Carlhintzeite, Ca2AlF7•H2O, from the Gigante granitic pegmatite, Córdoba province, Argentina: Description and crystal structure

Autores
Kampf, A. R.; Colombo, Fernando; González Del Tánago, J.
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Carlhintzeite, Ca2AlF7•H2O, has been found at the Gigante pegmatite, Punilla Department, Córdoba Province, Argentina. It occurs as colourless prismatic crystals up to 0.8 mm long, ubiquitously twinned on {001}. Electron microprobe analyses provided the empirical formula Ca1.98Al1.02F6.24(OH) 0.76•H1.62O. A crystal fragment used for the collection of structure data provided the triclinic, C1 cell: a = 9.4227(4), b = 6.9670(5), c = 9.2671(7) Å, α = 90.974(6), β = 104.802(5), γ = 90.026(6)°, V = 558.08(7) Å3 and Z = 4. The crystal structure, solved by direct methods and refined to R 1 = 0.0322 for 723 Fo > 4σF reflections, is made up of linkages of AlF6 octahedra, CaF8 polyhedra and CaF 6(H2O)2 polyhedra. The AlF6 octahedra are isolated from one another, but share polyhedral elements with Ca polyhedra. Most notably, the Al1 octahedron shares trans faces with two CaF 8 polyhedra and the Al2 octahedron shares trans edges with two CaF6(H2O)2 polyhedra. The linkage of the Ca polyhedra alone can be described as a framework in which edge-sharing chains along b are cross-linked by edge-sharing. Edge-sharing chains of Ca polyhedra along b in the carlhintzeite structure are similar to those along c in the structures of gearksutite, CaAlF4(OH)•(H2O), and prosopite, CaAl2F4(OH)4. © 2010 Mineralogical Society.
Fil: Kampf, A. R.. Natural History Museum of Los Angeles County; Estados Unidos
Fil: Colombo, Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
Fil: González Del Tánago, J.. Universidad Complutense de Madrid; España
Materia
ARGENTINA
CARLHINTZEITE
CORDOBA
CRYSTAL STRUCTURE
GEARKSUTITE
PROSOPITE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/54262
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/54262
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Carlhintzeite, Ca2AlF7•H2O, from the Gigante granitic pegmatite, Córdoba province, Argentina: Description and crystal structureKampf, A. R.Colombo, FernandoGonzález Del Tánago, J.ARGENTINACARLHINTZEITECORDOBACRYSTAL STRUCTUREGEARKSUTITEPROSOPITEhttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1Carlhintzeite, Ca2AlF7•H2O, has been found at the Gigante pegmatite, Punilla Department, Córdoba Province, Argentina. It occurs as colourless prismatic crystals up to 0.8 mm long, ubiquitously twinned on {001}. Electron microprobe analyses provided the empirical formula Ca1.98Al1.02F6.24(OH) 0.76•H1.62O. A crystal fragment used for the collection of structure data provided the triclinic, C1 cell: a = 9.4227(4), b = 6.9670(5), c = 9.2671(7) Å, α = 90.974(6), β = 104.802(5), γ = 90.026(6)°, V = 558.08(7) Å3 and Z = 4. The crystal structure, solved by direct methods and refined to R 1 = 0.0322 for 723 Fo > 4σF reflections, is made up of linkages of AlF6 octahedra, CaF8 polyhedra and CaF 6(H2O)2 polyhedra. The AlF6 octahedra are isolated from one another, but share polyhedral elements with Ca polyhedra. Most notably, the Al1 octahedron shares trans faces with two CaF 8 polyhedra and the Al2 octahedron shares trans edges with two CaF6(H2O)2 polyhedra. The linkage of the Ca polyhedra alone can be described as a framework in which edge-sharing chains along b are cross-linked by edge-sharing. Edge-sharing chains of Ca polyhedra along b in the carlhintzeite structure are similar to those along c in the structures of gearksutite, CaAlF4(OH)•(H2O), and prosopite, CaAl2F4(OH)4. © 2010 Mineralogical Society.Fil: Kampf, A. R.. Natural History Museum of Los Angeles County; Estados UnidosFil: Colombo, Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; ArgentinaFil: González Del Tánago, J.. Universidad Complutense de Madrid; EspañaMineralogical Soc2010-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/54262Kampf, A. R.; Colombo, Fernando; González Del Tánago, J.; Carlhintzeite, Ca2AlF7•H2O, from the Gigante granitic pegmatite, Córdoba province, Argentina: Description and crystal structure; Mineralogical Soc; Mineralogical Magazine; 74; 4; 8-2010; 623-6320026-461XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.ingentaconnect.com/contentone/minsoc/mag/2010/00000074/00000004/art00003info:eu-repo/semantics/altIdentifier/doi/10.1180/minmag.2010.074.4.623info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:33:29Zoai:ri.conicet.gov.ar:11336/54262instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:33:30.177CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Carlhintzeite, Ca2AlF7•H2O, from the Gigante granitic pegmatite, Córdoba province, Argentina: Description and crystal structure
title Carlhintzeite, Ca2AlF7•H2O, from the Gigante granitic pegmatite, Córdoba province, Argentina: Description and crystal structure
spellingShingle Carlhintzeite, Ca2AlF7•H2O, from the Gigante granitic pegmatite, Córdoba province, Argentina: Description and crystal structure
Kampf, A. R.
