A self-assembled organic/metal junction for water photo-oxidation
- Autores
- Olaya, Astrid J.; Omatsu, Terumasa; Hidalgo-Acosta, Jonnathan C.; Riva, Julieta Soledad; Bassetto, Victor Costa; Gasilova, Natalia; Girault, Hubert
- Año de publicación
- 2019
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- We report the in situ self-assembly of TTF, TTF ·+ , and BF 4 - or PF 6 - into p-type semiconductors on the surface of Pt microparticles dispersed in water/acetonitrile mixtures. The visible light photoactivation of these self-assemblies leads to water oxidation forming O 2 and H + , with an efficiency of 100% with respect to the initial concentration of TTF ·+ . TTF ·+ is then completely reduced to TTF upon photoreduction with water. The Pt microparticles act as floating microelectrodes whose Fermi level is imposed by the different redox species in solution; here predominantly TTF, TTF ·+ , and HTTF + , which furthermore showed no signs of decomposition in solution.
Fil: Olaya, Astrid J.. Swiss Federal Institute Of Technology Epfl; Suiza
Fil: Omatsu, Terumasa. Kyoto Institute Of Technology; Japón
Fil: Hidalgo-Acosta, Jonnathan C.. Swiss Federal Institute Of Technology Epfl; Suiza
Fil: Riva, Julieta Soledad. Swiss Federal Institute Of Technology Epfl; Suiza. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Bassetto, Victor Costa. Swiss Federal Institute Of Technology Epfl; Suiza
Fil: Gasilova, Natalia. Swiss Federal Institute Of Technology Epfl; Suiza
Fil: Girault, Hubert. Swiss Federal Institute Of Technology Epfl; Suiza - Materia
-
WATER OXIDATION
SELF_ASSEMBLY
TETRATHIAFULVALENE
REDOX ELECTROCATALYSIS
PHOTOCATALYSIS - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/112329
Ver los metadatos del registro completo
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A self-assembled organic/metal junction for water photo-oxidationOlaya, Astrid J.Omatsu, TerumasaHidalgo-Acosta, Jonnathan C.Riva, Julieta SoledadBassetto, Victor CostaGasilova, NataliaGirault, HubertWATER OXIDATIONSELF_ASSEMBLYTETRATHIAFULVALENEREDOX ELECTROCATALYSISPHOTOCATALYSIShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1We report the in situ self-assembly of TTF, TTF ·+ , and BF 4 - or PF 6 - into p-type semiconductors on the surface of Pt microparticles dispersed in water/acetonitrile mixtures. The visible light photoactivation of these self-assemblies leads to water oxidation forming O 2 and H + , with an efficiency of 100% with respect to the initial concentration of TTF ·+ . TTF ·+ is then completely reduced to TTF upon photoreduction with water. The Pt microparticles act as floating microelectrodes whose Fermi level is imposed by the different redox species in solution; here predominantly TTF, TTF ·+ , and HTTF + , which furthermore showed no signs of decomposition in solution.Fil: Olaya, Astrid J.. Swiss Federal Institute Of Technology Epfl; SuizaFil: Omatsu, Terumasa. Kyoto Institute Of Technology; JapónFil: Hidalgo-Acosta, Jonnathan C.. Swiss Federal Institute Of Technology Epfl; SuizaFil: Riva, Julieta Soledad. Swiss Federal Institute Of Technology Epfl; Suiza. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Bassetto, Victor Costa. Swiss Federal Institute Of Technology Epfl; SuizaFil: Gasilova, Natalia. Swiss Federal Institute Of Technology Epfl; SuizaFil: Girault, Hubert. Swiss Federal Institute Of Technology Epfl; SuizaAmerican Chemical Society2019-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/112329Olaya, Astrid J.; Omatsu, Terumasa; Hidalgo-Acosta, Jonnathan C.; Riva, Julieta Soledad; Bassetto, Victor Costa; et al.; A self-assembled organic/metal junction for water photo-oxidation; American Chemical Society; Journal of the American Chemical Society; 141; 16; 4-2019; 6765-67740002-78631520-5126CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/jacs.9b02693info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/jacs.9b02693info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:45:15Zoai:ri.conicet.gov.ar:11336/112329instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:45:15.334CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
A self-assembled organic/metal junction for water photo-oxidation |
title |
A self-assembled organic/metal junction for water photo-oxidation |
spellingShingle |
