On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production
- Autores
- Flores, Hugo Alejandro; Fasce, Laura Alejandra; Riccardi, Carmen Cristina
- Año de publicación
- 2013
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Aiming to determine a suitable model to describe the curing kinetics of a commercial epoxy/anhydride initiated by a quaternary amine system used for the production of glass reinforced pipes, calorimetric and infrared spectroscopic kinetics data were collected. Several phenomenological, isoconversional and mechanistics kinetics models were revisited and tried. In addition, the time-temperature-transformation diagram, which is fundamental for the design of curing cycles, was assessed from calorimetric and gel time experiments. It was found that the Kamal´s model and a mechanistic model comprising an activation reversible step followed by a propagation step (Mauri et al., 1997) were capable to well describe all the experimental data. The kinetics mechanism appeared to be independent of the initiator concentration as suggested by the constancy of the apparent activation energy obtained by the Kissinger´s method. According to the mechanistic model, the activation step resulted independent on initiator concentration while propagation rate accelerated with increasing it. The presence of glass fiber reinforcement did no affect the curing kinetics of the studied reactive system.
Fil: Flores, Hugo Alejandro. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
Fil: Fasce, Laura Alejandra. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
Fil: Riccardi, Carmen Cristina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina - Materia
-
ANHYDRIDE
DSC
EPOXY
FTIR
KINETICS
MECHANISTIC MODEL - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/2935
Ver los metadatos del registro completo
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On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe productionFlores, Hugo AlejandroFasce, Laura AlejandraRiccardi, Carmen CristinaANHYDRIDEDSCEPOXYFTIRKINETICSMECHANISTIC MODELhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Aiming to determine a suitable model to describe the curing kinetics of a commercial epoxy/anhydride initiated by a quaternary amine system used for the production of glass reinforced pipes, calorimetric and infrared spectroscopic kinetics data were collected. Several phenomenological, isoconversional and mechanistics kinetics models were revisited and tried. In addition, the time-temperature-transformation diagram, which is fundamental for the design of curing cycles, was assessed from calorimetric and gel time experiments. It was found that the Kamal´s model and a mechanistic model comprising an activation reversible step followed by a propagation step (Mauri et al., 1997) were capable to well describe all the experimental data. The kinetics mechanism appeared to be independent of the initiator concentration as suggested by the constancy of the apparent activation energy obtained by the Kissinger´s method. According to the mechanistic model, the activation step resulted independent on initiator concentration while propagation rate accelerated with increasing it. The presence of glass fiber reinforcement did no affect the curing kinetics of the studied reactive system.Fil: Flores, Hugo Alejandro. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); ArgentinaFil: Fasce, Laura Alejandra. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); ArgentinaFil: Riccardi, Carmen Cristina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); ArgentinaElsevier Science2013-10-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/2935Flores, Hugo Alejandro; Fasce, Laura Alejandra; Riccardi, Carmen Cristina; On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production; Elsevier Science; Thermochimica Acta; 573; 8-10-2013; 1-90040-6031enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0040603113004681info:eu-repo/semantics/altIdentifier/doi/10.1016/j.tca.2013.09.004info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:51:39Zoai:ri.conicet.gov.ar:11336/2935instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:51:39.61CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production |
title |
On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production |
spellingShingle |
On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production Flores, Hugo Alejandro ANHYDRIDE DSC EPOXY FTIR KINETICS MECHANISTIC MODEL |
title_short |
On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production |
title_full |
On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production |
title_fullStr |
On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production |
title_full_unstemmed |
On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production |
title_sort |
On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production |
dc.creator.none.fl_str_mv |
Flores, Hugo Alejandro Fasce, Laura Alejandra Riccardi, Carmen Cristina |
author |
Flores, Hugo Alejandro |
author_facet |
Flores, Hugo Alejandro Fasce, Laura Alejandra Riccardi, Carmen Cristina |
author_role |
author |
author2 |
Fasce, Laura Alejandra Riccardi, Carmen Cristina |
author2_role |
author author |
dc.subject.none.fl_str_mv |
ANHYDRIDE DSC EPOXY FTIR KINETICS MECHANISTIC MODEL |
topic |
ANHYDRIDE DSC EPOXY FTIR KINETICS MECHANISTIC MODEL |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Aiming to determine a suitable model to describe the curing kinetics of a commercial epoxy/anhydride initiated by a quaternary amine system used for the production of glass reinforced pipes, calorimetric and infrared spectroscopic kinetics data were collected. Several phenomenological, isoconversional and mechanistics kinetics models were revisited and tried. In addition, the time-temperature-transformation diagram, which is fundamental for the design of curing cycles, was assessed from calorimetric and gel time experiments. It was found that the Kamal´s model and a mechanistic model comprising an activation reversible step followed by a propagation step (Mauri et al., 1997) were capable to well describe all the experimental data. The kinetics mechanism appeared to be independent of the initiator concentration as suggested by the constancy of the apparent activation energy obtained by the Kissinger´s method. According to the mechanistic model, the activation step resulted independent on initiator concentration while propagation rate accelerated with increasing it. The presence of glass fiber reinforcement did no affect the curing kinetics of the studied reactive system. Fil: Flores, Hugo Alejandro. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina Fil: Fasce, Laura Alejandra. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina Fil: Riccardi, Carmen Cristina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina |
description |
Aiming to determine a suitable model to describe the curing kinetics of a commercial epoxy/anhydride initiated by a quaternary amine system used for the production of glass reinforced pipes, calorimetric and infrared spectroscopic kinetics data were collected. Several phenomenological, isoconversional and mechanistics kinetics models were revisited and tried. In addition, the time-temperature-transformation diagram, which is fundamental for the design of curing cycles, was assessed from calorimetric and gel time experiments. It was found that the Kamal´s model and a mechanistic model comprising an activation reversible step followed by a propagation step (Mauri et al., 1997) were capable to well describe all the experimental data. The kinetics mechanism appeared to be independent of the initiator concentration as suggested by the constancy of the apparent activation energy obtained by the Kissinger´s method. According to the mechanistic model, the activation step resulted independent on initiator concentration while propagation rate accelerated with increasing it. The presence of glass fiber reinforcement did no affect the curing kinetics of the studied reactive system. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-10-08 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/2935 Flores, Hugo Alejandro; Fasce, Laura Alejandra; Riccardi, Carmen Cristina; On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production; Elsevier Science; Thermochimica Acta; 573; 8-10-2013; 1-9 0040-6031 |
url |
http://hdl.handle.net/11336/2935 |
identifier_str_mv |
Flores, Hugo Alejandro; Fasce, Laura Alejandra; Riccardi, Carmen Cristina; On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production; Elsevier Science; Thermochimica Acta; 573; 8-10-2013; 1-9 0040-6031 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0040603113004681 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.tca.2013.09.004 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842269108489420800 |
score |
13.13397 |