On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production

Autores
Flores, Hugo Alejandro; Fasce, Laura Alejandra; Riccardi, Carmen Cristina
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Aiming to determine a suitable model to describe the curing kinetics of a commercial epoxy/anhydride initiated by a quaternary amine system used for the production of glass reinforced pipes, calorimetric and infrared spectroscopic kinetics data were collected. Several phenomenological, isoconversional and mechanistics kinetics models were revisited and tried. In addition, the time-temperature-transformation diagram, which is fundamental for the design of curing cycles, was assessed from calorimetric and gel time experiments. It was found that the Kamal´s model and a mechanistic model comprising an activation reversible step followed by a propagation step (Mauri et al., 1997) were capable to well describe all the experimental data. The kinetics mechanism appeared to be independent of the initiator concentration as suggested by the constancy of the apparent activation energy obtained by the Kissinger´s method. According to the mechanistic model, the activation step resulted independent on initiator concentration while propagation rate accelerated with increasing it. The presence of glass fiber reinforcement did no affect the curing kinetics of the studied reactive system.
Fil: Flores, Hugo Alejandro. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
Fil: Fasce, Laura Alejandra. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
Fil: Riccardi, Carmen Cristina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
Materia
ANHYDRIDE
DSC
EPOXY
FTIR
KINETICS
MECHANISTIC MODEL
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/2935
Acceder
id CONICETDig_565974efa640179388bf3afc51009ac5
oai_identifier_str oai:ri.conicet.gov.ar:11336/2935
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe productionFlores, Hugo AlejandroFasce, Laura AlejandraRiccardi, Carmen CristinaANHYDRIDEDSCEPOXYFTIRKINETICSMECHANISTIC MODELhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Aiming to determine a suitable model to describe the curing kinetics of a commercial epoxy/anhydride initiated by a quaternary amine system used for the production of glass reinforced pipes, calorimetric and infrared spectroscopic kinetics data were collected. Several phenomenological, isoconversional and mechanistics kinetics models were revisited and tried. In addition, the time-temperature-transformation diagram, which is fundamental for the design of curing cycles, was assessed from calorimetric and gel time experiments. It was found that the Kamal´s model and a mechanistic model comprising an activation reversible step followed by a propagation step (Mauri et al., 1997) were capable to well describe all the experimental data. The kinetics mechanism appeared to be independent of the initiator concentration as suggested by the constancy of the apparent activation energy obtained by the Kissinger´s method. According to the mechanistic model, the activation step resulted independent on initiator concentration while propagation rate accelerated with increasing it. The presence of glass fiber reinforcement did no affect the curing kinetics of the studied reactive system.Fil: Flores, Hugo Alejandro. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); ArgentinaFil: Fasce, Laura Alejandra. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); ArgentinaFil: Riccardi, Carmen Cristina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); ArgentinaElsevier Science2013-10-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/2935Flores, Hugo Alejandro; Fasce, Laura Alejandra; Riccardi, Carmen Cristina; On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production; Elsevier Science; Thermochimica Acta; 573; 8-10-2013; 1-90040-6031enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0040603113004681info:eu-repo/semantics/altIdentifier/doi/10.1016/j.tca.2013.09.004info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:48:12Zoai:ri.conicet.gov.ar:11336/2935instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:48:12.568CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production
title On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production
spellingShingle On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production
Flores, Hugo Alejandro
ANHYDRIDE
DSC
EPOXY
FTIR
KINETICS
MECHANISTIC MODEL
title_short On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production
title_full On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production
title_fullStr On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production
title_full_unstemmed On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production
title_sort On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production
dc.creator.none.fl_str_mv Flores, Hugo Alejandro
Fasce, Laura Alejandra
Riccardi, Carmen Cristina
author Flores, Hugo Alejandro
author_facet Flores, Hugo Alejandro
Fasce, Laura Alejandra
Riccardi, Carmen Cristina
author_role author
author2 Fasce, Laura Alejandra
Riccardi, Carmen Cristina
author2_role author
author
dc.subject.none.fl_str_mv ANHYDRIDE
DSC
EPOXY
FTIR
KINETICS
MECHANISTIC MODEL
topic ANHYDRIDE
DSC
EPOXY
FTIR
KINETICS
MECHANISTIC MODEL
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Aiming to determine a suitable model to describe the curing kinetics of a commercial epoxy/anhydride initiated by a quaternary amine system used for the production of glass reinforced pipes, calorimetric and infrared spectroscopic kinetics data were collected. Several phenomenological, isoconversional and mechanistics kinetics models were revisited and tried. In addition, the time-temperature-transformation diagram, which is fundamental for the design of curing cycles, was assessed from calorimetric and gel time experiments. It was found that the Kamal´s model and a mechanistic model comprising an activation reversible step followed by a propagation step (Mauri et al., 1997) were capable to well describe all the experimental data. The kinetics mechanism appeared to be independent of the initiator concentration as suggested by the constancy of the apparent activation energy obtained by the Kissinger´s method. According to the mechanistic model, the activation step resulted independent on initiator concentration while propagation rate accelerated with increasing it. The presence of glass fiber reinforcement did no affect the curing kinetics of the studied reactive system.
Fil: Flores, Hugo Alejandro. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
Fil: Fasce, Laura Alejandra. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
Fil: Riccardi, Carmen Cristina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
description Aiming to determine a suitable model to describe the curing kinetics of a commercial epoxy/anhydride initiated by a quaternary amine system used for the production of glass reinforced pipes, calorimetric and infrared spectroscopic kinetics data were collected. Several phenomenological, isoconversional and mechanistics kinetics models were revisited and tried. In addition, the time-temperature-transformation diagram, which is fundamental for the design of curing cycles, was assessed from calorimetric and gel time experiments. It was found that the Kamal´s model and a mechanistic model comprising an activation reversible step followed by a propagation step (Mauri et al., 1997) were capable to well describe all the experimental data. The kinetics mechanism appeared to be independent of the initiator concentration as suggested by the constancy of the apparent activation energy obtained by the Kissinger´s method. According to the mechanistic model, the activation step resulted independent on initiator concentration while propagation rate accelerated with increasing it. The presence of glass fiber reinforcement did no affect the curing kinetics of the studied reactive system.
publishDate 2013
dc.date.none.fl_str_mv 2013-10-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/2935
Flores, Hugo Alejandro; Fasce, Laura Alejandra; Riccardi, Carmen Cristina; On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production; Elsevier Science; Thermochimica Acta; 573; 8-10-2013; 1-9
0040-6031
url http://hdl.handle.net/11336/2935
identifier_str_mv Flores, Hugo Alejandro; Fasce, Laura Alejandra; Riccardi, Carmen Cristina; On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production; Elsevier Science; Thermochimica Acta; 573; 8-10-2013; 1-9
0040-6031
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0040603113004681
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.tca.2013.09.004
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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