Creep behaviour of injection moulded polyamide 6/organoclay nanocomposites by nanoindentation and cantilever-bending

Autores
Seltzer, Rocío; Yiu-wing Mai; Frontini, Patricia Maria
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The creep behaviour of injection moulded PA 6/organoclay nanocomposites was studied by depth-sensing nanoindentation and DMA cantilever-bending. The glass transitions of PA 6 and its nanocomposites were decreased below room temperature upon saturation with water so that the materials could be tested in the rubbery regime. For nanoindentation creep on the skin and core regions of injection moulded samples, whilst organoclay improves the creep resistance of PA 6, the enhancement is due to the decrease of the initial compliance at zero time but the time-dependent creep is actually increased. In contrast, for cantilever-bending creep, organoclay reduces the creep compliance and the time-dependent creep in PA 6. It is suggested that the organoclay imparts a constraint effect on the PA 6 molecular chains, restricting their mobility in the bulk compared to the surface and hence improving their resistance to creep. A modified Halpin–Tsai equation was used to model their creep behaviour under these two loading configurations and compared to experimental data.
Fil: Seltzer, Rocío. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina. The University of Sydney; Australia
Fil: Yiu-wing Mai. The University of Sydney; Australia
Fil: Frontini, Patricia Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Materia
Polymer-Matrix Composites (Pmcs)
Creep
Mechanical Testing
Depth-Sensing Indentation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/6296
Acceder
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network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Creep behaviour of injection moulded polyamide 6/organoclay nanocomposites by nanoindentation and cantilever-bendingSeltzer, RocíoYiu-wing MaiFrontini, Patricia MariaPolymer-Matrix Composites (Pmcs)CreepMechanical TestingDepth-Sensing Indentationhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The creep behaviour of injection moulded PA 6/organoclay nanocomposites was studied by depth-sensing nanoindentation and DMA cantilever-bending. The glass transitions of PA 6 and its nanocomposites were decreased below room temperature upon saturation with water so that the materials could be tested in the rubbery regime. For nanoindentation creep on the skin and core regions of injection moulded samples, whilst organoclay improves the creep resistance of PA 6, the enhancement is due to the decrease of the initial compliance at zero time but the time-dependent creep is actually increased. In contrast, for cantilever-bending creep, organoclay reduces the creep compliance and the time-dependent creep in PA 6. It is suggested that the organoclay imparts a constraint effect on the PA 6 molecular chains, restricting their mobility in the bulk compared to the surface and hence improving their resistance to creep. A modified Halpin–Tsai equation was used to model their creep behaviour under these two loading configurations and compared to experimental data.Fil: Seltzer, Rocío. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina. The University of Sydney; AustraliaFil: Yiu-wing Mai. The University of Sydney; AustraliaFil: Frontini, Patricia Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaElsevier2011-04-28info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/6296Seltzer, Rocío; Yiu-wing Mai; Frontini, Patricia Maria; Creep behaviour of injection moulded polyamide 6/organoclay nanocomposites by nanoindentation and cantilever-bending; Elsevier; Composites Part B: Engineering; 43; 1; 28-4-2011; 83-891359-8368enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1359836811001764info:eu-repo/semantics/altIdentifier/doi/10.1016/j.compositesb.2011.04.035info:eu-repo/semantics/altIdentifier/issn/1359-8368info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:35:20Zoai:ri.conicet.gov.ar:11336/6296instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:35:20.971CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Creep behaviour of injection moulded polyamide 6/organoclay nanocomposites by nanoindentation and cantilever-bending
title Creep behaviour of injection moulded polyamide 6/organoclay nanocomposites by nanoindentation and cantilever-bending
spellingShingle Creep behaviour of injection moulded polyamide 6/organoclay nanocomposites by nanoindentation and cantilever-bending
Seltzer, Rocío
Polymer-Matrix Composites (Pmcs)
Creep
Mechanical Testing
