Expanding the toolbox for enantioselective sulfide oxidations: Streptomyces strains as biocatalysts

Autores
Mascotti, María Laura; Palazzolo, Martín Alejandro; Lewkowicz, Elizabeth Sandra; Kurina Sanz, Marcela Beatriz
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Sulfide oxidase activity ofStreptomyces genus is reported here for the first time. Three Streptomyces strains were selected as new tools to access to enantioenriched R- and S-dialkyl sulfoxides. The bacterial screening was carried out using cyclohexyl methyl sulfide as model substrate.Both sulfoxide antipodes were obtained in a one-pot, time-dependent biotransformation employing S. phaeochromogenes NCIMB 11741 as biocatalyst. S. flavogriseus ATCC 33331produced mainly the S-enantiomer, while S. hiroshimensis ATCC 27429 yielded enantiopure R-cyclohexyl methyl sulfoxide.
Fil: Mascotti, María Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Palazzolo, Martín Alejandro. Universidad Nacional de Quilmes. Departamento de Ciencia y Tecnología. Area Química. Laboratorio de Biotransformaciones; Argentina
Fil: Lewkowicz, Elizabeth Sandra. Universidad Nacional de Quilmes. Departamento de Ciencia y Tecnología. Area Química. Laboratorio de Biotransformaciones; Argentina
Fil: Kurina Sanz, Marcela Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones en Tecnología Química; Argentina
Materia
Asymmetric Sulfoxidation
Dialkyl Sulfides
Streptomyces
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/2969
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Expanding the toolbox for enantioselective sulfide oxidations: Streptomyces strains as biocatalystsMascotti, María LauraPalazzolo, Martín AlejandroLewkowicz, Elizabeth SandraKurina Sanz, Marcela BeatrizAsymmetric SulfoxidationDialkyl SulfidesStreptomyceshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Sulfide oxidase activity ofStreptomyces genus is reported here for the first time. Three Streptomyces strains were selected as new tools to access to enantioenriched R- and S-dialkyl sulfoxides. The bacterial screening was carried out using cyclohexyl methyl sulfide as model substrate.Both sulfoxide antipodes were obtained in a one-pot, time-dependent biotransformation employing S. phaeochromogenes NCIMB 11741 as biocatalyst. S. flavogriseus ATCC 33331produced mainly the S-enantiomer, while S. hiroshimensis ATCC 27429 yielded enantiopure R-cyclohexyl methyl sulfoxide.Fil: Mascotti, María Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Palazzolo, Martín Alejandro. Universidad Nacional de Quilmes. Departamento de Ciencia y Tecnología. Area Química. Laboratorio de Biotransformaciones; ArgentinaFil: Lewkowicz, Elizabeth Sandra. Universidad Nacional de Quilmes. Departamento de Ciencia y Tecnología. Area Química. Laboratorio de Biotransformaciones; ArgentinaFil: Kurina Sanz, Marcela Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones en Tecnología Química; ArgentinaElsevier2013-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/2969Mascotti, María Laura; Palazzolo, Martín Alejandro; Lewkowicz, Elizabeth Sandra; Kurina Sanz, Marcela Beatriz; Expanding the toolbox for enantioselective sulfide oxidations: Streptomyces strains as biocatalysts; Elsevier; Biocatalysis and Agricultural Biotechnology; 2; 4; 10-2013; 399-4021878-8181enginfo:eu-repo/semantics/altIdentifier/issn/1878-8181info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1878818113000959info:eu-repo/semantics/altIdentifier/doi/10.1016/j.bcab.2013.08.003info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:05:56Zoai:ri.conicet.gov.ar:11336/2969instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:05:56.378CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Expanding the toolbox for enantioselective sulfide oxidations: Streptomyces strains as biocatalysts
title Expanding the toolbox for enantioselective sulfide oxidations: Streptomyces strains as biocatalysts
spellingShingle Expanding the toolbox for enantioselective sulfide oxidations: Streptomyces strains as biocatalysts
