Non-covalent interactions at electrochemicalinterfaces: one model fits all?

Autores
Cabello, Gema; Leiva, Ezequiel Pedro M.; Gutierrez, Claudio; Cuesta, Angel
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The shift with increasing concentration of alkali-metal cations of the potentials of both the spike and the hump observed in the cyclic voltammograms of Pt(111) electrodes in sulfuric acid solutions is shown to obey the simple model recently developed by us to explain the effect of non-covalent interactions at the electrical double layer. The results suggest that the model, originally developed to describe the effect of alkali-metal cations on the cyclic voltammogram of cyanide-modified Pt(111) electrodes, is of general applicability and can explain quantitatively the effect of cations on the properties of the electrical double layer.
Fil: Cabello, Gema. Instituto de Química Física “Rocasolano”. Madrid; Argentina
Fil: Leiva, Ezequiel Pedro M.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Gutierrez, Claudio. Instituto de Química Física “Rocasolano”. Madrid; Argentina
Fil: Cuesta, Angel. Instituto de Química Física “Rocasolano”. Madrid; Argentina. University Of Aberdeen; Reino Unido
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/31349
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Non-covalent interactions at electrochemicalinterfaces: one model fits all?Cabello, GemaLeiva, Ezequiel Pedro M.Gutierrez, ClaudioCuesta, Angelhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The shift with increasing concentration of alkali-metal cations of the potentials of both the spike and the hump observed in the cyclic voltammograms of Pt(111) electrodes in sulfuric acid solutions is shown to obey the simple model recently developed by us to explain the effect of non-covalent interactions at the electrical double layer. The results suggest that the model, originally developed to describe the effect of alkali-metal cations on the cyclic voltammogram of cyanide-modified Pt(111) electrodes, is of general applicability and can explain quantitatively the effect of cations on the properties of the electrical double layer.Fil: Cabello, Gema. Instituto de Química Física “Rocasolano”. Madrid; ArgentinaFil: Leiva, Ezequiel Pedro M.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Gutierrez, Claudio. Instituto de Química Física “Rocasolano”. Madrid; ArgentinaFil: Cuesta, Angel. Instituto de Química Física “Rocasolano”. Madrid; Argentina. University Of Aberdeen; Reino UnidoRoyal Society of Chemistry2014-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31349Cabello, Gema; Leiva, Ezequiel Pedro M.; Gutierrez, Claudio; Cuesta, Angel; Non-covalent interactions at electrochemicalinterfaces: one model fits all?; Royal Society of Chemistry; Physical Chemistry Chemical Physics; 16; 5-2014; 14281-142861463-9076CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1039/c3cp53354ainfo:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2014/CP/C3CP53354Ainfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:50:09Zoai:ri.conicet.gov.ar:11336/31349instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:50:09.328CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Non-covalent interactions at electrochemicalinterfaces: one model fits all?
title Non-covalent interactions at electrochemicalinterfaces: one model fits all?
spellingShingle Non-covalent interactions at electrochemicalinterfaces: one model fits all?
Cabello, Gema
title_short Non-covalent interactions at electrochemicalinterfaces: one model fits all?
title_full Non-covalent interactions at electrochemicalinterfaces: one model fits all?
title_fullStr Non-covalent interactions at electrochemicalinterfaces: one model fits all?
title_full_unstemmed Non-covalent interactions at electrochemicalinterfaces: one model fits all?
title_sort Non-covalent interactions at electrochemicalinterfaces: one model fits all?
dc.creator.none.fl_str_mv Cabello, Gema
Leiva, Ezequiel Pedro M.
Gutierrez, Claudio
Cuesta, Angel
author Cabello, Gema
author_facet Cabello, Gema
Leiva, Ezequiel Pedro M.
Gutierrez, Claudio
Cuesta, Angel
author_role author
author2 Leiva, Ezequiel Pedro M.
Gutierrez, Claudio
Cuesta, Angel
author2_role author
author
author
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The shift with increasing concentration of alkali-metal cations of the potentials of both the spike and the hump observed in the cyclic voltammograms of Pt(111) electrodes in sulfuric acid solutions is shown to obey the simple model recently developed by us to explain the effect of non-covalent interactions at the electrical double layer. The results suggest that the model, originally developed to describe the effect of alkali-metal cations on the cyclic voltammogram of cyanide-modified Pt(111) electrodes, is of general applicability and can explain quantitatively the effect of cations on the properties of the electrical double layer.
Fil: Cabello, Gema. Instituto de Química Física “Rocasolano”. Madrid; Argentina
Fil: Leiva, Ezequiel Pedro M.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Gutierrez, Claudio. Instituto de Química Física “Rocasolano”. Madrid; Argentina
Fil: Cuesta, Angel. Instituto de Química Física “Rocasolano”. Madrid; Argentina. University Of Aberdeen; Reino Unido
description The shift with increasing concentration of alkali-metal cations of the potentials of both the spike and the hump observed in the cyclic voltammograms of Pt(111) electrodes in sulfuric acid solutions is shown to obey the simple model recently developed by us to explain the effect of non-covalent interactions at the electrical double layer. The results suggest that the model, originally developed to describe the effect of alkali-metal cations on the cyclic voltammogram of cyanide-modified Pt(111) electrodes, is of general applicability and can explain quantitatively the effect of cations on the properties of the electrical double layer.
publishDate 2014
dc.date.none.fl_str_mv 2014-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/31349
Cabello, Gema; Leiva, Ezequiel Pedro M.; Gutierrez, Claudio; Cuesta, Angel; Non-covalent interactions at electrochemicalinterfaces: one model fits all?; Royal Society of Chemistry; Physical Chemistry Chemical Physics; 16; 5-2014; 14281-14286
1463-9076
CONICET Digital
CONICET
url http://hdl.handle.net/11336/31349
identifier_str_mv Cabello, Gema; Leiva, Ezequiel Pedro M.; Gutierrez, Claudio; Cuesta, Angel; Non-covalent interactions at electrochemicalinterfaces: one model fits all?; Royal Society of Chemistry; Physical Chemistry Chemical Physics; 16; 5-2014; 14281-14286
1463-9076
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1039/c3cp53354a
info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2014/CP/C3CP53354A
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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