Jesus
Midgley, Paul A.
author White, Thomas A.
author_facet White, Thomas A.
Moreno, Mario Sergio Jesus
Midgley, Paul A.
author_role author
author2 Moreno, Mario Sergio Jesus
Midgley, Paul A.
author2_role author
author
dc.subject.none.fl_str_mv precession electron diffraction
tin oxide
topic precession electron diffraction
tin oxide
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The structure of an intermediate form of tin oxide was investigated by precession electron diffraction. The results support a revised version of a layered, vacancy-ordered structure for Sn304 proposed in the preceding literature. The lattice parameters were found to be consistent with a monoclinic cell which is a distorted superlattice of the cassiterite structure. Zero-order Laue zone (ZOLZ) Patterson maps, phased projections and phases measured from a [001] first-order Laue zone (FOLZ) conditional Patterson map all support the proposed modification to the tin coordinates over the unmodified form. The results of kinematical refinement were not satisfactory, although weak features found in the Patterson maps were consistent with the oxygen atoms being located close to the previously proposed positions.
Fil: White, Thomas A.. University of Cambridge; Reino Unido
Fil: Moreno, Mario Sergio Jesus. Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. - Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología; Argentina
Fil: Midgley, Paul A.. University of Cambridge; Reino Unido
description The structure of an intermediate form of tin oxide was investigated by precession electron diffraction. The results support a revised version of a layered, vacancy-ordered structure for Sn304 proposed in the preceding literature. The lattice parameters were found to be consistent with a monoclinic cell which is a distorted superlattice of the cassiterite structure. Zero-order Laue zone (ZOLZ) Patterson maps, phased projections and phases measured from a [001] first-order Laue zone (FOLZ) conditional Patterson map all support the proposed modification to the tin coordinates over the unmodified form. The results of kinematical refinement were not satisfactory, although weak features found in the Patterson maps were consistent with the oxygen atoms being located close to the previously proposed positions.
publishDate 2010
dc.date.none.fl_str_mv 2010-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/125007
White, Thomas A.; Moreno, Mario Sergio Jesus; Midgley, Paul A.; Structure determination of the intermediate tin oxide Sn304 by precession electron diffraction; Oldenbourg Verlag; Zeitschrift Fur Kristallographie; 225; 2-3; 3-2010; 56-66
0044-2968
CONICET Digital
CONICET
url http://hdl.handle.net/11336/125007
identifier_str_mv White, Thomas A.; Moreno, Mario Sergio Jesus; Midgley, Paul A.; Structure determination of the intermediate tin oxide Sn304 by precession electron diffraction; Oldenbourg Verlag; Zeitschrift Fur Kristallographie; 225; 2-3; 3-2010; 56-66
0044-2968
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/document/doi/10.1524/zkri.2010.1210/html
info:eu-repo/semantics/altIdentifier/doi/10.1524/zkri.2010.1210
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Oldenbourg Verlag
publisher.none.fl_str_mv Oldenbourg Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846082733498957824
score 13.22299

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