Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation

Autores
Pagano, A.M.; Mascheroni, Rodolfo Horacio
Año de publicación
2003
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The GAB (Guggenheim, Andersen, and de Boer) equation was adjusted to literature data of sorption of Amarunthus cruentus L. (Me vs. a w for adsorption and desorption) determined at 25,30, 35,40,45, 50, 55,65,70, and 90°C, in the range of water activity from 0.029 to 0.979. To quantify the goodness of fit, the correlation coefficient (R2), the sum of squares (RSS), the standard error of the estimate (Sy), the mean relative deviation (MRD) and the plots of residuals were analysed. The three theoretical parameters of the GAB model (Mo, C, and K) gave a good correlation (R2 > 0.9817, RSS < 0.0297, MRD < 0.138, Sy < 0.0143, and random residuals-plots) in the range of a w from 0.029 to 0.979, of interest in seed storage and processing. However this correlation does not consider the effect of temperature (T) on coefficient values. In a second stage, parameters Mo and K were adjusted at each temperature. Very low variances were obtained in the range 25-65°C for desorption and in the range 25-55°C for adsorption. These results suggested that Mo and K remain almost constant and a correlation with T is not justified. On the contrary sense, parameter C showed stronger variation with T. This was explained by the analysis of sensitivity for the influence of C on moisture content. On this basis, the relation C-T was proposed by an Arrhenius-type relation [C=A.exp(B/T)] and this function was incorporated to the original GAB model to re-estimate the parameters A, B, Mo, and K. The developed modification provides a generalised and precise expression of GAB model for Amaranth.
Fil: Pagano, A.M.. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ingeniería Olavarría. Grupo Tecnologías de Semillas; Argentina
Fil: Mascheroni, Rodolfo Horacio. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentina
Materia
AMARANTH
DESORPTION
GAB MODEL
ISOTHERMS
SORPTION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/128219
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/128219
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB EquationPagano, A.M.Mascheroni, Rodolfo HoracioAMARANTHDESORPTIONGAB MODELISOTHERMSSORPTIONhttps://purl.org/becyt/ford/2.11https://purl.org/becyt/ford/2The GAB (Guggenheim, Andersen, and de Boer) equation was adjusted to literature data of sorption of Amarunthus cruentus L. (Me vs. a w for adsorption and desorption) determined at 25,30, 35,40,45, 50, 55,65,70, and 90°C, in the range of water activity from 0.029 to 0.979. To quantify the goodness of fit, the correlation coefficient (R2), the sum of squares (RSS), the standard error of the estimate (Sy), the mean relative deviation (MRD) and the plots of residuals were analysed. The three theoretical parameters of the GAB model (Mo, C, and K) gave a good correlation (R2 > 0.9817, RSS < 0.0297, MRD < 0.138, Sy < 0.0143, and random residuals-plots) in the range of a w from 0.029 to 0.979, of interest in seed storage and processing. However this correlation does not consider the effect of temperature (T) on coefficient values. In a second stage, parameters Mo and K were adjusted at each temperature. Very low variances were obtained in the range 25-65°C for desorption and in the range 25-55°C for adsorption. These results suggested that Mo and K remain almost constant and a correlation with T is not justified. On the contrary sense, parameter C showed stronger variation with T. This was explained by the analysis of sensitivity for the influence of C on moisture content. On this basis, the relation C-T was proposed by an Arrhenius-type relation [C=A.exp(B/T)] and this function was incorporated to the original GAB model to re-estimate the parameters A, B, Mo, and K. The developed modification provides a generalised and precise expression of GAB model for Amaranth.Fil: Pagano, A.M.. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ingeniería Olavarría. Grupo Tecnologías de Semillas; ArgentinaFil: Mascheroni, Rodolfo Horacio. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; ArgentinaTaylor & Francis2003-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/128219Pagano, A.M.; Mascheroni, Rodolfo Horacio; Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation; Taylor & Francis; International Journal Of Food Properties; 6; 3; 11-2003; 369-3911094-29121532-2386CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://tinyurl.com/yhdol2tainfo:eu-repo/semantics/altIdentifier/doi/10.1081/JFP-120020116info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:29:10Zoai:ri.conicet.gov.ar:11336/128219instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:29:11.166CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation
title Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation
spellingShingle Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation
Pagano, A.M.
AMARANTH
DESORPTION
GAB MODEL
ISOTHERMS
SORPTION
title_short Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation
title_full Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation
title_fullStr Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation
title_full_unstemmed Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation
title_sort Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation
dc.creator.none.fl_str_mv Pagano, A.M.