A self-assembled organic/metal junction for water photo-oxidation Olaya, Astrid J. WATER OXIDATION SELF_ASSEMBLY TETRATHIAFULVALENE REDOX ELECTROCATALYSIS PHOTOCATALYSIS |
title_short |
A self-assembled organic/metal junction for water photo-oxidation |
title_full |
A self-assembled organic/metal junction for water photo-oxidation |
title_fullStr |
A self-assembled organic/metal junction for water photo-oxidation |
title_full_unstemmed |
A self-assembled organic/metal junction for water photo-oxidation |
title_sort |
A self-assembled organic/metal junction for water photo-oxidation |
dc.creator.none.fl_str_mv |
Olaya, Astrid J. Omatsu, Terumasa Hidalgo-Acosta, Jonnathan C. Riva, Julieta Soledad Bassetto, Victor Costa Gasilova, Natalia Girault, Hubert |
author |
Olaya, Astrid J. |
author_facet |
Olaya, Astrid J. Omatsu, Terumasa Hidalgo-Acosta, Jonnathan C. Riva, Julieta Soledad Bassetto, Victor Costa Gasilova, Natalia Girault, Hubert |
author_role |
author |
author2 |
Omatsu, Terumasa Hidalgo-Acosta, Jonnathan C. Riva, Julieta Soledad Bassetto, Victor Costa Gasilova, Natalia Girault, Hubert |
author2_role |
author author author author author author |
dc.subject.none.fl_str_mv |
WATER OXIDATION SELF_ASSEMBLY TETRATHIAFULVALENE REDOX ELECTROCATALYSIS PHOTOCATALYSIS |
topic |
WATER OXIDATION SELF_ASSEMBLY TETRATHIAFULVALENE REDOX ELECTROCATALYSIS PHOTOCATALYSIS |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
We report the in situ self-assembly of TTF, TTF ·+ , and BF 4 - or PF 6 - into p-type semiconductors on the surface of Pt microparticles dispersed in water/acetonitrile mixtures. The visible light photoactivation of these self-assemblies leads to water oxidation forming O 2 and H + , with an efficiency of 100% with respect to the initial concentration of TTF ·+ . TTF ·+ is then completely reduced to TTF upon photoreduction with water. The Pt microparticles act as floating microelectrodes whose Fermi level is imposed by the different redox species in solution; here predominantly TTF, TTF ·+ , and HTTF + , which furthermore showed no signs of decomposition in solution. Fil: Olaya, Astrid J.. Swiss Federal Institute Of Technology Epfl; Suiza Fil: Omatsu, Terumasa. Kyoto Institute Of Technology; Japón Fil: Hidalgo-Acosta, Jonnathan C.. Swiss Federal Institute Of Technology Epfl; Suiza Fil: Riva, Julieta Soledad. Swiss Federal Institute Of Technology Epfl; Suiza. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Bassetto, Victor Costa. Swiss Federal Institute Of Technology Epfl; Suiza Fil: Gasilova, Natalia. Swiss Federal Institute Of Technology Epfl; Suiza Fil: Girault, Hubert. Swiss Federal Institute Of Technology Epfl; Suiza |
description |
We report the in situ self-assembly of TTF, TTF ·+ , and BF 4 - or PF 6 - into p-type semiconductors on the surface of Pt microparticles dispersed in water/acetonitrile mixtures. The visible light photoactivation of these self-assemblies leads to water oxidation forming O 2 and H + , with an efficiency of 100% with respect to the initial concentration of TTF ·+ . TTF ·+ is then completely reduced to TTF upon photoreduction with water. The Pt microparticles act as floating microelectrodes whose Fermi level is imposed by the different redox species in solution; here predominantly TTF, TTF ·+ , and HTTF + , which furthermore showed no signs of decomposition in solution. |
publishDate |
2019 |
dc.date.none.fl_str_mv |
2019-04 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/112329 Olaya, Astrid J.; Omatsu, Terumasa; Hidalgo-Acosta, Jonnathan C.; Riva, Julieta Soledad; Bassetto, Victor Costa; et al.; A self-assembled organic/metal junction for water photo-oxidation; American Chemical Society; Journal of the American Chemical Society; 141; 16; 4-2019; 6765-6774 0002-7863 1520-5126 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/112329 |
identifier_str_mv |
Olaya, Astrid J.; Omatsu, Terumasa; Hidalgo-Acosta, Jonnathan C.; Riva, Julieta Soledad; Bassetto, Victor Costa; et al.; A self-assembled organic/metal junction for water photo-oxidation; American Chemical Society; Journal of the American Chemical Society; 141; 16; 4-2019; 6765-6774 0002-7863 1520-5126 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1021/jacs.9b02693 info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/jacs.9b02693 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844614491951595520 |
score |
13.070432 |