Coupled High Spin CoII Ions Linked by Symmetrical Double Hydrogen Bonds: Role of a Slowly Relaxing CuII Impurity in Interrupting the CoII–CoII Exchange Interaction

Autores
Pérez, Ana Laura; Kemmerer, Axel; Rey, Marilin de Los Angeles; Dalosto, Sergio Daniel; Ramos, Carlos Alberto; Passeggi, Mario Cesar Guillermo; Rizzi, Alberto Claudio; Brondino, Carlos Dante
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
CoII and CuII ions are two paramagnetic transition metal ions showing different relaxation rates (ν), with νCo II >> νCu II. To measure the isotropic exchange constant (J) between high spin CoII ions and between CuII ions and high spin CoII ions, we performed magnetic and EPR measurements complemented with computational calculations on pure trans-diaqua-bis(picolinato-N,O)-cobalt(II) dihydrate (1), on the CuII ion doped compound of 1 (2), and on the CuII ion doped compound in a ZnII matrix isomorphous to 1. The temperature dependence of the CuII EPR resonance lines of 2 induced by the fast relaxing CoII ion host as well as the evaluation of the temperature-independent CoII?CoII and CuII?CoII isotropic exchange interaction are analyzed. We determined an antiferromagnetic interaction [JCo?Co = ?1.07(1) cm?1] associated with a double symmetrical hydrogen bond bridge and another one [|J|Co?Cu = 0.0015(2) cm?1] associated with a double but asymmetrical hydrogen bond bridge, which are in line with the values obtained from computational calculations. This work shows that EPR spectroscopy can advantageously be used to evaluate weak exchange interactions between distinct metal ions with different relaxation rates by using the fact that those metal?metal interactions that broaden the EPR resonance line, which are described by matrices with a trace of zero, are averaged out at high temperatures.
Fil: Pérez, Ana Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Física; Argentina
Fil: Kemmerer, Axel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Física; Argentina
Fil: Rey, Marilin de Los Angeles. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Física; Argentina
Fil: Dalosto, Sergio Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Física del Litoral. Universidad Nacional del Litoral. Instituto de Física del Litoral; Argentina
Fil: Ramos, Carlos Alberto. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Passeggi, Mario Cesar Guillermo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Física del Litoral. Universidad Nacional del Litoral. Instituto de Física del Litoral; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Física; Argentina
Fil: Rizzi, Alberto Claudio. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Física; Argentina
Fil: Brondino, Carlos Dante. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Física; Argentina
Materia
COBALT
COPPER
EPR SPECTROSCOPY
MAGNETIC PROPERTIES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/84973
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/84973
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Coupled High Spin CoII Ions Linked by Symmetrical Double Hydrogen Bonds: Role of a Slowly Relaxing CuII Impurity in Interrupting the CoII–CoII Exchange InteractionPérez, Ana LauraKemmerer, AxelRey, Marilin de Los AngelesDalosto, Sergio DanielRamos, Carlos AlbertoPasseggi, Mario Cesar GuillermoRizzi, Alberto ClaudioBrondino, Carlos DanteCOBALTCOPPEREPR SPECTROSCOPYMAGNETIC PROPERTIEShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1CoII and CuII ions are two paramagnetic transition metal ions showing different relaxation rates (ν), with νCo II >> νCu II. To measure the isotropic exchange constant (J) between high spin CoII ions and between CuII ions and high spin CoII ions, we performed magnetic and EPR measurements complemented with computational calculations on pure trans-diaqua-bis(picolinato-N,O)-cobalt(II) dihydrate (1), on the CuII ion doped compound of 1 (2), and on the CuII ion doped compound in a ZnII matrix isomorphous to 1. The temperature dependence of the CuII EPR resonance lines of 2 induced by the fast relaxing CoII ion host as well as the evaluation of the temperature-independent CoII?CoII and CuII?CoII isotropic exchange interaction are analyzed. We determined an antiferromagnetic interaction [JCo?Co = ?1.07(1) cm?1] associated with a double symmetrical hydrogen bond bridge and another one [|J|Co?Cu = 0.0015(2) cm?1] associated with a double but asymmetrical hydrogen bond bridge, which are in line with the values obtained from computational calculations. This work shows that EPR spectroscopy can advantageously be used to evaluate weak exchange interactions between distinct metal ions with different relaxation rates by using the fact that those metal?metal interactions that broaden the EPR resonance line, which are described by matrices with a trace of zero, are averaged out at high temperatures.Fil: Pérez, Ana Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Física; ArgentinaFil: Kemmerer, Axel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Física; ArgentinaFil: Rey, Marilin de Los Angeles. