Activated dynamics and timescale separation within the landscape paradigm: Signature of complexity, diversity and glassiness

Autores
Appignanesi, Gustavo Adrian; Alarcon, Laureano Martin; Rodriguez Fris, Jorge Ariel; Frechero, Marisa Alejandra; Montani, Rosana A.
Año de publicación
2005
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The landscape paradigm has become a widespread picture within the realm of complex systems. Complex systems include a great variety of systems, ranging from glasses to biopolymers, which display a common dynamical behavior. Within this framework, the dynamics of a such a system can be envisioned as the search it performs on its (potential energy) landscape. This approach rests on the belief that the relaxation behavior depends only on generic features, irrespective of specific details and lies on the validity of a timescale separation scenario computationally corroborated but not properly validated yet form first principles. In this work we shall show that the prevalence of activated dynamics over other kinds of mechanisms determines the emergence of complex dynamical behavior. Thus, complexity and diversity are not intrinsic properties of a system but depend on the kind of exploration of the landscape. We shall focus mainly on an ample generic context (complex hierarchical systems which have been used as models of glasses, spin glasses and biopolymers) and a specific one (model glass formers). For the last case we shall be able to reveal (in mechanistic terms) the microscopic rationale for the occurrence of timescale separation. Furthermore, we shall explore the connections between these two up to now mostly unrelated contexts and the relation to a variational principle, and we shall reveal the conditions for the applicability of the landscape approach.
Fil: Appignanesi, Gustavo Adrian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Alarcon, Laureano Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Rodriguez Fris, Jorge Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Frechero, Marisa Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Montani, Rosana A.. Universidad Nacional del Sur. Departamento de Química; Argentina
Materia
ACTIVATED DYNAMICS
BIOPOLYMER FOLDING
COMPLEX SYSTEMS
GLASSY SYSTEMS
HIERARCHICAL SYSTEMS
MOLECULAR DYNAMICS
RELAXATION
ULTRAMETRIC SPACES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/94248
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/94248
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Activated dynamics and timescale separation within the landscape paradigm: Signature of complexity, diversity and glassinessAppignanesi, Gustavo AdrianAlarcon, Laureano MartinRodriguez Fris, Jorge ArielFrechero, Marisa AlejandraMontani, Rosana A.ACTIVATED DYNAMICSBIOPOLYMER FOLDINGCOMPLEX SYSTEMSGLASSY SYSTEMSHIERARCHICAL SYSTEMSMOLECULAR DYNAMICSRELAXATIONULTRAMETRIC SPACEShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The landscape paradigm has become a widespread picture within the realm of complex systems. Complex systems include a great variety of systems, ranging from glasses to biopolymers, which display a common dynamical behavior. Within this framework, the dynamics of a such a system can be envisioned as the search it performs on its (potential energy) landscape. This approach rests on the belief that the relaxation behavior depends only on generic features, irrespective of specific details and lies on the validity of a timescale separation scenario computationally corroborated but not properly validated yet form first principles. In this work we shall show that the prevalence of activated dynamics over other kinds of mechanisms determines the emergence of complex dynamical behavior. Thus, complexity and diversity are not intrinsic properties of a system but depend on the kind of exploration of the landscape. We shall focus mainly on an ample generic context (complex hierarchical systems which have been used as models of glasses, spin glasses and biopolymers) and a specific one (model glass formers). For the last case we shall be able to reveal (in mechanistic terms) the microscopic rationale for the occurrence of timescale separation. Furthermore, we shall explore the connections between these two up to now mostly unrelated contexts and the relation to a variational principle, and we shall reveal the conditions for the applicability of the landscape approach.Fil: Appignanesi, Gustavo Adrian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Alarcon, Laureano Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Rodriguez Fris, Jorge Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Frechero, Marisa Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Montani, Rosana A.. Universidad Nacional del Sur. Departamento de Química; ArgentinaElsevier Science2005-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/94248Appignanesi, Gustavo Adrian; Alarcon, Laureano Martin; Rodriguez Fris, Jorge Ariel; Frechero, Marisa Alejandra; Montani, Rosana A.; Activated dynamics and timescale separation within the landscape paradigm: Signature of complexity, diversity and glassiness; Elsevier Science; Biophysical Chemistry; 115; 2-3 SPEC. ISS.; 4-2005; 129-1340301-4622CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0301462204003564info:eu-repo/semantics/altIdentifier/doi/10.1016/j.bpc.2004.12.017info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:30:36Zoai:ri.conicet.gov.ar:11336/94248instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:30:36.641CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Activated dynamics and timescale separation within the landscape paradigm: Signature of complexity, diversity and glassiness
title Activated dynamics and timescale separation within the landscape paradigm: Signature of complexity, diversity and glassiness
spellingShingle Activated dynamics and timescale separation within the landscape paradigm: Signature of complexity, diversity and glassiness
Appignanesi, Gustavo Adrian
ACTIVATED DYNAMICS
BIOPOLYMER FOLDING
COMPLEX SYSTEMS
GLASSY SYSTEMS
HIERARCHICAL SYSTEMS
MOLECULAR DYNAMICS
RELAXATION
ULTRAMETRIC SPACES
title_short Activated dynamics and timescale separation within the landscape paradigm: Signature of complexity, diversity and glassiness
title_full Activated dynamics and timescale separation within the landscape paradigm: Signature of complexity, diversity and glassiness
title_fullStr Activated dynamics and timescale separation within the landscape paradigm: Signature of complexity, diversity and glassiness
title_full_unstemmed Activated dynamics and timescale separation within the landscape paradigm: Signature of complexity, diversity and glassiness
title_sort Activated dynamics and timescale separation within the landscape paradigm: Signature of complexity, diversity and glassiness
dc.creator.none.fl_str_mv Appignanesi, Gustavo Adrian
Alarcon, Laureano Martin
Rodriguez Fris, Jorge Ariel
Frechero, Marisa Alejandra
Montani, Rosana A.
