Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation

Autores
Calandra, Julia; Postigo, Jose Alberto; Russo, Diana; Sbarbati Nudelman, Norma; Tereñas, Juan José
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The classical radical-based hydrosilylation reaction of organic compounds bearing C[BOND]C multiple bonds is usually carried out in organic solvents and is herein presented in water with both hydrophobic and hydrophilic substrates. Thermal and photochemical initiations are used to accomplish the radical-induced hydrosilylation reaction of C[BOND]C multiple bonds in water with tris(trimethylsilyl)silane ((Me3Si)3SiH). Photochemical radical initiation in the absence of a chemical radical precursor other than the silane is found to be a very efficient and convenient method to induce the hydrosilylation reaction of C[BOND]C multiple bonds of organic compounds with (Me3Si)3SiH in water. This new alternate radical-based methodology studied in water is confronted with the classical radical thermal initiation of hydrosilylation reactions triggered through the thermal decomposition of azo compounds.
Fil: Calandra, Julia. Universidad de Belgrano; Argentina
Fil: Postigo, Jose Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Belgrano; Argentina
Fil: Russo, Diana . Universidad de Belgrano; Argentina
Fil: Sbarbati Nudelman, Norma. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina
Fil: Tereñas, Juan José. Universidad de Belgrano; Argentina
Materia
Photochemical Initiation
Radical Reactions in Water
Silyl Radicals
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/14270
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiationCalandra, JuliaPostigo, Jose AlbertoRusso, Diana Sbarbati Nudelman, NormaTereñas, Juan JoséPhotochemical InitiationRadical Reactions in WaterSilyl Radicalshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The classical radical-based hydrosilylation reaction of organic compounds bearing C[BOND]C multiple bonds is usually carried out in organic solvents and is herein presented in water with both hydrophobic and hydrophilic substrates. Thermal and photochemical initiations are used to accomplish the radical-induced hydrosilylation reaction of C[BOND]C multiple bonds in water with tris(trimethylsilyl)silane ((Me3Si)3SiH). Photochemical radical initiation in the absence of a chemical radical precursor other than the silane is found to be a very efficient and convenient method to induce the hydrosilylation reaction of C[BOND]C multiple bonds of organic compounds with (Me3Si)3SiH in water. This new alternate radical-based methodology studied in water is confronted with the classical radical thermal initiation of hydrosilylation reactions triggered through the thermal decomposition of azo compounds.Fil: Calandra, Julia. Universidad de Belgrano; ArgentinaFil: Postigo, Jose Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Belgrano; ArgentinaFil: Russo, Diana . Universidad de Belgrano; ArgentinaFil: Sbarbati Nudelman, Norma. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; ArgentinaFil: Tereñas, Juan José. Universidad de Belgrano; ArgentinaWiley2010-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/14270Calandra, Julia; Postigo, Jose Alberto; Russo, Diana ; Sbarbati Nudelman, Norma; Tereñas, Juan José; Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation; Wiley; Journal Of Physical Organic Chemistry; 23; 10; 10-2010; 944-9490894-32301099-1395enginfo:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/poc.1732/abstractinfo:eu-repo/semantics/altIdentifier/doi/10.1002/poc.1732info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:09:55Zoai:ri.conicet.gov.ar:11336/14270instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:09:55.303CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation
title Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation
spellingShingle Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation
Calandra, Julia
Photochemical Initiation
Radical Reactions in Water
Silyl Radicals
title_short Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation
title_full Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation
title_fullStr Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation
title_full_unstemmed Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation
title_sort Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation
dc.creator.none.fl_str_mv Calandra, Julia
Postigo, Jose Alberto
Russo, Diana
Sbarbati Nudelman, Norma
Tereñas, Juan José
author Calandra, Julia
author_facet Calandra, Julia
Postigo, Jose Alberto
Russo, Diana
Sbarbati Nudelman, Norma
Tereñas, Juan José
author_role author
author2 Postigo, Jose Alberto
Russo, Diana
Sbarbati Nudelman, Norma
Tereñas, Juan José
author2_role author
author
author
author
dc.subject.none.fl_str_mv Photochemical Initiation
Radical Reactions in Water
Silyl Radicals
topic Photochemical Initiation
Radical Reactions in Water
Silyl Radicals
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The classical radical-based hydrosilylation reaction of organic compounds bearing C[BOND]C multiple bonds is usually carried out in organic solvents and is herein presented in water with both hydrophobic and hydrophilic substrates. Thermal and photochemical initiations are used to accomplish the radical-induced hydrosilylation reaction of C[BOND]C multiple bonds in water with tris(trimethylsilyl)silane ((Me3Si)3SiH). Photochemical radical initiation in the absence of a chemical radical precursor other than the silane is found to be a very efficient and convenient method to induce the hydrosilylation reaction of C[BOND]C multiple bonds of organic compounds with (Me3Si)3SiH in water. This new alternate radical-based methodology studied in water is confronted with the classical radical thermal initiation of hydrosilylation reactions triggered through the thermal decomposition of azo compounds.
Fil: Calandra, Julia. Universidad de Belgrano; Argentina
Fil: Postigo, Jose Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Belgrano; Argentina
Fil: Russo, Diana . Universidad de Belgrano; Argentina
Fil: Sbarbati Nudelman, Norma. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina
Fil: Tereñas, Juan José. Universidad de Belgrano; Argentina
description The classical radical-based hydrosilylation reaction of organic compounds bearing C[BOND]C multiple bonds is usually carried out in organic solvents and is herein presented in water with both hydrophobic and hydrophilic substrates. Thermal and photochemical initiations are used to accomplish the radical-induced hydrosilylation reaction of C[BOND]C multiple bonds in water with tris(trimethylsilyl)silane ((Me3Si)3SiH). Photochemical radical initiation in the absence of a chemical radical precursor other than the silane is found to be a very efficient and convenient method to induce the hydrosilylation reaction of C[BOND]C multiple bonds of organic compounds with (Me3Si)3SiH in water. This new alternate radical-based methodology studied in water is confronted with the classical radical thermal initiation of hydrosilylation reactions triggered through the thermal decomposition of azo compounds.
publishDate 2010
dc.date.none.fl_str_mv 2010-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/14270
Calandra, Julia; Postigo, Jose Alberto; Russo, Diana ; Sbarbati Nudelman, Norma; Tereñas, Juan José; Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation; Wiley; Journal Of Physical Organic Chemistry; 23; 10; 10-2010; 944-949
0894-3230
1099-1395
url http://hdl.handle.net/11336/14270
identifier_str_mv Calandra, Julia; Postigo, Jose Alberto; Russo, Diana ; Sbarbati Nudelman, Norma; Tereñas, Juan José; Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation; Wiley; Journal Of Physical Organic Chemistry; 23; 10; 10-2010; 944-949
0894-3230
1099-1395
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/poc.1732/abstract
info:eu-repo/semantics/altIdentifier/doi/10.1002/poc.1732
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.993085

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