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Física; ArgentinaFil: Dalosto, Sergio Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Física del Litoral. Universidad Nacional del Litoral. Instituto de Física del Litoral; ArgentinaFil: Ramos, Carlos Alberto. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; ArgentinaFil: Passeggi, Mario Cesar Guillermo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Física del Litoral. Universidad Nacional del Litoral. Instituto de Física del Litoral; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Física; ArgentinaFil: Rizzi, Alberto Claudio. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Física; ArgentinaFil: Brondino, Carlos Dante. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Física; ArgentinaWiley VCH Verlag2018-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/84973Pérez, Ana Laura; Kemmerer, Axel; Rey, Marilin de Los Angeles; Dalosto, Sergio Daniel; Ramos, Carlos Alberto; et al.; Coupled High Spin CoII Ions Linked by Symmetrical Double Hydrogen Bonds: Role of a Slowly Relaxing CuII Impurity in Interrupting the CoII–CoII Exchange Interaction; Wiley VCH Verlag; European Journal of Inorganic Chemistry; 2018; 42; 11-2018; 4604-46131099-06821434-1948CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/ejic.201800593info:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201800593info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:50:37Zoai:ri.conicet.gov.ar:11336/84973instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:50:37.596CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Coupled High Spin CoII Ions Linked by Symmetrical Double Hydrogen Bonds: Role of a Slowly Relaxing CuII Impurity in Interrupting the CoII–CoII Exchange Interaction
title Coupled High Spin CoII Ions Linked by Symmetrical Double Hydrogen Bonds: Role of a Slowly Relaxing CuII Impurity in Interrupting the CoII–CoII Exchange Interaction
spellingShingle Coupled High Spin CoII Ions Linked by Symmetrical Double Hydrogen Bonds: Role of a Slowly Relaxing CuII Impurity in Interrupting the CoII–CoII Exchange Interaction
Pérez, Ana Laura
COBALT
COPPER
EPR SPECTROSCOPY
MAGNETIC PROPERTIES
title_short Coupled High Spin CoII Ions Linked by Symmetrical Double Hydrogen Bonds: Role of a Slowly Relaxing CuII Impurity in Interrupting the CoII–CoII Exchange Interaction
title_full Coupled High Spin CoII Ions Linked by Symmetrical Double Hydrogen Bonds: Role of a Slowly Relaxing CuII Impurity in Interrupting the CoII–CoII Exchange Interaction
title_fullStr Coupled High Spin CoII Ions Linked by Symmetrical Double Hydrogen Bonds: Role of a Slowly Relaxing CuII Impurity in Interrupting the CoII–CoII Exchange Interaction
title_full_unstemmed Coupled High Spin CoII Ions Linked by Symmetrical Double Hydrogen Bonds: Role of a Slowly Relaxing CuII Impurity in Interrupting the CoII–CoII Exchange Interaction
title_sort Coupled High Spin CoII Ions Linked by Symmetrical Double Hydrogen Bonds: Role of a Slowly Relaxing CuII Impurity in Interrupting the CoII–CoII Exchange Interaction
dc.creator.none.fl_str_mv Pérez, Ana Laura
Kemmerer, Axel
Rey, Marilin de Los Angeles
Dalosto, Sergio Daniel
Ramos, Carlos Alberto
Passeggi, Mario Cesar Guillermo
Rizzi, Alberto Claudio
Brondino, Carlos Dante
author Pérez, Ana Laura
author_facet Pérez, Ana Laura
Kemmerer, Axel
Rey, Marilin de Los Angeles
Dalosto, Sergio Daniel
Ramos, Carlos Alberto
Passeggi, Mario Cesar Guillermo
Rizzi, Alberto Claudio
Brondino, Carlos Dante
author_role author
author2 Kemmerer, Axel
Rey, Marilin de Los Angeles
Dalosto, Sergio Daniel
Ramos, Carlos Alberto
Passeggi, Mario Cesar Guillermo
Rizzi, Alberto Claudio
Brondino, Carlos Dante
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv COBALT
COPPER
EPR SPECTROSCOPY
MAGNETIC PROPERTIES
topic COBALT
COPPER
EPR SPECTROSCOPY
MAGNETIC PROPERTIES
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv CoII and CuII ions are two paramagnetic transition metal ions showing different relaxation rates (ν), with νCo II >> νCu II. To measure the isotropic exchange constant (J) between high spin CoII ions and between CuII ions and high spin CoII ions, we performed magnetic and EPR measurements complemented with computational calculations on pure trans-diaqua-bis(picolinato-N,O)-cobalt(II) dihydrate (1), on the CuII ion doped compound of 1 (2), and on the CuII ion doped compound in a ZnII matrix isomorphous to 1. The temperature dependence of the CuII EPR resonance lines of 2 induced by the fast relaxing CoII ion host as well as the evaluation of the temperature-independent CoII?CoII and CuII?CoII isotropic exchange interaction are analyzed. We determined an antiferromagnetic interaction [JCo?Co = ?1.07(1) cm?1] associated with a double symmetrical hydrogen bond bridge and another one [|J|Co?Cu = 0.0015(2) cm?1] associated with a double but asymmetrical hydrogen bond bridge, which are in line with the values obtained from computational calculations. This work shows that EPR spectroscopy can advantageously be used to evaluate weak exchange interactions between distinct metal ions with different relaxation rates by using the fact that those metal?metal interactions that broaden the EPR resonance line, which are described by matrices with a trace of zero, are averaged out at high temperatures.
