Local and Extended-Order Evolution of Synthetic Talc during Hydrothermal Synthesis: Extended X-ray Absorption Fine Structure, X-ray Diffraction, and Fourier Transform Infrared Spec...

Autores: Dumas, Angela; Mizrahi, Martin Daniel; Martin, François; Requejo, Felix Gregorio
Año de publicación: 2015
Idioma: inglés
Tipo de recurso: artículo
Estado: versión publicada
Descripción: Synthetic talc is a newfiller of industrial interest due to its submicronsize, its chemical and mineral purity, and its hydrophilic character. To develop this filler on a preindustrial scale, this work aimed to understand the mechanisms of transformation from the amorphous talc precursor to crystalline synthetic talc. X-ray diffraction, Fourier transform infrared spectroscopy, and extended X-ray absorption fine structure at Ni−K edge techniques were used to study a Ni-talc series composed of a talc precursor sample and talc samples synthesized at 100, 200, and 300°C for 1 or 6 h. As soon as the Ni-talc precursor precipitated, a tetrahedral−octahedral−tetrahedral-type structure appeared that was characterized by 2−3 Ni-octahedra distanced 3.07 Å from each other and by 3−4 Si tetrahedra distributed on the top and bottom of the octahedral"sheet" and distanced 3.29 Å from Ni. Simultaneously following the synthesis temperature, the octahedral sheet grew, and the tetrahedral sheet expanded; the distances Ni−Ni and Ni−Si also gradually shortened. The intracrystalline distribution of the octahedral sheet was also studied. At 300 °C, a random distribution was obtained. Cluster distribution was not observed at low temperature, which we hypothesize is a function of crystallite size.
Fil: Dumas, Angela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Centre Nationale de la Ricerche Scientifique. Géociences Environnement Toulouse; Francia
Fil: Mizrahi, Martin Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina
Fil: Martin, François. Centre Nationale de la Ricerche Scientifique. Géociences Environnement Toulouse; Francia
Fil: Requejo, Felix Gregorio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina
Materia: Synthetic Talc
Exafs
Xrd
Ftir
Nivel de accesibilidad: acceso abierto
Condiciones de uso: https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
Institución: Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador: oai:ri.conicet.gov.ar:11336/5489

