Influences of secondary phases on ferroelectric properties of Bi(Na,K)TiO3 ceramics

Autores
Ramajo, Leandro Alfredo; Camargo, Javier Eduardo; Rubio Marcos, Fernando; Castro, Miriam Susana
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The effect of secondary phases on ferroelectric properties of Bi0.5(Na0.8K0.2)0.5TiO3 (BNKT) is studied. Ceramic powders are prepared by the solid-state reaction method where the influence of different sintering temperatures is also studied. Then, samples are characterized by X-ray diffraction (XRD), Raman microspectroscopy, Scanning Electron Microscopy and impedance spectroscopy. Through XRD and Raman results,the perovskite structure is detected; together with small peaks corresponding to a secondary phase associated with a K2xNaxTi6O13-based phase. The secondary phases amount increases with the sintering temperature, yielding different combinations of K2xNaxTi6O13- and Bi0.5(Na1yKy)0.5 TiO3-based phases. Moreover, the content of the secondary phase improves the d33 piezoelectric constant and dielectric properties of BNKT ceramics. These results can benefit the understanding of BNKT ceramics and the expanding of their applications range.
Fil: Ramajo, Leandro Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Camargo, Javier Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Rubio Marcos, Fernando. Instituto de Ceramica y Vidrio de Madrid; España
Fil: Castro, Miriam Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Materia
Powders: Solid State Reaction
Ferroelectric Properties
Piezoelectric Properties
Perovskites
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/10427

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network_name_str CONICET Digital (CONICET)
spelling Influences of secondary phases on ferroelectric properties of Bi(Na,K)TiO3 ceramicsRamajo, Leandro AlfredoCamargo, Javier EduardoRubio Marcos, FernandoCastro, Miriam SusanaPowders: Solid State ReactionFerroelectric PropertiesPiezoelectric PropertiesPerovskiteshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The effect of secondary phases on ferroelectric properties of Bi0.5(Na0.8K0.2)0.5TiO3 (BNKT) is studied. Ceramic powders are prepared by the solid-state reaction method where the influence of different sintering temperatures is also studied. Then, samples are characterized by X-ray diffraction (XRD), Raman microspectroscopy, Scanning Electron Microscopy and impedance spectroscopy. Through XRD and Raman results,the perovskite structure is detected; together with small peaks corresponding to a secondary phase associated with a K2xNaxTi6O13-based phase. The secondary phases amount increases with the sintering temperature, yielding different combinations of K2xNaxTi6O13- and Bi0.5(Na1yKy)0.5 TiO3-based phases. Moreover, the content of the secondary phase improves the d33 piezoelectric constant and dielectric properties of BNKT ceramics. These results can benefit the understanding of BNKT ceramics and the expanding of their applications range.Fil: Ramajo, Leandro Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Camargo, Javier Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Rubio Marcos, Fernando. Instituto de Ceramica y Vidrio de Madrid; EspañaFil: Castro, Miriam Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaElsevier2014-12-24info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/10427Ramajo, Leandro Alfredo; Camargo, Javier Eduardo; Rubio Marcos, Fernando; Castro, Miriam Susana; Influences of secondary phases on ferroelectric properties of Bi(Na,K)TiO3 ceramics; Elsevier; Ceramics International; 41; 4; 24-12-2014; 5380-53860272-8842enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0272884214020215info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ceramint.2014.12.100info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:53:16Zoai:ri.conicet.gov.ar:11336/10427instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:53:16.959CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Influences of secondary phases on ferroelectric properties of Bi(Na,K)TiO3 ceramics
title Influences of secondary phases on ferroelectric properties of Bi(Na,K)TiO3 ceramics
spellingShingle Influences of secondary phases on ferroelectric properties of Bi(Na,K)TiO3 ceramics
Ramajo, Leandro Alfredo
Powders: Solid State Reaction
Ferroelectric Properties
Piezoelectric Properties
Perovskites
