A crystallization and structural study of the compound Pb2V2O7 synthesized by a facile sol–gel-based chemical route

Autores
Suárez Gómez, A.; Figueroa, Santiago Jose Alejandro; Lamas, Diego Germán; Cezar, Julio C.
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work, we carried out the synthesis of lead(II) divanadate(V) by means of a soft chemistry reaction based on a sol–gel-derived route. The final organic precursor was heat treated (T = 400, 500, 600, 750 and 800 °C) and structurally analyzed for each temperature by taking into account the results of FTIR spectroscopy, synchrotron X-ray powder diffraction and X-ray absorption near-edge structure. As an overall result, we report a final compound with remarkable crystallographic and morphological qualities that seem to keep all its structural features in the temperature range 450–700 °C before the structure incongruently melts. As a highlight, the desired material was obtained following a highly reproducible, low-cost, low-temperature and quite straightforward chemical route. Besides, this synthesis route could also allow the appropriate integration of lead(II) divanadate(V) nanoparticles, or nanolayers, into more complex systems as well as the feasibility for being expanded to other materials.
Fil: Suárez Gómez, A.. Universidad de Guadalajara; México
Fil: Figueroa, Santiago Jose Alejandro. Brazilian Center of Energy and Materials; Brasil. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Lamas, Diego Germán. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina
Fil: Cezar, Julio C.. Brazilian Center of Energy and Materials; Brasil
Materia
Divanadates
Synchrotron
Pb2v2o7
Sol Gel
Nanoparticles
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/41728
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling A crystallization and structural study of the compound Pb2V2O7 synthesized by a facile sol–gel-based chemical routeSuárez Gómez, A.Figueroa, Santiago Jose AlejandroLamas, Diego GermánCezar, Julio C.DivanadatesSynchrotronPb2v2o7Sol GelNanoparticleshttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2In this work, we carried out the synthesis of lead(II) divanadate(V) by means of a soft chemistry reaction based on a sol–gel-derived route. The final organic precursor was heat treated (T = 400, 500, 600, 750 and 800 °C) and structurally analyzed for each temperature by taking into account the results of FTIR spectroscopy, synchrotron X-ray powder diffraction and X-ray absorption near-edge structure. As an overall result, we report a final compound with remarkable crystallographic and morphological qualities that seem to keep all its structural features in the temperature range 450–700 °C before the structure incongruently melts. As a highlight, the desired material was obtained following a highly reproducible, low-cost, low-temperature and quite straightforward chemical route. Besides, this synthesis route could also allow the appropriate integration of lead(II) divanadate(V) nanoparticles, or nanolayers, into more complex systems as well as the feasibility for being expanded to other materials.Fil: Suárez Gómez, A.. Universidad de Guadalajara; MéxicoFil: Figueroa, Santiago Jose Alejandro. Brazilian Center of Energy and Materials; Brasil. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Lamas, Diego Germán. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; ArgentinaFil: Cezar, Julio C.. Brazilian Center of Energy and Materials; BrasilSpringer2015-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/41728Suárez Gómez, A.; Figueroa, Santiago Jose Alejandro; Lamas, Diego Germán; Cezar, Julio C.; A crystallization and structural study of the compound Pb2V2O7 synthesized by a facile sol–gel-based chemical route; Springer; Journal of Sol-Gel Science and Technology; 75; 2; 4-2015; 291-2970928-07071573-4846CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1007/s10971-015-3698-0info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007/s10971-015-3698-0info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:01:26Zoai:ri.conicet.gov.ar:11336/41728instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:01:26.883CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A crystallization and structural study of the compound Pb2V2O7 synthesized by a facile sol–gel-based chemical route
title A crystallization and structural study of the compound Pb2V2O7 synthesized by a facile sol–gel-based chemical route
spellingShingle A crystallization and structural study of the compound Pb2V2O7 synthesized by a facile sol–gel-based chemical route
Suárez Gómez, A.
