Co-Rh modified natural zeolites as new catalytic materials to oxidize propane and naphthalene from emission sources

Autores
Leguizamón Aparicio, María Silvia del Valle; Canafoglia, Maria Elena; Ocsachoque, Marco Antonio; Lick, Ileana Daniela; Botto, Irma Lia
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Natural zeolites as a raw material to prepare catalytic precursors for the oxidation reaction of linear and poly-aromatic hydrocarbons are reported in this work. The process consisted in the formation of mono- and bi-metallic species containing Co and Co-Rh on natural zeolite tuffs. The materials are analyzed by different physicochemical techniques and used as catalysts for propane and naphthalene oxidation in emissions sources. Comparatively, Rh-zeolites are the most active catalysts for propane conversion. In this case, the formation of mixed oxides seems to be conditioned by surface properties. It could also be suggested that the Rh incorporation on a non-active phase in bimetallic catalysts impacts the effectiveness of the system. In addition, the NO presence increases the activity of bimetallic materials. Rh-Co zeolite systems markedly influence the naphthalene combustion temperature. Whereas in the absence of a catalyst a conversion rate of 50% and 100% is reached at 430 C and 485 °C, respectively. It is interesting to observe that for RhCoCli-Mor and RhCoCli catalyst the 100% conversion is reached at 250 °C.
Fil: Leguizamón Aparicio, María Silvia del Valle. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
Fil: Canafoglia, Maria Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Ocsachoque, Marco Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
Fil: Lick, Ileana Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Botto, Irma Lia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina
Materia
CATALYSIS
COBALT
HYDROCARBONS COMBUSTION
NATURAL ZEOLITES
RHODIUM
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/37969
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/37969
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Co-Rh modified natural zeolites as new catalytic materials to oxidize propane and naphthalene from emission sourcesLeguizamón Aparicio, María Silvia del ValleCanafoglia, Maria ElenaOcsachoque, Marco AntonioLick, Ileana DanielaBotto, Irma LiaCATALYSISCOBALTHYDROCARBONS COMBUSTIONNATURAL ZEOLITESRHODIUMhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Natural zeolites as a raw material to prepare catalytic precursors for the oxidation reaction of linear and poly-aromatic hydrocarbons are reported in this work. The process consisted in the formation of mono- and bi-metallic species containing Co and Co-Rh on natural zeolite tuffs. The materials are analyzed by different physicochemical techniques and used as catalysts for propane and naphthalene oxidation in emissions sources. Comparatively, Rh-zeolites are the most active catalysts for propane conversion. In this case, the formation of mixed oxides seems to be conditioned by surface properties. It could also be suggested that the Rh incorporation on a non-active phase in bimetallic catalysts impacts the effectiveness of the system. In addition, the NO presence increases the activity of bimetallic materials. Rh-Co zeolite systems markedly influence the naphthalene combustion temperature. Whereas in the absence of a catalyst a conversion rate of 50% and 100% is reached at 430 C and 485 °C, respectively. It is interesting to observe that for RhCoCli-Mor and RhCoCli catalyst the 100% conversion is reached at 250 °C.Fil: Leguizamón Aparicio, María Silvia del Valle. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; ArgentinaFil: Canafoglia, Maria Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Ocsachoque, Marco Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; ArgentinaFil: Lick, Ileana Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Botto, Irma Lia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; ArgentinaDe Gruyter2016-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/37969Leguizamón Aparicio, María Silvia del Valle; Canafoglia, Maria Elena; Ocsachoque, Marco Antonio; Lick, Ileana Daniela; Botto, Irma Lia; Co-Rh modified natural zeolites as new catalytic materials to oxidize propane and naphthalene from emission sources; De Gruyter; Open Chemistry; 14; 1; 1-2016; 335-3422391-5420CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1515/chem-2016-0036info:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/view/j/chem.2016.14.issue-1/chem-2016-0036/chem-2016-0036.xmlinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:11:43Zoai:ri.conicet.gov.ar:11336/37969instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:11:43.458CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Co-Rh modified natural zeolites as new catalytic materials to oxidize propane and naphthalene from emission sources
title Co-Rh modified natural zeolites as new catalytic materials to oxidize propane and naphthalene from emission sources
spellingShingle Co-Rh modified natural zeolites as new catalytic materials to oxidize propane and naphthalene from emission sources
Leguizamón Aparicio, María Silvia del Valle
CATALYSIS
COBALT
HYDROCARBONS COMBUSTION
NATURAL ZEOLITES