Acceder

id	CONICETDig_59f4b228aafe80186d388eaf6a98ae3f
oai_identifier_str	oai:ri.conicet.gov.ar:11336/5489
network_acronym_str	CONICETDig
repository_id_str	3498
network_name_str	CONICET Digital (CONICET)
spelling	Local and Extended-Order Evolution of Synthetic Talc during Hydrothermal Synthesis: Extended X-ray Absorption Fine Structure, X-ray Diffraction, and Fourier Transform Infrared Spectroscopy StudiesDumas, AngelaMizrahi, Martin DanielMartin, FrançoisRequejo, Felix GregorioSynthetic TalcExafsXrdFtirhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Synthetic talc is a newfiller of industrial interest due to its submicronsize, its chemical and mineral purity, and its hydrophilic character. To develop this filler on a preindustrial scale, this work aimed to understand the mechanisms of transformation from the amorphous talc precursor to crystalline synthetic talc. X-ray diffraction, Fourier transform infrared spectroscopy, and extended X-ray absorption fine structure at Ni−K edge techniques were used to study a Ni-talc series composed of a talc precursor sample and talc samples synthesized at 100, 200, and 300°C for 1 or 6 h. As soon as the Ni-talc precursor precipitated, a tetrahedral−octahedral−tetrahedral-type structure appeared that was characterized by 2−3 Ni-octahedra distanced 3.07 Å from each other and by 3−4 Si tetrahedra distributed on the top and bottom of the octahedral"sheet" and distanced 3.29 Å from Ni. Simultaneously following the synthesis temperature, the octahedral sheet grew, and the tetrahedral sheet expanded; the distances Ni−Ni and Ni−Si also gradually shortened. The intracrystalline distribution of the octahedral sheet was also studied. At 300 °C, a random distribution was obtained. Cluster distribution was not observed at low temperature, which we hypothesize is a function of crystallite size.Fil: Dumas, Angela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Centre Nationale de la Ricerche Scientifique. Géociences Environnement Toulouse; FranciaFil: Mizrahi, Martin Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; ArgentinaFil: Martin, François. Centre Nationale de la Ricerche Scientifique. Géociences Environnement Toulouse; FranciaFil: Requejo, Felix Gregorio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; ArgentinaAmerican Chemical Society2015-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5489Dumas, Angela; Mizrahi, Martin Daniel; Martin, François; Requejo, Felix Gregorio; Local and Extended-Order Evolution of Synthetic Talc during Hydrothermal Synthesis: Extended X-ray Absorption Fine Structure, X-ray Diffraction, and Fourier Transform Infrared Spectroscopy Studies; American Chemical Society; Crystal Growth & Design; 15; 11; 10-2015; 5451-54631528-7483enginfo:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/10.1021/acs.cgd.5b01076info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.cgd.5b01076info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:29:17Zoai:ri.conicet.gov.ar:11336/5489instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:29:17.372CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv	Local and Extended-Order Evolution of Synthetic Talc during Hydrothermal Synthesis: Extended X-ray Absorption Fine Structure, X-ray Diffraction, and Fourier Transform Infrared Spectroscopy Studies
title	Local and Extended-Order Evolution of Synthetic Talc during Hydrothermal Synthesis: Extended X-ray Absorption Fine Structure, X-ray Diffraction, and Fourier Transform Infrared Spectroscopy Studies
spellingShingle	Local and Extended-Order Evolution of Synthetic Talc during Hydrothermal Synthesis: Extended X-ray Absorption Fine Structure, X-ray Diffraction, and Fourier Transform Infrared Spectroscopy Studies Dumas, Angela Synthetic Talc Exafs Xrd Ftir
title_short	Local and Extended-Order Evolution of Synthetic Talc during Hydrothermal Synthesis: Extended X-ray Absorption Fine Structure, X-ray Diffraction, and Fourier Transform Infrared Spectroscopy Studies
title_full	Local and Extended-Order Evolution of Synthetic Talc during Hydrothermal Synthesis: Extended X-ray Absorption Fine Structure, X-ray Diffraction, and Fourier Transform Infrared Spectroscopy Studies
title_fullStr	Local and Extended-Order Evolution of Synthetic Talc during Hydrothermal Synthesis: Extended X-ray Absorption Fine Structure, X-ray Diffraction, and Fourier Transform Infrared Spectroscopy Studies
title_full_unstemmed	Local and Extended-Order Evolution of Synthetic Talc during Hydrothermal Synthesis: Extended X-ray Absorption Fine Structure, X-ray Diffraction, and Fourier Transform Infrared Spectroscopy Studies
title_sort	Local and Extended-Order Evolution of Synthetic Talc during Hydrothermal Synthesis: Extended X-ray Absorption Fine Structure, X-ray Diffraction, and Fourier Transform Infrared Spectroscopy Studies
dc.creator.none.fl_str_mv	Dumas, Angela Mizrahi, Martin Daniel Martin, François Requejo, Felix Gregorio
author	Dumas, Angela
author_facet	Dumas, Angela Mizrahi, Martin Daniel Martin, François Requejo, Felix Gregorio
author_role	author
author2	Mizrahi, Martin Daniel Martin, François Requejo, Felix Gregorio
author2_role	author author author
dc.subject.none.fl_str_mv	Synthetic Talc Exafs Xrd Ftir
topic	Synthetic Talc Exafs Xrd Ftir
