Additional constraints in adsorption-desorption kinetics
- Autores
- Manzi, Sergio Javier; Belardinelli, Rolando Elio; Costanza, Gregorio José; Pereyra, Victor Daniel
- Año de publicación
- 2009
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- In this work, the adsorption-desorption kinetic in the framework of the lattice gas model is analyzed. The transition probabilities are written as an expansion of the occupation configurations. Due to that, the detail balance principle determine half of the adsorption Ai and desorption Di coefficients, consequently, different functional relations between them are proposed. Introducing additional constrains, it is demonstrated that when those coefficients are linearly related through a parameter γ, there are values of lateral interaction V, that lead to anomalous behavior in the adsorption isotherms, the sticking coefficient and the thermal programmed desorption spectra. Diagrams for the allowed values of V and γ are also shown. Alternatively, a more reliable formulation for the adsorption desorption kinetic based on the transition state theory is introduced. In such way the equilibrium and non equilibrium observables do not present anomalous or inconsistent behavior.
Fil: Manzi, Sergio Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Belardinelli, Rolando Elio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Costanza, Gregorio José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Pereyra, Victor Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Matemática Aplicada de San Luis "Prof. Ezio Marchi". Universidad Nacional de San Luis. Facultad de Ciencias Físico, Matemáticas y Naturales. Instituto de Matemática Aplicada de San Luis "Prof. Ezio Marchi"; Argentina - Materia
-
PROBABILITY THEORY, STOCHASTIC PROCESSES, AND STATISTICS
ADSORPTION KINETICS
DESORPTION KINETICS
LATTICE GAS - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/137126
Ver los metadatos del registro completo
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Additional constraints in adsorption-desorption kineticsManzi, Sergio JavierBelardinelli, Rolando ElioCostanza, Gregorio JoséPereyra, Victor DanielPROBABILITY THEORY, STOCHASTIC PROCESSES, AND STATISTICSADSORPTION KINETICSDESORPTION KINETICSLATTICE GAShttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1In this work, the adsorption-desorption kinetic in the framework of the lattice gas model is analyzed. The transition probabilities are written as an expansion of the occupation configurations. Due to that, the detail balance principle determine half of the adsorption Ai and desorption Di coefficients, consequently, different functional relations between them are proposed. Introducing additional constrains, it is demonstrated that when those coefficients are linearly related through a parameter γ, there are values of lateral interaction V, that lead to anomalous behavior in the adsorption isotherms, the sticking coefficient and the thermal programmed desorption spectra. Diagrams for the allowed values of V and γ are also shown. Alternatively, a more reliable formulation for the adsorption desorption kinetic based on the transition state theory is introduced. In such way the equilibrium and non equilibrium observables do not present anomalous or inconsistent behavior.Fil: Manzi, Sergio Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; ArgentinaFil: Belardinelli, Rolando Elio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; ArgentinaFil: Costanza, Gregorio José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; ArgentinaFil: Pereyra, Victor Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Matemática Aplicada de San Luis "Prof. Ezio Marchi". Universidad Nacional de San Luis. Facultad de Ciencias Físico, Matemáticas y Naturales. Instituto de Matemática Aplicada de San Luis "Prof. Ezio Marchi"; ArgentinaAmerican Physical Society2009-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/137126Manzi, Sergio Javier; Belardinelli, Rolando Elio; Costanza, Gregorio José; Pereyra, Victor Daniel; Additional constraints in adsorption-desorption kinetics; American Physical Society; Physical Review E: Statistical, Nonlinear and Soft Matter Physics; 79; 2; 2-2009; 1-10; 0211031539-3755CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1103/PhysRevE.79.021103info:eu-repo/semantics/altIdentifier/url/https://journals.aps.org/pre/abstract/10.1103/PhysRevE.79.021103info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:24:49Zoai:ri.conicet.gov.ar:11336/137126instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:24:49.373CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Additional constraints in adsorption-desorption kinetics |
title |
Additional constraints in adsorption-desorption kinetics |
spellingShingle |
Additional constraints in adsorption-desorption kinetics Manzi, Sergio Javier PROBABILITY THEORY, STOCHASTIC PROCESSES, AND STATISTICS ADSORPTION KINETICS DESORPTION KINETICS LATTICE GAS |
title_short |