RHODIUM
title_short Co-Rh modified natural zeolites as new catalytic materials to oxidize propane and naphthalene from emission sources
title_full Co-Rh modified natural zeolites as new catalytic materials to oxidize propane and naphthalene from emission sources
title_fullStr Co-Rh modified natural zeolites as new catalytic materials to oxidize propane and naphthalene from emission sources
title_full_unstemmed Co-Rh modified natural zeolites as new catalytic materials to oxidize propane and naphthalene from emission sources
title_sort Co-Rh modified natural zeolites as new catalytic materials to oxidize propane and naphthalene from emission sources
dc.creator.none.fl_str_mv Leguizamón Aparicio, María Silvia del Valle
Canafoglia, Maria Elena
Ocsachoque, Marco Antonio
Lick, Ileana Daniela
Botto, Irma Lia
author Leguizamón Aparicio, María Silvia del Valle
author_facet Leguizamón Aparicio, María Silvia del Valle
Canafoglia, Maria Elena
Ocsachoque, Marco Antonio
Lick, Ileana Daniela
Botto, Irma Lia
author_role author
author2 Canafoglia, Maria Elena
Ocsachoque, Marco Antonio
Lick, Ileana Daniela
Botto, Irma Lia
author2_role author
author
author
author
dc.subject.none.fl_str_mv CATALYSIS
COBALT
HYDROCARBONS COMBUSTION
NATURAL ZEOLITES
RHODIUM
topic CATALYSIS
COBALT
HYDROCARBONS COMBUSTION
NATURAL ZEOLITES
RHODIUM
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Natural zeolites as a raw material to prepare catalytic precursors for the oxidation reaction of linear and poly-aromatic hydrocarbons are reported in this work. The process consisted in the formation of mono- and bi-metallic species containing Co and Co-Rh on natural zeolite tuffs. The materials are analyzed by different physicochemical techniques and used as catalysts for propane and naphthalene oxidation in emissions sources. Comparatively, Rh-zeolites are the most active catalysts for propane conversion. In this case, the formation of mixed oxides seems to be conditioned by surface properties. It could also be suggested that the Rh incorporation on a non-active phase in bimetallic catalysts impacts the effectiveness of the system. In addition, the NO presence increases the activity of bimetallic materials. Rh-Co zeolite systems markedly influence the naphthalene combustion temperature. Whereas in the absence of a catalyst a conversion rate of 50% and 100% is reached at 430 C and 485 °C, respectively. It is interesting to observe that for RhCoCli-Mor and RhCoCli catalyst the 100% conversion is reached at 250 °C.
Fil: Leguizamón Aparicio, María Silvia del Valle. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
Fil: Canafoglia, Maria Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Ocsachoque, Marco Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
Fil: Lick, Ileana Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Botto, Irma Lia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina
description Natural zeolites as a raw material to prepare catalytic precursors for the oxidation reaction of linear and poly-aromatic hydrocarbons are reported in this work. The process consisted in the formation of mono- and bi-metallic species containing Co and Co-Rh on natural zeolite tuffs. The materials are analyzed by different physicochemical techniques and used as catalysts for propane and naphthalene oxidation in emissions sources. Comparatively, Rh-zeolites are the most active catalysts for propane conversion. In this case, the formation of mixed oxides seems to be conditioned by surface properties. It could also be suggested that the Rh incorporation on a non-active phase in bimetallic catalysts impacts the effectiveness of the system. In addition, the NO presence increases the activity of bimetallic materials. Rh-Co zeolite systems markedly influence the naphthalene combustion temperature. Whereas in the absence of a catalyst a conversion rate of 50% and 100% is reached at 430 C and 485 °C, respectively. It is interesting to observe that for RhCoCli-Mor and RhCoCli catalyst the 100% conversion is reached at 250 °C.
publishDate 2016
dc.date.none.fl_str_mv 2016-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/37969
Leguizamón Aparicio, María Silvia del Valle; Canafoglia, Maria Elena; Ocsachoque, Marco Antonio; Lick, Ileana Daniela; Botto, Irma Lia; Co-Rh modified natural zeolites as new catalytic materials to oxidize propane and naphthalene from emission sources; De Gruyter; Open Chemistry; 14; 1; 1-2016; 335-342
2391-5420
CONICET Digital
CONICET
url http://hdl.handle.net/11336/37969
identifier_str_mv Leguizamón Aparicio, María Silvia del Valle; Canafoglia, Maria Elena; Ocsachoque, Marco Antonio; Lick, Ileana Daniela; Botto, Irma Lia; Co-Rh modified natural zeolites as new catalytic materials to oxidize propane and naphthalene from emission sources; De Gruyter; Open Chemistry; 14; 1; 1-2016; 335-342
2391-5420
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1515/chem-2016-0036
info:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/view/j/chem.2016.14.issue-1/chem-2016-0036/chem-2016-0036.xml
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv De Gruyter
publisher.none.fl_str_mv De Gruyter
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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