Size and surface effects in the magnetic order of CoFe2O4 nanoparticles

Autores
Pianciola, Betiana Noelia; Lima, Enio Junior; Troiani, Horacio Esteban; Nagamine, Luiz C.C.M.; Cohen, R.; Zysler, Roberto Daniel
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work, we have focused on the size dependence of the magnetic properties and the surface effects of CoFe2O4 nanoparticles synthesized by high-temperature chemical method with diameter d~2, 4.5, and 7 nm, with narrow size distribution. transmission electron microscopy (TEM) images and X-ray diffraction (XRD) profiles indicates that samples with 7 and 4.5 nm present a high crystallinity while the 2 nm sample has a poor one. We have investigated by magnetization measurements and in-field Mössbauer spectroscopy the influence of the surface in the internal magnetic order of the particles. Particles with d=7 nm have almost single domain behavior and the monodomain occupies approximately the whole particle. In the sample with d=4.5 nm the surface anisotropy is large enough to alter the ferrimagnetic order in the particle shell. Then, a surface/volume ratio of ~60% is the crossover between a single domain nanoparticle and a frustrated order in a magnetic core-shell structure, due to the competition between surface anisotropy and exchange interaction+crystalline anisotropy in cobalt ferrite. In the d=2 nm sample the poor crystallinity and the large surface/volume ratio avoid the ferrimagnetic order in the particle down to T=5 K.
Fil: Pianciola, Betiana Noelia. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Lima, Enio Junior. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Troiani, Horacio Esteban. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Nagamine, Luiz C.C.M.. Universidade de Sao Paulo; Brasil
Fil: Cohen, R.. Universidade de Sao Paulo; Brasil
Fil: Zysler, Roberto Daniel. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Materia
FINE PARTICLES
MAGNETIC ORDERING
SIZE EFFECTS
SUPERPARAMAGNETISM
SURFACE EFFECTS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/38066
Acceder
id CONICETDig_52baed37b92ca1b18f074515a946a32f
oai_identifier_str oai:ri.conicet.gov.ar:11336/38066
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Size and surface effects in the magnetic order of CoFe2O4 nanoparticlesPianciola, Betiana NoeliaLima, Enio JuniorTroiani, Horacio EstebanNagamine, Luiz C.C.M.Cohen, R.Zysler, Roberto DanielFINE PARTICLESMAGNETIC ORDERINGSIZE EFFECTSSUPERPARAMAGNETISMSURFACE EFFECTShttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2In this work, we have focused on the size dependence of the magnetic properties and the surface effects of CoFe2O4 nanoparticles synthesized by high-temperature chemical method with diameter d~2, 4.5, and 7 nm, with narrow size distribution. transmission electron microscopy (TEM) images and X-ray diffraction (XRD) profiles indicates that samples with 7 and 4.5 nm present a high crystallinity while the 2 nm sample has a poor one. We have investigated by magnetization measurements and in-field Mössbauer spectroscopy the influence of the surface in the internal magnetic order of the particles. Particles with d=7 nm have almost single domain behavior and the monodomain occupies approximately the whole particle. In the sample with d=4.5 nm the surface anisotropy is large enough to alter the ferrimagnetic order in the particle shell. Then, a surface/volume ratio of ~60% is the crossover between a single domain nanoparticle and a frustrated order in a magnetic core-shell structure, due to the competition between surface anisotropy and exchange interaction+crystalline anisotropy in cobalt ferrite. In the d=2 nm sample the poor crystallinity and the large surface/volume ratio avoid the ferrimagnetic order in the particle down to T=5 K.Fil: Pianciola, Betiana Noelia. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaFil: Lima, Enio Junior. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaFil: Troiani, Horacio Esteban. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaFil: Nagamine, Luiz C.C.M.. Universidade de Sao Paulo; BrasilFil: Cohen, R.. Universidade de Sao Paulo; BrasilFil: Zysler, Roberto Daniel. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaElsevier Science2015-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/38066Pianciola, Betiana Noelia; Lima, Enio Junior; Troiani, Horacio Esteban; Nagamine, Luiz C.C.M.; Cohen, R.; et al.; Size and surface effects in the magnetic order of CoFe2O4 nanoparticles; Elsevier Science; Journal of Magnetism and Magnetic Materials; 377; 3-2015; 44-510304-8853CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jmmm.2014.10.054info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:01:30Zoai:ri.conicet.gov.ar:11336/38066instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:01:31.268CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Size and surface effects in the magnetic order of CoFe2O4 nanoparticles
title Size and surface effects in the magnetic order of CoFe2O4 nanoparticles
spellingShingle Size and surface effects in the magnetic order of CoFe2O4 nanoparticles
Pianciola, Betiana Noelia
FINE PARTICLES
MAGNETIC ORDERING
SIZE EFFECTS
SUPERPARAMAGNETISM
SURFACE EFFECTS
title_short Size and surface effects in the magnetic order of CoFe2O4 nanoparticles
title_full Size and surface effects in the magnetic order of CoFe2O4 nanoparticles
title_fullStr Size and surface effects in the magnetic order of CoFe2O4 nanoparticles
title_full_unstemmed Size and surface effects in the magnetic order of CoFe2O4 nanoparticles
title_sort Size and surface effects in the magnetic order of CoFe2O4 nanoparticles
dc.creator.none.fl_str_mv Pianciola, Betiana Noelia
Lima, Enio Junior
Troiani, Horacio Esteban
Nagamine, Luiz C.C.M.
