Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion

Autores
Harvey, Miguel Angel; Suarez, Sebastian; Zolotarev, Pavel N.; Proserpio, Davide M.; Baggio, Ricardo Fortunato
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A nickel(II) coordination complex, bis[2,6-bis(1H-benzimidazol-2-yl-κN3)pyridine-κN]nickel(II) sulfate, [Ni(C19H13N5)2]SO4 or [Ni(H2L)2]SO4, having four peripheral tetrahedrally oriented N - H donor units, combines with sulfate bridges to create hydrogen-bonded structures of varied dimensionality. The three crystal structures reported herein in the space groups P212121, I and Pccn are defined solely by strong charge-assisted N - H...O hydrogen bonds and contain disordered guests (water and dimethylformamide) that vary in size, shape and degree of hydrophilicity. Two of the compounds are channelled solids with three-dimensional structures, while the third is one-dimensional in nature. In spite of their differences, all three present a striking resemblance to the previously reported anhydrous relative [Guo et al. (2011). Chin. J. Inorg. Chem.27, 1517-1520], which is considered as the reference framework from which all three title compounds are derived. The hydrogen-bonded frameworks are described and compared using crystallographic and topological approaches.
Fil: Harvey, Miguel Angel. Universidad Nacional de la Patagonia "San Juan Bosco"; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Centro Nacional Patagónico; Argentina
Fil: Suarez, Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Zolotarev, Pavel N.. Samara State Technical University; Rusia
Fil: Proserpio, Davide M.. Samara State Technical University; Rusia. Università degli Studi di Milano; Italia
Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Materia
CRYSTAL STRUCTURE
HYDROGEN-BONDED POROUS STRUCTURES
SULFATE BRIDGE
TOPOLOGICAL ANALYSIS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/88637
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/88637
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anionHarvey, Miguel AngelSuarez, SebastianZolotarev, Pavel N.Proserpio, Davide M.Baggio, Ricardo FortunatoCRYSTAL STRUCTUREHYDROGEN-BONDED POROUS STRUCTURESSULFATE BRIDGETOPOLOGICAL ANALYSIShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A nickel(II) coordination complex, bis[2,6-bis(1H-benzimidazol-2-yl-κN3)pyridine-κN]nickel(II) sulfate, [Ni(C19H13N5)2]SO4 or [Ni(H2L)2]SO4, having four peripheral tetrahedrally oriented N - H donor units, combines with sulfate bridges to create hydrogen-bonded structures of varied dimensionality. The three crystal structures reported herein in the space groups P212121, I and Pccn are defined solely by strong charge-assisted N - H...O hydrogen bonds and contain disordered guests (water and dimethylformamide) that vary in size, shape and degree of hydrophilicity. Two of the compounds are channelled solids with three-dimensional structures, while the third is one-dimensional in nature. In spite of their differences, all three present a striking resemblance to the previously reported anhydrous relative [Guo et al. (2011). Chin. J. Inorg. Chem.27, 1517-1520], which is considered as the reference framework from which all three title compounds are derived. The hydrogen-bonded frameworks are described and compared using crystallographic and topological approaches.Fil: Harvey, Miguel Angel. Universidad Nacional de la Patagonia "San Juan Bosco"; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Centro Nacional Patagónico; ArgentinaFil: Suarez, Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Zolotarev, Pavel N.. Samara State Technical University; RusiaFil: Proserpio, Davide M.. Samara State Technical University; Rusia. Università degli Studi di Milano; ItaliaFil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; ArgentinaWiley Blackwell Publishing, Inc2018-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/88637Harvey, Miguel Angel; Suarez, Sebastian; Zolotarev, Pavel N.; Proserpio, Davide M.; Baggio, Ricardo Fortunato; Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C: Structural Chemistry; 74; 3; 3-2018; 351-3592053-2296CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1107/S2053229618002413info:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S2053229618002413info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-12-23T13:39:08Zoai:ri.conicet.gov.ar:11336/88637instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-12-23 13:39:08.32CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion
title Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion
spellingShingle Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion
Harvey, Miguel Angel
CRYSTAL STRUCTURE
HYDROGEN-BONDED POROUS STRUCTURES
SULFATE BRIDGE
TOPOLOGICAL ANALYSIS
title_short Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion
title_full Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion
title_fullStr Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion
title_full_unstemmed Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion
title_sort Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion
dc.creator.none.fl_str_mv Harvey, Miguel Angel
Suarez, Sebastian
Zolotarev, Pavel N.