Additional constraints in adsorption-desorption kinetics |
title_full |
Additional constraints in adsorption-desorption kinetics |
title_fullStr |
Additional constraints in adsorption-desorption kinetics |
title_full_unstemmed |
Additional constraints in adsorption-desorption kinetics |
title_sort |
Additional constraints in adsorption-desorption kinetics |
dc.creator.none.fl_str_mv |
Manzi, Sergio Javier Belardinelli, Rolando Elio Costanza, Gregorio José Pereyra, Victor Daniel |
author |
Manzi, Sergio Javier |
author_facet |
Manzi, Sergio Javier Belardinelli, Rolando Elio Costanza, Gregorio José Pereyra, Victor Daniel |
author_role |
author |
author2 |
Belardinelli, Rolando Elio Costanza, Gregorio José Pereyra, Victor Daniel |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
PROBABILITY THEORY, STOCHASTIC PROCESSES, AND STATISTICS ADSORPTION KINETICS DESORPTION KINETICS LATTICE GAS |
topic |
PROBABILITY THEORY, STOCHASTIC PROCESSES, AND STATISTICS ADSORPTION KINETICS DESORPTION KINETICS LATTICE GAS |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.3 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
In this work, the adsorption-desorption kinetic in the framework of the lattice gas model is analyzed. The transition probabilities are written as an expansion of the occupation configurations. Due to that, the detail balance principle determine half of the adsorption Ai and desorption Di coefficients, consequently, different functional relations between them are proposed. Introducing additional constrains, it is demonstrated that when those coefficients are linearly related through a parameter γ, there are values of lateral interaction V, that lead to anomalous behavior in the adsorption isotherms, the sticking coefficient and the thermal programmed desorption spectra. Diagrams for the allowed values of V and γ are also shown. Alternatively, a more reliable formulation for the adsorption desorption kinetic based on the transition state theory is introduced. In such way the equilibrium and non equilibrium observables do not present anomalous or inconsistent behavior. Fil: Manzi, Sergio Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina Fil: Belardinelli, Rolando Elio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina Fil: Costanza, Gregorio José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina Fil: Pereyra, Victor Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Matemática Aplicada de San Luis "Prof. Ezio Marchi". Universidad Nacional de San Luis. Facultad de Ciencias Físico, Matemáticas y Naturales. Instituto de Matemática Aplicada de San Luis "Prof. Ezio Marchi"; Argentina |
description |
In this work, the adsorption-desorption kinetic in the framework of the lattice gas model is analyzed. The transition probabilities are written as an expansion of the occupation configurations. Due to that, the detail balance principle determine half of the adsorption Ai and desorption Di coefficients, consequently, different functional relations between them are proposed. Introducing additional constrains, it is demonstrated that when those coefficients are linearly related through a parameter γ, there are values of lateral interaction V, that lead to anomalous behavior in the adsorption isotherms, the sticking coefficient and the thermal programmed desorption spectra. Diagrams for the allowed values of V and γ are also shown. Alternatively, a more reliable formulation for the adsorption desorption kinetic based on the transition state theory is introduced. In such way the equilibrium and non equilibrium observables do not present anomalous or inconsistent behavior. |
publishDate |
2009 |
dc.date.none.fl_str_mv |
2009-02 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/137126 Manzi, Sergio Javier; Belardinelli, Rolando Elio; Costanza, Gregorio José; Pereyra, Victor Daniel; Additional constraints in adsorption-desorption kinetics; American Physical Society; Physical Review E: Statistical, Nonlinear and Soft Matter Physics; 79; 2; 2-2009; 1-10; 021103 1539-3755 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/137126 |
identifier_str_mv |
Manzi, Sergio Javier; Belardinelli, Rolando Elio; Costanza, Gregorio José; Pereyra, Victor Daniel; Additional constraints in adsorption-desorption kinetics; American Physical Society; Physical Review E: Statistical, Nonlinear and Soft Matter Physics; 79; 2; 2-2009; 1-10; 021103 1539-3755 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1103/PhysRevE.79.021103 info:eu-repo/semantics/altIdentifier/url/https://journals.aps.org/pre/abstract/10.1103/PhysRevE.79.021103 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
American Physical Society |
publisher.none.fl_str_mv |
American Physical Society |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
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CONICET Digital (CONICET) |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844614245591810048 |
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13.070432 |