Cohen, R.
Zysler, Roberto Daniel
author Pianciola, Betiana Noelia
author_facet Pianciola, Betiana Noelia
Lima, Enio Junior
Troiani, Horacio Esteban
Nagamine, Luiz C.C.M.
Cohen, R.
Zysler, Roberto Daniel
author_role author
author2 Lima, Enio Junior
Troiani, Horacio Esteban
Nagamine, Luiz C.C.M.
Cohen, R.
Zysler, Roberto Daniel
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv FINE PARTICLES
MAGNETIC ORDERING
SIZE EFFECTS
SUPERPARAMAGNETISM
SURFACE EFFECTS
topic FINE PARTICLES
MAGNETIC ORDERING
SIZE EFFECTS
SUPERPARAMAGNETISM
SURFACE EFFECTS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In this work, we have focused on the size dependence of the magnetic properties and the surface effects of CoFe2O4 nanoparticles synthesized by high-temperature chemical method with diameter d~2, 4.5, and 7 nm, with narrow size distribution. transmission electron microscopy (TEM) images and X-ray diffraction (XRD) profiles indicates that samples with 7 and 4.5 nm present a high crystallinity while the 2 nm sample has a poor one. We have investigated by magnetization measurements and in-field Mössbauer spectroscopy the influence of the surface in the internal magnetic order of the particles. Particles with d=7 nm have almost single domain behavior and the monodomain occupies approximately the whole particle. In the sample with d=4.5 nm the surface anisotropy is large enough to alter the ferrimagnetic order in the particle shell. Then, a surface/volume ratio of ~60% is the crossover between a single domain nanoparticle and a frustrated order in a magnetic core-shell structure, due to the competition between surface anisotropy and exchange interaction+crystalline anisotropy in cobalt ferrite. In the d=2 nm sample the poor crystallinity and the large surface/volume ratio avoid the ferrimagnetic order in the particle down to T=5 K.
Fil: Pianciola, Betiana Noelia. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Lima, Enio Junior. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Troiani, Horacio Esteban. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Nagamine, Luiz C.C.M.. Universidade de Sao Paulo; Brasil
Fil: Cohen, R.. Universidade de Sao Paulo; Brasil
Fil: Zysler, Roberto Daniel. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
description In this work, we have focused on the size dependence of the magnetic properties and the surface effects of CoFe2O4 nanoparticles synthesized by high-temperature chemical method with diameter d~2, 4.5, and 7 nm, with narrow size distribution. transmission electron microscopy (TEM) images and X-ray diffraction (XRD) profiles indicates that samples with 7 and 4.5 nm present a high crystallinity while the 2 nm sample has a poor one. We have investigated by magnetization measurements and in-field Mössbauer spectroscopy the influence of the surface in the internal magnetic order of the particles. Particles with d=7 nm have almost single domain behavior and the monodomain occupies approximately the whole particle. In the sample with d=4.5 nm the surface anisotropy is large enough to alter the ferrimagnetic order in the particle shell. Then, a surface/volume ratio of ~60% is the crossover between a single domain nanoparticle and a frustrated order in a magnetic core-shell structure, due to the competition between surface anisotropy and exchange interaction+crystalline anisotropy in cobalt ferrite. In the d=2 nm sample the poor crystallinity and the large surface/volume ratio avoid the ferrimagnetic order in the particle down to T=5 K.
publishDate 2015
dc.date.none.fl_str_mv 2015-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/38066
Pianciola, Betiana Noelia; Lima, Enio Junior; Troiani, Horacio Esteban; Nagamine, Luiz C.C.M.; Cohen, R.; et al.; Size and surface effects in the magnetic order of CoFe2O4 nanoparticles; Elsevier Science; Journal of Magnetism and Magnetic Materials; 377; 3-2015; 44-51
0304-8853
CONICET Digital
CONICET
url http://hdl.handle.net/11336/38066
identifier_str_mv Pianciola, Betiana Noelia; Lima, Enio Junior; Troiani, Horacio Esteban; Nagamine, Luiz C.C.M.; Cohen, R.; et al.; Size and surface effects in the magnetic order of CoFe2O4 nanoparticles; Elsevier Science; Journal of Magnetism and Magnetic Materials; 377; 3-2015; 44-51
0304-8853
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jmmm.2014.10.054
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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