Proserpio, Davide M.
Baggio, Ricardo Fortunato
author Harvey, Miguel Angel
author_facet Harvey, Miguel Angel
Suarez, Sebastian
Zolotarev, Pavel N.
Proserpio, Davide M.
Baggio, Ricardo Fortunato
author_role author
author2 Suarez, Sebastian
Zolotarev, Pavel N.
Proserpio, Davide M.
Baggio, Ricardo Fortunato
author2_role author
author
author
author
dc.subject.none.fl_str_mv CRYSTAL STRUCTURE
HYDROGEN-BONDED POROUS STRUCTURES
SULFATE BRIDGE
TOPOLOGICAL ANALYSIS
topic CRYSTAL STRUCTURE
HYDROGEN-BONDED POROUS STRUCTURES
SULFATE BRIDGE
TOPOLOGICAL ANALYSIS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A nickel(II) coordination complex, bis[2,6-bis(1H-benzimidazol-2-yl-κN3)pyridine-κN]nickel(II) sulfate, [Ni(C19H13N5)2]SO4 or [Ni(H2L)2]SO4, having four peripheral tetrahedrally oriented N - H donor units, combines with sulfate bridges to create hydrogen-bonded structures of varied dimensionality. The three crystal structures reported herein in the space groups P212121, I and Pccn are defined solely by strong charge-assisted N - H...O hydrogen bonds and contain disordered guests (water and dimethylformamide) that vary in size, shape and degree of hydrophilicity. Two of the compounds are channelled solids with three-dimensional structures, while the third is one-dimensional in nature. In spite of their differences, all three present a striking resemblance to the previously reported anhydrous relative [Guo et al. (2011). Chin. J. Inorg. Chem.27, 1517-1520], which is considered as the reference framework from which all three title compounds are derived. The hydrogen-bonded frameworks are described and compared using crystallographic and topological approaches.
Fil: Harvey, Miguel Angel. Universidad Nacional de la Patagonia "San Juan Bosco"; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Centro Nacional Patagónico; Argentina
Fil: Suarez, Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Zolotarev, Pavel N.. Samara State Technical University; Rusia
Fil: Proserpio, Davide M.. Samara State Technical University; Rusia. Università degli Studi di Milano; Italia
Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
description A nickel(II) coordination complex, bis[2,6-bis(1H-benzimidazol-2-yl-κN3)pyridine-κN]nickel(II) sulfate, [Ni(C19H13N5)2]SO4 or [Ni(H2L)2]SO4, having four peripheral tetrahedrally oriented N - H donor units, combines with sulfate bridges to create hydrogen-bonded structures of varied dimensionality. The three crystal structures reported herein in the space groups P212121, I and Pccn are defined solely by strong charge-assisted N - H...O hydrogen bonds and contain disordered guests (water and dimethylformamide) that vary in size, shape and degree of hydrophilicity. Two of the compounds are channelled solids with three-dimensional structures, while the third is one-dimensional in nature. In spite of their differences, all three present a striking resemblance to the previously reported anhydrous relative [Guo et al. (2011). Chin. J. Inorg. Chem.27, 1517-1520], which is considered as the reference framework from which all three title compounds are derived. The hydrogen-bonded frameworks are described and compared using crystallographic and topological approaches.
publishDate 2018
dc.date.none.fl_str_mv 2018-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/88637
Harvey, Miguel Angel; Suarez, Sebastian; Zolotarev, Pavel N.; Proserpio, Davide M.; Baggio, Ricardo Fortunato; Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C: Structural Chemistry; 74; 3; 3-2018; 351-359
2053-2296
CONICET Digital
CONICET
url http://hdl.handle.net/11336/88637
identifier_str_mv Harvey, Miguel Angel; Suarez, Sebastian; Zolotarev, Pavel N.; Proserpio, Davide M.; Baggio, Ricardo Fortunato; Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C: Structural Chemistry; 74; 3; 3-2018; 351-359
2053-2296
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1107/S2053229618002413
info:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S2053229618002413
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley Blackwell Publishing, Inc
publisher.none.fl_str_mv Wiley Blackwell Publishing, Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.952241

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