Divanadates
Synchrotron
Pb2v2o7
Sol Gel
Nanoparticles
title_short A crystallization and structural study of the compound Pb2V2O7 synthesized by a facile sol–gel-based chemical route
title_full A crystallization and structural study of the compound Pb2V2O7 synthesized by a facile sol–gel-based chemical route
title_fullStr A crystallization and structural study of the compound Pb2V2O7 synthesized by a facile sol–gel-based chemical route
title_full_unstemmed A crystallization and structural study of the compound Pb2V2O7 synthesized by a facile sol–gel-based chemical route
title_sort A crystallization and structural study of the compound Pb2V2O7 synthesized by a facile sol–gel-based chemical route
dc.creator.none.fl_str_mv Suárez Gómez, A.
Figueroa, Santiago Jose Alejandro
Lamas, Diego Germán
Cezar, Julio C.
author Suárez Gómez, A.
author_facet Suárez Gómez, A.
Figueroa, Santiago Jose Alejandro
Lamas, Diego Germán
Cezar, Julio C.
author_role author
author2 Figueroa, Santiago Jose Alejandro
Lamas, Diego Germán
Cezar, Julio C.
author2_role author
author
author
dc.subject.none.fl_str_mv Divanadates
Synchrotron
Pb2v2o7
Sol Gel
Nanoparticles
topic Divanadates
Synchrotron
Pb2v2o7
Sol Gel
Nanoparticles
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In this work, we carried out the synthesis of lead(II) divanadate(V) by means of a soft chemistry reaction based on a sol–gel-derived route. The final organic precursor was heat treated (T = 400, 500, 600, 750 and 800 °C) and structurally analyzed for each temperature by taking into account the results of FTIR spectroscopy, synchrotron X-ray powder diffraction and X-ray absorption near-edge structure. As an overall result, we report a final compound with remarkable crystallographic and morphological qualities that seem to keep all its structural features in the temperature range 450–700 °C before the structure incongruently melts. As a highlight, the desired material was obtained following a highly reproducible, low-cost, low-temperature and quite straightforward chemical route. Besides, this synthesis route could also allow the appropriate integration of lead(II) divanadate(V) nanoparticles, or nanolayers, into more complex systems as well as the feasibility for being expanded to other materials.
Fil: Suárez Gómez, A.. Universidad de Guadalajara; México
Fil: Figueroa, Santiago Jose Alejandro. Brazilian Center of Energy and Materials; Brasil. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Lamas, Diego Germán. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina
Fil: Cezar, Julio C.. Brazilian Center of Energy and Materials; Brasil
description In this work, we carried out the synthesis of lead(II) divanadate(V) by means of a soft chemistry reaction based on a sol–gel-derived route. The final organic precursor was heat treated (T = 400, 500, 600, 750 and 800 °C) and structurally analyzed for each temperature by taking into account the results of FTIR spectroscopy, synchrotron X-ray powder diffraction and X-ray absorption near-edge structure. As an overall result, we report a final compound with remarkable crystallographic and morphological qualities that seem to keep all its structural features in the temperature range 450–700 °C before the structure incongruently melts. As a highlight, the desired material was obtained following a highly reproducible, low-cost, low-temperature and quite straightforward chemical route. Besides, this synthesis route could also allow the appropriate integration of lead(II) divanadate(V) nanoparticles, or nanolayers, into more complex systems as well as the feasibility for being expanded to other materials.
publishDate 2015
dc.date.none.fl_str_mv 2015-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/41728
Suárez Gómez, A.; Figueroa, Santiago Jose Alejandro; Lamas, Diego Germán; Cezar, Julio C.; A crystallization and structural study of the compound Pb2V2O7 synthesized by a facile sol–gel-based chemical route; Springer; Journal of Sol-Gel Science and Technology; 75; 2; 4-2015; 291-297
0928-0707
1573-4846
CONICET Digital
CONICET
url http://hdl.handle.net/11336/41728
identifier_str_mv Suárez Gómez, A.; Figueroa, Santiago Jose Alejandro; Lamas, Diego Germán; Cezar, Julio C.; A crystallization and structural study of the compound Pb2V2O7 synthesized by a facile sol–gel-based chemical route; Springer; Journal of Sol-Gel Science and Technology; 75; 2; 4-2015; 291-297
0928-0707
1573-4846
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1007/s10971-015-3698-0
info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007/s10971-015-3698-0
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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