Prediction of homogeneous azeotropes with interval analysis techniques exploiting topological considerations
- Autores
- Salomone, Hector Enrique; Espinosa, Hector Jose Maria
- Año de publicación
- 2001
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- In this paper, we present an efficient method for the prediction of homogeneous azeotropes. The method is an adaptation of a former method based on interval analysis techniques. An interval Newton with generalized bisection (IN/GB) technique is used to find all the roots of a set of equations representing the azeotropy condition. The novel contribution is to combine this robust technique with the Zharov - Serafimov topological index theory. By checking the topological consistency, it is possible to avoid the numerical verification of the nonexistence and therefore to reduce significantly the total computation time. In addition, a simplified model is selectively used at the first stage of the algorithm for providing good starting points for the second stage, where the full model is used for solution refining. In this way, more computation time is saved without compromising the reliability of the method. As a result, the performance of the method is comparable to the one of the fastest local methods.
Fil: Salomone, Hector Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo y Diseño. Universidad Tecnológica Nacional. Facultad Regional Santa Fe. Instituto de Desarrollo y Diseño; Argentina
Fil: Espinosa, Hector Jose Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo y Diseño. Universidad Tecnológica Nacional. Facultad Regional Santa Fe. Instituto de Desarrollo y Diseño; Argentina - Materia
-
AZEOTROPE COMPOSITION CALCULATION
INTERVAL MATHEMATICS
IN/GB
TOPOLOGICAL CONSISTENCY - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/186298
Ver los metadatos del registro completo
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Prediction of homogeneous azeotropes with interval analysis techniques exploiting topological considerationsSalomone, Hector EnriqueEspinosa, Hector Jose MariaAZEOTROPE COMPOSITION CALCULATIONINTERVAL MATHEMATICSIN/GBTOPOLOGICAL CONSISTENCYhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2In this paper, we present an efficient method for the prediction of homogeneous azeotropes. The method is an adaptation of a former method based on interval analysis techniques. An interval Newton with generalized bisection (IN/GB) technique is used to find all the roots of a set of equations representing the azeotropy condition. The novel contribution is to combine this robust technique with the Zharov - Serafimov topological index theory. By checking the topological consistency, it is possible to avoid the numerical verification of the nonexistence and therefore to reduce significantly the total computation time. In addition, a simplified model is selectively used at the first stage of the algorithm for providing good starting points for the second stage, where the full model is used for solution refining. In this way, more computation time is saved without compromising the reliability of the method. As a result, the performance of the method is comparable to the one of the fastest local methods.Fil: Salomone, Hector Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo y Diseño. Universidad Tecnológica Nacional. Facultad Regional Santa Fe. Instituto de Desarrollo y Diseño; ArgentinaFil: Espinosa, Hector Jose Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo y Diseño. Universidad Tecnológica Nacional. Facultad Regional Santa Fe. Instituto de Desarrollo y Diseño; ArgentinaAmerican Chemical Society2001-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/186298Salomone, Hector Enrique; Espinosa, Hector Jose Maria; Prediction of homogeneous azeotropes with interval analysis techniques exploiting topological considerations; American Chemical Society; Industrial & Engineering Chemical Research; 40; 6; 3-2001; 1580-15880888-5885CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/ie000608ginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ie000608ginfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:34:24Zoai:ri.conicet.gov.ar:11336/186298instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:34:24.894CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Prediction of homogeneous azeotropes with interval analysis techniques exploiting topological considerations |
title |
Prediction of homogeneous azeotropes with interval analysis techniques exploiting topological considerations |
spellingShingle |
Prediction of homogeneous azeotropes with interval analysis techniques exploiting topological considerations Salomone, Hector Enrique AZEOTROPE COMPOSITION CALCULATION INTERVAL MATHEMATICS IN/GB TOPOLOGICAL CONSISTENCY |
title_short |
Prediction of homogeneous azeotropes with interval analysis techniques exploiting topological considerations |
title_full |
Prediction of homogeneous azeotropes with interval analysis techniques exploiting topological considerations |
title_fullStr |
Prediction of homogeneous azeotropes with interval analysis techniques exploiting topological considerations |
title_full_unstemmed |
Prediction of homogeneous azeotropes with interval analysis techniques exploiting topological considerations |
title_sort |
Prediction of homogeneous azeotropes with interval analysis techniques exploiting topological considerations |
dc.creator.none.fl_str_mv |
Salomone, Hector Enrique Espinosa, Hector Jose Maria |
author |
Salomone, Hector Enrique |
author_facet |
Salomone, Hector Enrique Espinosa, Hector Jose Maria |
author_role |
author |
author2 |
Espinosa, Hector Jose Maria |
author2_role |
author |
dc.subject.none.fl_str_mv |
AZEOTROPE COMPOSITION CALCULATION INTERVAL MATHEMATICS IN/GB TOPOLOGICAL CONSISTENCY |
topic |
AZEOTROPE COMPOSITION CALCULATION INTERVAL MATHEMATICS IN/GB TOPOLOGICAL CONSISTENCY |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
In this paper, we present an efficient method for the prediction of homogeneous azeotropes. The method is an adaptation of a former method based on interval analysis techniques. An interval Newton with generalized bisection (IN/GB) technique is used to find all the roots of a set of equations representing the azeotropy condition. The novel contribution is to combine this robust technique with the Zharov - Serafimov topological index theory. By checking the topological consistency, it is possible to avoid the numerical verification of the nonexistence and therefore to reduce significantly the total computation time. In addition, a simplified model is selectively used at the first stage of the algorithm for providing good starting points for the second stage, where the full model is used for solution refining. In this way, more computation time is saved without compromising the reliability of the method. As a result, the performance of the method is comparable to the one of the fastest local methods. Fil: Salomone, Hector Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo y Diseño. Universidad Tecnológica Nacional. Facultad Regional Santa Fe. Instituto de Desarrollo y Diseño; Argentina Fil: Espinosa, Hector Jose Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo y Diseño. Universidad Tecnológica Nacional. Facultad Regional Santa Fe. Instituto de Desarrollo y Diseño; Argentina |
description |
In this paper, we present an efficient method for the prediction of homogeneous azeotropes. The method is an adaptation of a former method based on interval analysis techniques. An interval Newton with generalized bisection (IN/GB) technique is used to find all the roots of a set of equations representing the azeotropy condition. The novel contribution is to combine this robust technique with the Zharov - Serafimov topological index theory. By checking the topological consistency, it is possible to avoid the numerical verification of the nonexistence and therefore to reduce significantly the total computation time. In addition, a simplified model is selectively used at the first stage of the algorithm for providing good starting points for the second stage, where the full model is used for solution refining. In this way, more computation time is saved without compromising the reliability of the method. As a result, the performance of the method is comparable to the one of the fastest local methods. |
publishDate |
2001 |
dc.date.none.fl_str_mv |
2001-03 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/186298 Salomone, Hector Enrique; Espinosa, Hector Jose Maria; Prediction of homogeneous azeotropes with interval analysis techniques exploiting topological considerations; American Chemical Society; Industrial & Engineering Chemical Research; 40; 6; 3-2001; 1580-1588 0888-5885 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/186298 |
identifier_str_mv |
Salomone, Hector Enrique; Espinosa, Hector Jose Maria; Prediction of homogeneous azeotropes with interval analysis techniques exploiting topological considerations; American Chemical Society; Industrial & Engineering Chemical Research; 40; 6; 3-2001; 1580-1588 0888-5885 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/ie000608g info:eu-repo/semantics/altIdentifier/doi/10.1021/ie000608g |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
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reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) |
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CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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13.070432 |