Heat-induced changes in dairy products containing sucrose
- Autores
- Rozycki, Sergio Darío; Buera, Maria del Pilar; Pauletti, Miguel Sebastian
- Año de publicación
- 2010
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The aim of the present work was to analyse the influence of the variables reaction temperature, casein-sucrose ratio and pH, on the kinetic parameters of gelation reactions, the gelation time and the functionality of casein micelles in concentrated milk systems containing sucrose. Global constant rate reaction order of gelation and were calculated, the first varying between four different orders of magnitude and the second between 1 and 7. Mathematical models allowing the prediction of gelation time with a good fit (r2 > 0.94) were obtained. Activation energy (Ea) for gelation decreased as pH decreased. In presence of sucrose, Ea values showed a higher temperature dependence. Gel functionality showed to be pH independent. Although the kinetic aspects of the reactions were affected by pH, the thermodynamic ones remained almost unchanged. Aggregation and gelation were very fast at pH 6. When comparing gelation kinetics with those corresponding to fluorescence and colour development, gelation showed to be produced much earlier than the latter two phenomena.
Fil: Rozycki, Sergio Darío. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología de los Alimentos; Argentina
Fil: Buera, Maria del Pilar. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Pauletti, Miguel Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología de los Alimentos; Argentina - Materia
-
COLOUR
CONCENTRATED MILK
FLUORESCENCE
KINETICS
THERMAL GELATION - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/98639
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Heat-induced changes in dairy products containing sucroseRozycki, Sergio DaríoBuera, Maria del PilarPauletti, Miguel SebastianCOLOURCONCENTRATED MILKFLUORESCENCEKINETICSTHERMAL GELATIONhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2https://purl.org/becyt/ford/4.2https://purl.org/becyt/ford/4https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The aim of the present work was to analyse the influence of the variables reaction temperature, casein-sucrose ratio and pH, on the kinetic parameters of gelation reactions, the gelation time and the functionality of casein micelles in concentrated milk systems containing sucrose. Global constant rate reaction order of gelation and were calculated, the first varying between four different orders of magnitude and the second between 1 and 7. Mathematical models allowing the prediction of gelation time with a good fit (r2 > 0.94) were obtained. Activation energy (Ea) for gelation decreased as pH decreased. In presence of sucrose, Ea values showed a higher temperature dependence. Gel functionality showed to be pH independent. Although the kinetic aspects of the reactions were affected by pH, the thermodynamic ones remained almost unchanged. Aggregation and gelation were very fast at pH 6. When comparing gelation kinetics with those corresponding to fluorescence and colour development, gelation showed to be produced much earlier than the latter two phenomena.Fil: Rozycki, Sergio Darío. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología de los Alimentos; ArgentinaFil: Buera, Maria del Pilar. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Pauletti, Miguel Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología de los Alimentos; ArgentinaElsevier2010-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/98639Rozycki, Sergio Darío; Buera, Maria del Pilar; Pauletti, Miguel Sebastian; Heat-induced changes in dairy products containing sucrose; Elsevier; Food Chemistry; 118; 1; 1-2010; 67-730308-8146CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0308814609005408?via%3Dihubinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.foodchem.2009.04.096info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:49:03Zoai:ri.conicet.gov.ar:11336/98639instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:49:03.91CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Heat-induced changes in dairy products containing sucrose |
title |
Heat-induced changes in dairy products containing sucrose |
spellingShingle |
Heat-induced changes in dairy products containing sucrose Rozycki, Sergio Darío COLOUR CONCENTRATED MILK FLUORESCENCE KINETICS THERMAL GELATION |
title_short |
Heat-induced changes in dairy products containing sucrose |
title_full |
Heat-induced changes in dairy products containing sucrose |
title_fullStr |
Heat-induced changes in dairy products containing sucrose |
title_full_unstemmed |
Heat-induced changes in dairy products containing sucrose |
title_sort |
Heat-induced changes in dairy products containing sucrose |
dc.creator.none.fl_str_mv |
Rozycki, Sergio Darío Buera, Maria del Pilar Pauletti, Miguel Sebastian |
author |
Rozycki, Sergio Darío |
author_facet |
Rozycki, Sergio Darío Buera, Maria del Pilar Pauletti, Miguel Sebastian |
author_role |
author |
author2 |
Buera, Maria del Pilar Pauletti, Miguel Sebastian |
author2_role |
author author |
dc.subject.none.fl_str_mv |
COLOUR CONCENTRATED MILK FLUORESCENCE KINETICS THERMAL GELATION |
topic |
COLOUR CONCENTRATED MILK FLUORESCENCE KINETICS THERMAL GELATION |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 https://purl.org/becyt/ford/4.2 https://purl.org/becyt/ford/4 https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The aim of the present work was to analyse the influence of the variables reaction temperature, casein-sucrose ratio and pH, on the kinetic parameters of gelation reactions, the gelation time and the functionality of casein micelles in concentrated milk systems containing sucrose. Global constant rate reaction order of gelation and were calculated, the first varying between four different orders of magnitude and the second between 1 and 7. Mathematical models allowing the prediction of gelation time with a good fit (r2 > 0.94) were obtained. Activation energy (Ea) for gelation decreased as pH decreased. In presence of sucrose, Ea values showed a higher temperature dependence. Gel functionality showed to be pH independent. Although the kinetic aspects of the reactions were affected by pH, the thermodynamic ones remained almost unchanged. Aggregation and gelation were very fast at pH 6. When comparing gelation kinetics with those corresponding to fluorescence and colour development, gelation showed to be produced much earlier than the latter two phenomena. Fil: Rozycki, Sergio Darío. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología de los Alimentos; Argentina Fil: Buera, Maria del Pilar. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Pauletti, Miguel Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología de los Alimentos; Argentina |
description |
The aim of the present work was to analyse the influence of the variables reaction temperature, casein-sucrose ratio and pH, on the kinetic parameters of gelation reactions, the gelation time and the functionality of casein micelles in concentrated milk systems containing sucrose. Global constant rate reaction order of gelation and were calculated, the first varying between four different orders of magnitude and the second between 1 and 7. Mathematical models allowing the prediction of gelation time with a good fit (r2 > 0.94) were obtained. Activation energy (Ea) for gelation decreased as pH decreased. In presence of sucrose, Ea values showed a higher temperature dependence. Gel functionality showed to be pH independent. Although the kinetic aspects of the reactions were affected by pH, the thermodynamic ones remained almost unchanged. Aggregation and gelation were very fast at pH 6. When comparing gelation kinetics with those corresponding to fluorescence and colour development, gelation showed to be produced much earlier than the latter two phenomena. |
publishDate |
2010 |
dc.date.none.fl_str_mv |
2010-01 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/98639 Rozycki, Sergio Darío; Buera, Maria del Pilar; Pauletti, Miguel Sebastian; Heat-induced changes in dairy products containing sucrose; Elsevier; Food Chemistry; 118; 1; 1-2010; 67-73 0308-8146 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/98639 |
identifier_str_mv |
Rozycki, Sergio Darío; Buera, Maria del Pilar; Pauletti, Miguel Sebastian; Heat-induced changes in dairy products containing sucrose; Elsevier; Food Chemistry; 118; 1; 1-2010; 67-73 0308-8146 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0308814609005408?via%3Dihub info:eu-repo/semantics/altIdentifier/doi/10.1016/j.foodchem.2009.04.096 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613520515137536 |
score |
13.070432 |