Mascheroni, Rodolfo Horacio
author Pagano, A.M.
author_facet Pagano, A.M.
Mascheroni, Rodolfo Horacio
author_role author
author2 Mascheroni, Rodolfo Horacio
author2_role author
dc.subject.none.fl_str_mv AMARANTH
DESORPTION
GAB MODEL
ISOTHERMS
SORPTION
topic AMARANTH
DESORPTION
GAB MODEL
ISOTHERMS
SORPTION
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.11
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The GAB (Guggenheim, Andersen, and de Boer) equation was adjusted to literature data of sorption of Amarunthus cruentus L. (Me vs. a w for adsorption and desorption) determined at 25,30, 35,40,45, 50, 55,65,70, and 90°C, in the range of water activity from 0.029 to 0.979. To quantify the goodness of fit, the correlation coefficient (R2), the sum of squares (RSS), the standard error of the estimate (Sy), the mean relative deviation (MRD) and the plots of residuals were analysed. The three theoretical parameters of the GAB model (Mo, C, and K) gave a good correlation (R2 > 0.9817, RSS < 0.0297, MRD < 0.138, Sy < 0.0143, and random residuals-plots) in the range of a w from 0.029 to 0.979, of interest in seed storage and processing. However this correlation does not consider the effect of temperature (T) on coefficient values. In a second stage, parameters Mo and K were adjusted at each temperature. Very low variances were obtained in the range 25-65°C for desorption and in the range 25-55°C for adsorption. These results suggested that Mo and K remain almost constant and a correlation with T is not justified. On the contrary sense, parameter C showed stronger variation with T. This was explained by the analysis of sensitivity for the influence of C on moisture content. On this basis, the relation C-T was proposed by an Arrhenius-type relation [C=A.exp(B/T)] and this function was incorporated to the original GAB model to re-estimate the parameters A, B, Mo, and K. The developed modification provides a generalised and precise expression of GAB model for Amaranth.
Fil: Pagano, A.M.. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ingeniería Olavarría. Grupo Tecnologías de Semillas; Argentina
Fil: Mascheroni, Rodolfo Horacio. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentina
description The GAB (Guggenheim, Andersen, and de Boer) equation was adjusted to literature data of sorption of Amarunthus cruentus L. (Me vs. a w for adsorption and desorption) determined at 25,30, 35,40,45, 50, 55,65,70, and 90°C, in the range of water activity from 0.029 to 0.979. To quantify the goodness of fit, the correlation coefficient (R2), the sum of squares (RSS), the standard error of the estimate (Sy), the mean relative deviation (MRD) and the plots of residuals were analysed. The three theoretical parameters of the GAB model (Mo, C, and K) gave a good correlation (R2 > 0.9817, RSS < 0.0297, MRD < 0.138, Sy < 0.0143, and random residuals-plots) in the range of a w from 0.029 to 0.979, of interest in seed storage and processing. However this correlation does not consider the effect of temperature (T) on coefficient values. In a second stage, parameters Mo and K were adjusted at each temperature. Very low variances were obtained in the range 25-65°C for desorption and in the range 25-55°C for adsorption. These results suggested that Mo and K remain almost constant and a correlation with T is not justified. On the contrary sense, parameter C showed stronger variation with T. This was explained by the analysis of sensitivity for the influence of C on moisture content. On this basis, the relation C-T was proposed by an Arrhenius-type relation [C=A.exp(B/T)] and this function was incorporated to the original GAB model to re-estimate the parameters A, B, Mo, and K. The developed modification provides a generalised and precise expression of GAB model for Amaranth.
publishDate 2003
dc.date.none.fl_str_mv 2003-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/128219
Pagano, A.M.; Mascheroni, Rodolfo Horacio; Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation; Taylor & Francis; International Journal Of Food Properties; 6; 3; 11-2003; 369-391
1094-2912
1532-2386
CONICET Digital
CONICET
url http://hdl.handle.net/11336/128219
identifier_str_mv Pagano, A.M.; Mascheroni, Rodolfo Horacio; Water Sorption of Amaranthus cruentus L. Seeds Modelled by GAB Equation; Taylor & Francis; International Journal Of Food Properties; 6; 3; 11-2003; 369-391
1094-2912
1532-2386
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://tinyurl.com/yhdol2ta
info:eu-repo/semantics/altIdentifier/doi/10.1081/JFP-120020116
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Taylor & Francis
publisher.none.fl_str_mv Taylor & Francis
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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