author Appignanesi, Gustavo Adrian
author_facet Appignanesi, Gustavo Adrian
Alarcon, Laureano Martin
Rodriguez Fris, Jorge Ariel
Frechero, Marisa Alejandra
Montani, Rosana A.
author_role author
author2 Alarcon, Laureano Martin
Rodriguez Fris, Jorge Ariel
Frechero, Marisa Alejandra
Montani, Rosana A.
author2_role author
author
author
author
dc.subject.none.fl_str_mv ACTIVATED DYNAMICS
BIOPOLYMER FOLDING
COMPLEX SYSTEMS
GLASSY SYSTEMS
HIERARCHICAL SYSTEMS
MOLECULAR DYNAMICS
RELAXATION
ULTRAMETRIC SPACES
topic ACTIVATED DYNAMICS
BIOPOLYMER FOLDING
COMPLEX SYSTEMS
GLASSY SYSTEMS
HIERARCHICAL SYSTEMS
MOLECULAR DYNAMICS
RELAXATION
ULTRAMETRIC SPACES
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The landscape paradigm has become a widespread picture within the realm of complex systems. Complex systems include a great variety of systems, ranging from glasses to biopolymers, which display a common dynamical behavior. Within this framework, the dynamics of a such a system can be envisioned as the search it performs on its (potential energy) landscape. This approach rests on the belief that the relaxation behavior depends only on generic features, irrespective of specific details and lies on the validity of a timescale separation scenario computationally corroborated but not properly validated yet form first principles. In this work we shall show that the prevalence of activated dynamics over other kinds of mechanisms determines the emergence of complex dynamical behavior. Thus, complexity and diversity are not intrinsic properties of a system but depend on the kind of exploration of the landscape. We shall focus mainly on an ample generic context (complex hierarchical systems which have been used as models of glasses, spin glasses and biopolymers) and a specific one (model glass formers). For the last case we shall be able to reveal (in mechanistic terms) the microscopic rationale for the occurrence of timescale separation. Furthermore, we shall explore the connections between these two up to now mostly unrelated contexts and the relation to a variational principle, and we shall reveal the conditions for the applicability of the landscape approach.
Fil: Appignanesi, Gustavo Adrian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Alarcon, Laureano Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Rodriguez Fris, Jorge Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Frechero, Marisa Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Montani, Rosana A.. Universidad Nacional del Sur. Departamento de Química; Argentina
description The landscape paradigm has become a widespread picture within the realm of complex systems. Complex systems include a great variety of systems, ranging from glasses to biopolymers, which display a common dynamical behavior. Within this framework, the dynamics of a such a system can be envisioned as the search it performs on its (potential energy) landscape. This approach rests on the belief that the relaxation behavior depends only on generic features, irrespective of specific details and lies on the validity of a timescale separation scenario computationally corroborated but not properly validated yet form first principles. In this work we shall show that the prevalence of activated dynamics over other kinds of mechanisms determines the emergence of complex dynamical behavior. Thus, complexity and diversity are not intrinsic properties of a system but depend on the kind of exploration of the landscape. We shall focus mainly on an ample generic context (complex hierarchical systems which have been used as models of glasses, spin glasses and biopolymers) and a specific one (model glass formers). For the last case we shall be able to reveal (in mechanistic terms) the microscopic rationale for the occurrence of timescale separation. Furthermore, we shall explore the connections between these two up to now mostly unrelated contexts and the relation to a variational principle, and we shall reveal the conditions for the applicability of the landscape approach.
publishDate 2005
dc.date.none.fl_str_mv 2005-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/94248
Appignanesi, Gustavo Adrian; Alarcon, Laureano Martin; Rodriguez Fris, Jorge Ariel; Frechero, Marisa Alejandra; Montani, Rosana A.; Activated dynamics and timescale separation within the landscape paradigm: Signature of complexity, diversity and glassiness; Elsevier Science; Biophysical Chemistry; 115; 2-3 SPEC. ISS.; 4-2005; 129-134
0301-4622
CONICET Digital
CONICET
url http://hdl.handle.net/11336/94248
identifier_str_mv Appignanesi, Gustavo Adrian; Alarcon, Laureano Martin; Rodriguez Fris, Jorge Ariel; Frechero, Marisa Alejandra; Montani, Rosana A.; Activated dynamics and timescale separation within the landscape paradigm: Signature of complexity, diversity and glassiness; Elsevier Science; Biophysical Chemistry; 115; 2-3 SPEC. ISS.; 4-2005; 129-134
0301-4622
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0301462204003564
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.bpc.2004.12.017
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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