Mascotti, María Laura
Asymmetric Sulfoxidation
Dialkyl Sulfides
Streptomyces
title_short Expanding the toolbox for enantioselective sulfide oxidations: Streptomyces strains as biocatalysts
title_full Expanding the toolbox for enantioselective sulfide oxidations: Streptomyces strains as biocatalysts
title_fullStr Expanding the toolbox for enantioselective sulfide oxidations: Streptomyces strains as biocatalysts
title_full_unstemmed Expanding the toolbox for enantioselective sulfide oxidations: Streptomyces strains as biocatalysts
title_sort Expanding the toolbox for enantioselective sulfide oxidations: Streptomyces strains as biocatalysts
dc.creator.none.fl_str_mv Mascotti, María Laura
Palazzolo, Martín Alejandro
Lewkowicz, Elizabeth Sandra
Kurina Sanz, Marcela Beatriz
author Mascotti, María Laura
author_facet Mascotti, María Laura
Palazzolo, Martín Alejandro
Lewkowicz, Elizabeth Sandra
Kurina Sanz, Marcela Beatriz
author_role author
author2 Palazzolo, Martín Alejandro
Lewkowicz, Elizabeth Sandra
Kurina Sanz, Marcela Beatriz
author2_role author
author
author
dc.subject.none.fl_str_mv Asymmetric Sulfoxidation
Dialkyl Sulfides
Streptomyces
topic Asymmetric Sulfoxidation
Dialkyl Sulfides
Streptomyces
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Sulfide oxidase activity ofStreptomyces genus is reported here for the first time. Three Streptomyces strains were selected as new tools to access to enantioenriched R- and S-dialkyl sulfoxides. The bacterial screening was carried out using cyclohexyl methyl sulfide as model substrate.Both sulfoxide antipodes were obtained in a one-pot, time-dependent biotransformation employing S. phaeochromogenes NCIMB 11741 as biocatalyst. S. flavogriseus ATCC 33331produced mainly the S-enantiomer, while S. hiroshimensis ATCC 27429 yielded enantiopure R-cyclohexyl methyl sulfoxide.
Fil: Mascotti, María Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Palazzolo, Martín Alejandro. Universidad Nacional de Quilmes. Departamento de Ciencia y Tecnología. Area Química. Laboratorio de Biotransformaciones; Argentina
Fil: Lewkowicz, Elizabeth Sandra. Universidad Nacional de Quilmes. Departamento de Ciencia y Tecnología. Area Química. Laboratorio de Biotransformaciones; Argentina
Fil: Kurina Sanz, Marcela Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones en Tecnología Química; Argentina
description Sulfide oxidase activity ofStreptomyces genus is reported here for the first time. Three Streptomyces strains were selected as new tools to access to enantioenriched R- and S-dialkyl sulfoxides. The bacterial screening was carried out using cyclohexyl methyl sulfide as model substrate.Both sulfoxide antipodes were obtained in a one-pot, time-dependent biotransformation employing S. phaeochromogenes NCIMB 11741 as biocatalyst. S. flavogriseus ATCC 33331produced mainly the S-enantiomer, while S. hiroshimensis ATCC 27429 yielded enantiopure R-cyclohexyl methyl sulfoxide.
publishDate 2013
dc.date.none.fl_str_mv 2013-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/2969
Mascotti, María Laura; Palazzolo, Martín Alejandro; Lewkowicz, Elizabeth Sandra; Kurina Sanz, Marcela Beatriz; Expanding the toolbox for enantioselective sulfide oxidations: Streptomyces strains as biocatalysts; Elsevier; Biocatalysis and Agricultural Biotechnology; 2; 4; 10-2013; 399-402
1878-8181
url http://hdl.handle.net/11336/2969
identifier_str_mv Mascotti, María Laura; Palazzolo, Martín Alejandro; Lewkowicz, Elizabeth Sandra; Kurina Sanz, Marcela Beatriz; Expanding the toolbox for enantioselective sulfide oxidations: Streptomyces strains as biocatalysts; Elsevier; Biocatalysis and Agricultural Biotechnology; 2; 4; 10-2013; 399-402
1878-8181
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/1878-8181
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1878818113000959
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.bcab.2013.08.003
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846781348880056320
score 12.982451

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