title_short Influences of secondary phases on ferroelectric properties of Bi(Na,K)TiO3 ceramics
title_full Influences of secondary phases on ferroelectric properties of Bi(Na,K)TiO3 ceramics
title_fullStr Influences of secondary phases on ferroelectric properties of Bi(Na,K)TiO3 ceramics
title_full_unstemmed Influences of secondary phases on ferroelectric properties of Bi(Na,K)TiO3 ceramics
title_sort Influences of secondary phases on ferroelectric properties of Bi(Na,K)TiO3 ceramics
dc.creator.none.fl_str_mv Ramajo, Leandro Alfredo
Camargo, Javier Eduardo
Rubio Marcos, Fernando
Castro, Miriam Susana
author Ramajo, Leandro Alfredo
author_facet Ramajo, Leandro Alfredo
Camargo, Javier Eduardo
Rubio Marcos, Fernando
Castro, Miriam Susana
author_role author
author2 Camargo, Javier Eduardo
Rubio Marcos, Fernando
Castro, Miriam Susana
author2_role author
author
author
dc.subject.none.fl_str_mv Powders: Solid State Reaction
Ferroelectric Properties
Piezoelectric Properties
Perovskites
topic Powders: Solid State Reaction
Ferroelectric Properties
Piezoelectric Properties
Perovskites
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The effect of secondary phases on ferroelectric properties of Bi0.5(Na0.8K0.2)0.5TiO3 (BNKT) is studied. Ceramic powders are prepared by the solid-state reaction method where the influence of different sintering temperatures is also studied. Then, samples are characterized by X-ray diffraction (XRD), Raman microspectroscopy, Scanning Electron Microscopy and impedance spectroscopy. Through XRD and Raman results,the perovskite structure is detected; together with small peaks corresponding to a secondary phase associated with a K2xNaxTi6O13-based phase. The secondary phases amount increases with the sintering temperature, yielding different combinations of K2xNaxTi6O13- and Bi0.5(Na1yKy)0.5 TiO3-based phases. Moreover, the content of the secondary phase improves the d33 piezoelectric constant and dielectric properties of BNKT ceramics. These results can benefit the understanding of BNKT ceramics and the expanding of their applications range.
Fil: Ramajo, Leandro Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Camargo, Javier Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Rubio Marcos, Fernando. Instituto de Ceramica y Vidrio de Madrid; España
Fil: Castro, Miriam Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
description The effect of secondary phases on ferroelectric properties of Bi0.5(Na0.8K0.2)0.5TiO3 (BNKT) is studied. Ceramic powders are prepared by the solid-state reaction method where the influence of different sintering temperatures is also studied. Then, samples are characterized by X-ray diffraction (XRD), Raman microspectroscopy, Scanning Electron Microscopy and impedance spectroscopy. Through XRD and Raman results,the perovskite structure is detected; together with small peaks corresponding to a secondary phase associated with a K2xNaxTi6O13-based phase. The secondary phases amount increases with the sintering temperature, yielding different combinations of K2xNaxTi6O13- and Bi0.5(Na1yKy)0.5 TiO3-based phases. Moreover, the content of the secondary phase improves the d33 piezoelectric constant and dielectric properties of BNKT ceramics. These results can benefit the understanding of BNKT ceramics and the expanding of their applications range.
publishDate 2014
dc.date.none.fl_str_mv 2014-12-24
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/10427
Ramajo, Leandro Alfredo; Camargo, Javier Eduardo; Rubio Marcos, Fernando; Castro, Miriam Susana; Influences of secondary phases on ferroelectric properties of Bi(Na,K)TiO3 ceramics; Elsevier; Ceramics International; 41; 4; 24-12-2014; 5380-5386
0272-8842
url http://hdl.handle.net/11336/10427
identifier_str_mv Ramajo, Leandro Alfredo; Camargo, Javier Eduardo; Rubio Marcos, Fernando; Castro, Miriam Susana; Influences of secondary phases on ferroelectric properties of Bi(Na,K)TiO3 ceramics; Elsevier; Ceramics International; 41; 4; 24-12-2014; 5380-5386
0272-8842
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0272884214020215
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ceramint.2014.12.100
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
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application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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