purl_subject.fl_str_mv	https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv	Synthetic talc is a newfiller of industrial interest due to its submicronsize, its chemical and mineral purity, and its hydrophilic character. To develop this filler on a preindustrial scale, this work aimed to understand the mechanisms of transformation from the amorphous talc precursor to crystalline synthetic talc. X-ray diffraction, Fourier transform infrared spectroscopy, and extended X-ray absorption fine structure at Ni−K edge techniques were used to study a Ni-talc series composed of a talc precursor sample and talc samples synthesized at 100, 200, and 300°C for 1 or 6 h. As soon as the Ni-talc precursor precipitated, a tetrahedral−octahedral−tetrahedral-type structure appeared that was characterized by 2−3 Ni-octahedra distanced 3.07 Å from each other and by 3−4 Si tetrahedra distributed on the top and bottom of the octahedral"sheet" and distanced 3.29 Å from Ni. Simultaneously following the synthesis temperature, the octahedral sheet grew, and the tetrahedral sheet expanded; the distances Ni−Ni and Ni−Si also gradually shortened. The intracrystalline distribution of the octahedral sheet was also studied. At 300 °C, a random distribution was obtained. Cluster distribution was not observed at low temperature, which we hypothesize is a function of crystallite size. Fil: Dumas, Angela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Centre Nationale de la Ricerche Scientifique. Géociences Environnement Toulouse; Francia Fil: Mizrahi, Martin Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina Fil: Martin, François. Centre Nationale de la Ricerche Scientifique. Géociences Environnement Toulouse; Francia Fil: Requejo, Felix Gregorio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina
description	Synthetic talc is a newfiller of industrial interest due to its submicronsize, its chemical and mineral purity, and its hydrophilic character. To develop this filler on a preindustrial scale, this work aimed to understand the mechanisms of transformation from the amorphous talc precursor to crystalline synthetic talc. X-ray diffraction, Fourier transform infrared spectroscopy, and extended X-ray absorption fine structure at Ni−K edge techniques were used to study a Ni-talc series composed of a talc precursor sample and talc samples synthesized at 100, 200, and 300°C for 1 or 6 h. As soon as the Ni-talc precursor precipitated, a tetrahedral−octahedral−tetrahedral-type structure appeared that was characterized by 2−3 Ni-octahedra distanced 3.07 Å from each other and by 3−4 Si tetrahedra distributed on the top and bottom of the octahedral"sheet" and distanced 3.29 Å from Ni. Simultaneously following the synthesis temperature, the octahedral sheet grew, and the tetrahedral sheet expanded; the distances Ni−Ni and Ni−Si also gradually shortened. The intracrystalline distribution of the octahedral sheet was also studied. At 300 °C, a random distribution was obtained. Cluster distribution was not observed at low temperature, which we hypothesize is a function of crystallite size.
publishDate	2015
dc.date.none.fl_str_mv	2015-10
dc.type.none.fl_str_mv	info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo
format	article
status_str	publishedVersion
dc.identifier.none.fl_str_mv	http://hdl.handle.net/11336/5489 Dumas, Angela; Mizrahi, Martin Daniel; Martin, François; Requejo, Felix Gregorio; Local and Extended-Order Evolution of Synthetic Talc during Hydrothermal Synthesis: Extended X-ray Absorption Fine Structure, X-ray Diffraction, and Fourier Transform Infrared Spectroscopy Studies; American Chemical Society; Crystal Growth & Design; 15; 11; 10-2015; 5451-5463 1528-7483
url	http://hdl.handle.net/11336/5489
identifier_str_mv	Dumas, Angela; Mizrahi, Martin Daniel; Martin, François; Requejo, Felix Gregorio; Local and Extended-Order Evolution of Synthetic Talc during Hydrothermal Synthesis: Extended X-ray Absorption Fine Structure, X-ray Diffraction, and Fourier Transform Infrared Spectroscopy Studies; American Chemical Society; Crystal Growth & Design; 15; 11; 10-2015; 5451-5463 1528-7483
dc.language.none.fl_str_mv	eng
language	eng
dc.relation.none.fl_str_mv	info:eu-repo/semantics/altIdentifier/doi/ info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/10.1021/acs.cgd.5b01076 info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.cgd.5b01076
dc.rights.none.fl_str_mv	info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv	openAccess
rights_invalid_str_mv	https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv	application/pdf application/pdf
dc.publisher.none.fl_str_mv	American Chemical Society
publisher.none.fl_str_mv	American Chemical Society
dc.source.none.fl_str_mv	reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str	CONICET Digital (CONICET)
collection	CONICET Digital (CONICET)
instname_str	Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv	CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv	dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_	1844614298575306752
score	13.070432

Local and Extended-Order Evolution of Synthetic Talc during Hydrothermal Synthesis: Extended X-ray Absorption Fine Structure, X-ray Diffraction, and Fourier Transform Infrared Spec...

Publicaciones similares