Depth-Sensing Indentation
title_short Creep behaviour of injection moulded polyamide 6/organoclay nanocomposites by nanoindentation and cantilever-bending
title_full Creep behaviour of injection moulded polyamide 6/organoclay nanocomposites by nanoindentation and cantilever-bending
title_fullStr Creep behaviour of injection moulded polyamide 6/organoclay nanocomposites by nanoindentation and cantilever-bending
title_full_unstemmed Creep behaviour of injection moulded polyamide 6/organoclay nanocomposites by nanoindentation and cantilever-bending
title_sort Creep behaviour of injection moulded polyamide 6/organoclay nanocomposites by nanoindentation and cantilever-bending
dc.creator.none.fl_str_mv Seltzer, Rocío
Yiu-wing Mai
Frontini, Patricia Maria
author Seltzer, Rocío
author_facet Seltzer, Rocío
Yiu-wing Mai
Frontini, Patricia Maria
author_role author
author2 Yiu-wing Mai
Frontini, Patricia Maria
author2_role author
author
dc.subject.none.fl_str_mv Polymer-Matrix Composites (Pmcs)
Creep
Mechanical Testing
Depth-Sensing Indentation
topic Polymer-Matrix Composites (Pmcs)
Creep
Mechanical Testing
Depth-Sensing Indentation
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The creep behaviour of injection moulded PA 6/organoclay nanocomposites was studied by depth-sensing nanoindentation and DMA cantilever-bending. The glass transitions of PA 6 and its nanocomposites were decreased below room temperature upon saturation with water so that the materials could be tested in the rubbery regime. For nanoindentation creep on the skin and core regions of injection moulded samples, whilst organoclay improves the creep resistance of PA 6, the enhancement is due to the decrease of the initial compliance at zero time but the time-dependent creep is actually increased. In contrast, for cantilever-bending creep, organoclay reduces the creep compliance and the time-dependent creep in PA 6. It is suggested that the organoclay imparts a constraint effect on the PA 6 molecular chains, restricting their mobility in the bulk compared to the surface and hence improving their resistance to creep. A modified Halpin–Tsai equation was used to model their creep behaviour under these two loading configurations and compared to experimental data.
Fil: Seltzer, Rocío. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina. The University of Sydney; Australia
Fil: Yiu-wing Mai. The University of Sydney; Australia
Fil: Frontini, Patricia Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
description The creep behaviour of injection moulded PA 6/organoclay nanocomposites was studied by depth-sensing nanoindentation and DMA cantilever-bending. The glass transitions of PA 6 and its nanocomposites were decreased below room temperature upon saturation with water so that the materials could be tested in the rubbery regime. For nanoindentation creep on the skin and core regions of injection moulded samples, whilst organoclay improves the creep resistance of PA 6, the enhancement is due to the decrease of the initial compliance at zero time but the time-dependent creep is actually increased. In contrast, for cantilever-bending creep, organoclay reduces the creep compliance and the time-dependent creep in PA 6. It is suggested that the organoclay imparts a constraint effect on the PA 6 molecular chains, restricting their mobility in the bulk compared to the surface and hence improving their resistance to creep. A modified Halpin–Tsai equation was used to model their creep behaviour under these two loading configurations and compared to experimental data.
publishDate 2011
dc.date.none.fl_str_mv 2011-04-28
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/6296
Seltzer, Rocío; Yiu-wing Mai; Frontini, Patricia Maria; Creep behaviour of injection moulded polyamide 6/organoclay nanocomposites by nanoindentation and cantilever-bending; Elsevier; Composites Part B: Engineering; 43; 1; 28-4-2011; 83-89
1359-8368
url http://hdl.handle.net/11336/6296
identifier_str_mv Seltzer, Rocío; Yiu-wing Mai; Frontini, Patricia Maria; Creep behaviour of injection moulded polyamide 6/organoclay nanocomposites by nanoindentation and cantilever-bending; Elsevier; Composites Part B: Engineering; 43; 1; 28-4-2011; 83-89
1359-8368
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1359836811001764
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.compositesb.2011.04.035
info:eu-repo/semantics/altIdentifier/issn/1359-8368
info:eu-repo/semantics/altIdentifier/doi/
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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