Fil: Pérez, Ana Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Física; Argentina
Fil: Kemmerer, Axel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Física; Argentina
Fil: Rey, Marilin de Los Angeles. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Física; Argentina
Fil: Dalosto, Sergio Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Física del Litoral. Universidad Nacional del Litoral. Instituto de Física del Litoral; Argentina
Fil: Ramos, Carlos Alberto. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Passeggi, Mario Cesar Guillermo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Física del Litoral. Universidad Nacional del Litoral. Instituto de Física del Litoral; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Física; Argentina
Fil: Rizzi, Alberto Claudio. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Física; Argentina
Fil: Brondino, Carlos Dante. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Física; Argentina
description CoII and CuII ions are two paramagnetic transition metal ions showing different relaxation rates (ν), with νCo II >> νCu II. To measure the isotropic exchange constant (J) between high spin CoII ions and between CuII ions and high spin CoII ions, we performed magnetic and EPR measurements complemented with computational calculations on pure trans-diaqua-bis(picolinato-N,O)-cobalt(II) dihydrate (1), on the CuII ion doped compound of 1 (2), and on the CuII ion doped compound in a ZnII matrix isomorphous to 1. The temperature dependence of the CuII EPR resonance lines of 2 induced by the fast relaxing CoII ion host as well as the evaluation of the temperature-independent CoII?CoII and CuII?CoII isotropic exchange interaction are analyzed. We determined an antiferromagnetic interaction [JCo?Co = ?1.07(1) cm?1] associated with a double symmetrical hydrogen bond bridge and another one [|J|Co?Cu = 0.0015(2) cm?1] associated with a double but asymmetrical hydrogen bond bridge, which are in line with the values obtained from computational calculations. This work shows that EPR spectroscopy can advantageously be used to evaluate weak exchange interactions between distinct metal ions with different relaxation rates by using the fact that those metal?metal interactions that broaden the EPR resonance line, which are described by matrices with a trace of zero, are averaged out at high temperatures.
publishDate 2018
dc.date.none.fl_str_mv 2018-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/84973
Pérez, Ana Laura; Kemmerer, Axel; Rey, Marilin de Los Angeles; Dalosto, Sergio Daniel; Ramos, Carlos Alberto; et al.; Coupled High Spin CoII Ions Linked by Symmetrical Double Hydrogen Bonds: Role of a Slowly Relaxing CuII Impurity in Interrupting the CoII–CoII Exchange Interaction; Wiley VCH Verlag; European Journal of Inorganic Chemistry; 2018; 42; 11-2018; 4604-4613
1099-0682
1434-1948
CONICET Digital
CONICET
url http://hdl.handle.net/11336/84973
identifier_str_mv Pérez, Ana Laura; Kemmerer, Axel; Rey, Marilin de Los Angeles; Dalosto, Sergio Daniel; Ramos, Carlos Alberto; et al.; Coupled High Spin CoII Ions Linked by Symmetrical Double Hydrogen Bonds: Role of a Slowly Relaxing CuII Impurity in Interrupting the CoII–CoII Exchange Interaction; Wiley VCH Verlag; European Journal of Inorganic Chemistry; 2018; 42; 11-2018; 4604-4613
1099-0682
1434-1948
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/ejic.201800593
info:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201800593
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley VCH Verlag
publisher.none.fl_str_mv Wiley VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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