Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation
- Autores
- Pagano, A.M.; Mascheroni, Rodolfo Horacio
- Año de publicación
- 2003
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The GAB (Guggenheim, Andersen, and de Boer) equation was adjusted to literature data of sorption of Amarunthus cruentus L. (Me vs. a w for adsorption and desorption) determined at 25,30, 35,40,45, 50, 55,65,70, and 90°C, in the range of water activity from 0.029 to 0.979. To quantify the goodness of fit, the correlation coefficient (R2), the sum of squares (RSS), the standard error of the estimate (Sy), the mean relative deviation (MRD) and the plots of residuals were analysed. The three theoretical parameters of the GAB model (Mo, C, and K) gave a good correlation (R2 > 0.9817, RSS < 0.0297, MRD < 0.138, Sy < 0.0143, and random residuals-plots) in the range of a w from 0.029 to 0.979, of interest in seed storage and processing. However this correlation does not consider the effect of temperature (T) on coefficient values. In a second stage, parameters Mo and K were adjusted at each temperature. Very low variances were obtained in the range 25-65°C for desorption and in the range 25-55°C for adsorption. These results suggested that Mo and K remain almost constant and a correlation with T is not justified. On the contrary sense, parameter C showed stronger variation with T. This was explained by the analysis of sensitivity for the influence of C on moisture content. On this basis, the relation C-T was proposed by an Arrhenius-type relation [C=A.exp(B/T)] and this function was incorporated to the original GAB model to re-estimate the parameters A, B, Mo, and K. The developed modification provides a generalised and precise expression of GAB model for Amaranth.
Fil: Pagano, A.M.. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ingeniería Olavarría. Grupo Tecnologías de Semillas; Argentina
Fil: Mascheroni, Rodolfo Horacio. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentina - Materia
-
AMARANTH
DESORPTION
GAB MODEL
ISOTHERMS
SORPTION - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/128219
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Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB EquationPagano, A.M.Mascheroni, Rodolfo HoracioAMARANTHDESORPTIONGAB MODELISOTHERMSSORPTIONhttps://purl.org/becyt/ford/2.11https://purl.org/becyt/ford/2The GAB (Guggenheim, Andersen, and de Boer) equation was adjusted to literature data of sorption of Amarunthus cruentus L. (Me vs. a w for adsorption and desorption) determined at 25,30, 35,40,45, 50, 55,65,70, and 90°C, in the range of water activity from 0.029 to 0.979. To quantify the goodness of fit, the correlation coefficient (R2), the sum of squares (RSS), the standard error of the estimate (Sy), the mean relative deviation (MRD) and the plots of residuals were analysed. The three theoretical parameters of the GAB model (Mo, C, and K) gave a good correlation (R2 > 0.9817, RSS < 0.0297, MRD < 0.138, Sy < 0.0143, and random residuals-plots) in the range of a w from 0.029 to 0.979, of interest in seed storage and processing. However this correlation does not consider the effect of temperature (T) on coefficient values. In a second stage, parameters Mo and K were adjusted at each temperature. Very low variances were obtained in the range 25-65°C for desorption and in the range 25-55°C for adsorption. These results suggested that Mo and K remain almost constant and a correlation with T is not justified. On the contrary sense, parameter C showed stronger variation with T. This was explained by the analysis of sensitivity for the influence of C on moisture content. On this basis, the relation C-T was proposed by an Arrhenius-type relation [C=A.exp(B/T)] and this function was incorporated to the original GAB model to re-estimate the parameters A, B, Mo, and K. The developed modification provides a generalised and precise expression of GAB model for Amaranth.Fil: Pagano, A.M.. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ingeniería Olavarría. Grupo Tecnologías de Semillas; ArgentinaFil: Mascheroni, Rodolfo Horacio. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; ArgentinaTaylor & Francis2003-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/128219Pagano, A.M.; Mascheroni, Rodolfo Horacio; Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation; Taylor & Francis; International Journal Of Food Properties; 6; 3; 11-2003; 369-3911094-29121532-2386CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://tinyurl.com/yhdol2tainfo:eu-repo/semantics/altIdentifier/doi/10.1081/JFP-120020116info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:06:09Zoai:ri.conicet.gov.ar:11336/128219instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:06:10.299CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation |
title |
Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation |
spellingShingle |
Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation Pagano, A.M. AMARANTH DESORPTION GAB MODEL ISOTHERMS SORPTION |
title_short |
Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation |
title_full |
Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation |
title_fullStr |
Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation |
title_full_unstemmed |
Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation |
title_sort |
Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation |
dc.creator.none.fl_str_mv |
Pagano, A.M. Mascheroni, Rodolfo Horacio |
author |
Pagano, A.M. |
author_facet |
Pagano, A.M. Mascheroni, Rodolfo Horacio |
author_role |
author |
author2 |
Mascheroni, Rodolfo Horacio |
author2_role |
author |
dc.subject.none.fl_str_mv |
AMARANTH DESORPTION GAB MODEL ISOTHERMS SORPTION |
topic |
AMARANTH DESORPTION GAB MODEL ISOTHERMS SORPTION |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.11 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The GAB (Guggenheim, Andersen, and de Boer) equation was adjusted to literature data of sorption of Amarunthus cruentus L. (Me vs. a w for adsorption and desorption) determined at 25,30, 35,40,45, 50, 55,65,70, and 90°C, in the range of water activity from 0.029 to 0.979. To quantify the goodness of fit, the correlation coefficient (R2), the sum of squares (RSS), the standard error of the estimate (Sy), the mean relative deviation (MRD) and the plots of residuals were analysed. The three theoretical parameters of the GAB model (Mo, C, and K) gave a good correlation (R2 > 0.9817, RSS < 0.0297, MRD < 0.138, Sy < 0.0143, and random residuals-plots) in the range of a w from 0.029 to 0.979, of interest in seed storage and processing. However this correlation does not consider the effect of temperature (T) on coefficient values. In a second stage, parameters Mo and K were adjusted at each temperature. Very low variances were obtained in the range 25-65°C for desorption and in the range 25-55°C for adsorption. These results suggested that Mo and K remain almost constant and a correlation with T is not justified. On the contrary sense, parameter C showed stronger variation with T. This was explained by the analysis of sensitivity for the influence of C on moisture content. On this basis, the relation C-T was proposed by an Arrhenius-type relation [C=A.exp(B/T)] and this function was incorporated to the original GAB model to re-estimate the parameters A, B, Mo, and K. The developed modification provides a generalised and precise expression of GAB model for Amaranth. Fil: Pagano, A.M.. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ingeniería Olavarría. Grupo Tecnologías de Semillas; Argentina Fil: Mascheroni, Rodolfo Horacio. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentina |
description |
The GAB (Guggenheim, Andersen, and de Boer) equation was adjusted to literature data of sorption of Amarunthus cruentus L. (Me vs. a w for adsorption and desorption) determined at 25,30, 35,40,45, 50, 55,65,70, and 90°C, in the range of water activity from 0.029 to 0.979. To quantify the goodness of fit, the correlation coefficient (R2), the sum of squares (RSS), the standard error of the estimate (Sy), the mean relative deviation (MRD) and the plots of residuals were analysed. The three theoretical parameters of the GAB model (Mo, C, and K) gave a good correlation (R2 > 0.9817, RSS < 0.0297, MRD < 0.138, Sy < 0.0143, and random residuals-plots) in the range of a w from 0.029 to 0.979, of interest in seed storage and processing. However this correlation does not consider the effect of temperature (T) on coefficient values. In a second stage, parameters Mo and K were adjusted at each temperature. Very low variances were obtained in the range 25-65°C for desorption and in the range 25-55°C for adsorption. These results suggested that Mo and K remain almost constant and a correlation with T is not justified. On the contrary sense, parameter C showed stronger variation with T. This was explained by the analysis of sensitivity for the influence of C on moisture content. On this basis, the relation C-T was proposed by an Arrhenius-type relation [C=A.exp(B/T)] and this function was incorporated to the original GAB model to re-estimate the parameters A, B, Mo, and K. The developed modification provides a generalised and precise expression of GAB model for Amaranth. |
publishDate |
2003 |
dc.date.none.fl_str_mv |
2003-11 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/128219 Pagano, A.M.; Mascheroni, Rodolfo Horacio; Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation; Taylor & Francis; International Journal Of Food Properties; 6; 3; 11-2003; 369-391 1094-2912 1532-2386 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/128219 |
identifier_str_mv |
Pagano, A.M.; Mascheroni, Rodolfo Horacio; Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation; Taylor & Francis; International Journal Of Food Properties; 6; 3; 11-2003; 369-391 1094-2912 1532-2386 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://tinyurl.com/yhdol2ta info:eu-repo/semantics/altIdentifier/doi/10.1081/JFP-120020116 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Taylor & Francis |
publisher.none.fl_str_mv |
Taylor & Francis |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842269944978341888 |
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13.13397 |