ARGENTINA
CARLHINTZEITE
CORDOBA
CRYSTAL STRUCTURE
GEARKSUTITE
PROSOPITE
title_short Carlhintzeite, Ca2AlF7•H2O, from the Gigante granitic pegmatite, Córdoba province, Argentina: Description and crystal structure
title_full Carlhintzeite, Ca2AlF7•H2O, from the Gigante granitic pegmatite, Córdoba province, Argentina: Description and crystal structure
title_fullStr Carlhintzeite, Ca2AlF7•H2O, from the Gigante granitic pegmatite, Córdoba province, Argentina: Description and crystal structure
title_full_unstemmed Carlhintzeite, Ca2AlF7•H2O, from the Gigante granitic pegmatite, Córdoba province, Argentina: Description and crystal structure
title_sort Carlhintzeite, Ca2AlF7•H2O, from the Gigante granitic pegmatite, Córdoba province, Argentina: Description and crystal structure
dc.creator.none.fl_str_mv Kampf, A. R.
Colombo, Fernando
González Del Tánago, J.
author Kampf, A. R.
author_facet Kampf, A. R.
Colombo, Fernando
González Del Tánago, J.
author_role author
author2 Colombo, Fernando
González Del Tánago, J.
author2_role author
author
dc.subject.none.fl_str_mv ARGENTINA
CARLHINTZEITE
CORDOBA
CRYSTAL STRUCTURE
GEARKSUTITE
PROSOPITE
topic ARGENTINA
CARLHINTZEITE
CORDOBA
CRYSTAL STRUCTURE
GEARKSUTITE
PROSOPITE
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Carlhintzeite, Ca2AlF7•H2O, has been found at the Gigante pegmatite, Punilla Department, Córdoba Province, Argentina. It occurs as colourless prismatic crystals up to 0.8 mm long, ubiquitously twinned on {001}. Electron microprobe analyses provided the empirical formula Ca1.98Al1.02F6.24(OH) 0.76•H1.62O. A crystal fragment used for the collection of structure data provided the triclinic, C1 cell: a = 9.4227(4), b = 6.9670(5), c = 9.2671(7) Å, α = 90.974(6), β = 104.802(5), γ = 90.026(6)°, V = 558.08(7) Å3 and Z = 4. The crystal structure, solved by direct methods and refined to R 1 = 0.0322 for 723 Fo > 4σF reflections, is made up of linkages of AlF6 octahedra, CaF8 polyhedra and CaF 6(H2O)2 polyhedra. The AlF6 octahedra are isolated from one another, but share polyhedral elements with Ca polyhedra. Most notably, the Al1 octahedron shares trans faces with two CaF 8 polyhedra and the Al2 octahedron shares trans edges with two CaF6(H2O)2 polyhedra. The linkage of the Ca polyhedra alone can be described as a framework in which edge-sharing chains along b are cross-linked by edge-sharing. Edge-sharing chains of Ca polyhedra along b in the carlhintzeite structure are similar to those along c in the structures of gearksutite, CaAlF4(OH)•(H2O), and prosopite, CaAl2F4(OH)4. © 2010 Mineralogical Society.
Fil: Kampf, A. R.. Natural History Museum of Los Angeles County; Estados Unidos
Fil: Colombo, Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
Fil: González Del Tánago, J.. Universidad Complutense de Madrid; España
description Carlhintzeite, Ca2AlF7•H2O, has been found at the Gigante pegmatite, Punilla Department, Córdoba Province, Argentina. It occurs as colourless prismatic crystals up to 0.8 mm long, ubiquitously twinned on {001}. Electron microprobe analyses provided the empirical formula Ca1.98Al1.02F6.24(OH) 0.76•H1.62O. A crystal fragment used for the collection of structure data provided the triclinic, C1 cell: a = 9.4227(4), b = 6.9670(5), c = 9.2671(7) Å, α = 90.974(6), β = 104.802(5), γ = 90.026(6)°, V = 558.08(7) Å3 and Z = 4. The crystal structure, solved by direct methods and refined to R 1 = 0.0322 for 723 Fo > 4σF reflections, is made up of linkages of AlF6 octahedra, CaF8 polyhedra and CaF 6(H2O)2 polyhedra. The AlF6 octahedra are isolated from one another, but share polyhedral elements with Ca polyhedra. Most notably, the Al1 octahedron shares trans faces with two CaF 8 polyhedra and the Al2 octahedron shares trans edges with two CaF6(H2O)2 polyhedra. The linkage of the Ca polyhedra alone can be described as a framework in which edge-sharing chains along b are cross-linked by edge-sharing. Edge-sharing chains of Ca polyhedra along b in the carlhintzeite structure are similar to those along c in the structures of gearksutite, CaAlF4(OH)•(H2O), and prosopite, CaAl2F4(OH)4. © 2010 Mineralogical Society.
publishDate 2010
dc.date.none.fl_str_mv 2010-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/54262
Kampf, A. R.; Colombo, Fernando; González Del Tánago, J.; Carlhintzeite, Ca2AlF7•H2O, from the Gigante granitic pegmatite, Córdoba province, Argentina: Description and crystal structure; Mineralogical Soc; Mineralogical Magazine; 74; 4; 8-2010; 623-632
0026-461X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/54262
identifier_str_mv Kampf, A. R.; Colombo, Fernando; González Del Tánago, J.; Carlhintzeite, Ca2AlF7•H2O, from the Gigante granitic pegmatite, Córdoba province, Argentina: Description and crystal structure; Mineralogical Soc; Mineralogical Magazine; 74; 4; 8-2010; 623-632
0026-461X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.ingentaconnect.com/contentone/minsoc/mag/2010/00000074/00000004/art00003
info:eu-repo/semantics/altIdentifier/doi/10.1180/minmag.2010.074.4.623
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Mineralogical Soc
publisher.none.fl_str_mv Mineralogical Soc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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