The Role of a Sn Promoter on an Anodic Pt Electrocatalyst Prepared over H2O2-Functionalized Carbon Supports for Direct Ethanol Fuel Cell (DEFC) Applications

Autores
Azcoaga Chort, María Florencia; Stassi, Julieta Paola; de Miguel, Sergio Ruben; Veizaga, Natalia Soledad; Rodriguez, Virginia Ines
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Multiwalled carbon nanotubes and Vulcan carbon were functionalized with a 30 %v/v hydrogen peroxide solution and employed as supports for Pt and PtSn catalysts prepared by the polyol method. PtSn catalysts with a Pt loading of 20 wt.% and a Pt:Sn atomic ratio equal to 3:1 were evaluated in the ethanol electrooxidation reaction. The effects of the oxidizing treatment on the surface area and the surface chemical nature were analyzed through N2adsorption, isoelectric point, and temperature-programmed desorption measurements. Results showed that the H2O2treatment affects the surface area of the carbons to a great extent. Characterization results indicated that the performance of the electrocatalysts strongly depends both on the presence of Sn and on the support functionalization. PtSn/CNT-H2O2electrocatalyst displays a high electrochemical surface area and enhanced catalytic activity for ethanol oxidation in comparison to other catalysts in the present study.
Fil: Azcoaga Chort, María Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Stassi, Julieta Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: de Miguel, Sergio Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Veizaga, Natalia Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Rodriguez, Virginia Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
Electrocatalyst
Ethanol Fuel Cell
Sn Promoter
H2O2-Functionalized Carbon
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/236197
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/236197
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling The Role of a Sn Promoter on an Anodic Pt Electrocatalyst Prepared over H2O2-Functionalized Carbon Supports for Direct Ethanol Fuel Cell (DEFC) ApplicationsAzcoaga Chort, María FlorenciaStassi, Julieta Paolade Miguel, Sergio RubenVeizaga, Natalia SoledadRodriguez, Virginia InesElectrocatalystEthanol Fuel CellSn PromoterH2O2-Functionalized Carbonhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Multiwalled carbon nanotubes and Vulcan carbon were functionalized with a 30 %v/v hydrogen peroxide solution and employed as supports for Pt and PtSn catalysts prepared by the polyol method. PtSn catalysts with a Pt loading of 20 wt.% and a Pt:Sn atomic ratio equal to 3:1 were evaluated in the ethanol electrooxidation reaction. The effects of the oxidizing treatment on the surface area and the surface chemical nature were analyzed through N2adsorption, isoelectric point, and temperature-programmed desorption measurements. Results showed that the H2O2treatment affects the surface area of the carbons to a great extent. Characterization results indicated that the performance of the electrocatalysts strongly depends both on the presence of Sn and on the support functionalization. PtSn/CNT-H2O2electrocatalyst displays a high electrochemical surface area and enhanced catalytic activity for ethanol oxidation in comparison to other catalysts in the present study.Fil: Azcoaga Chort, María Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Stassi, Julieta Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: de Miguel, Sergio Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Veizaga, Natalia Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Rodriguez, Virginia Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaJohn Wiley & Sons2023-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/236197Azcoaga Chort, María Florencia; Stassi, Julieta Paola; de Miguel, Sergio Ruben; Veizaga, Natalia Soledad; Rodriguez, Virginia Ines; The Role of a Sn Promoter on an Anodic Pt Electrocatalyst Prepared over H2O2-Functionalized Carbon Supports for Direct Ethanol Fuel Cell (DEFC) Applications; John Wiley & Sons; ChemPlusChem; 88; 5; 4-2023; 1-112192-6506CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cplu.202300089info:eu-repo/semantics/altIdentifier/doi/10.1002/cplu.202300089info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:30:52Zoai:ri.conicet.gov.ar:11336/236197instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:30:52.346CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv The Role of a Sn Promoter on an Anodic Pt Electrocatalyst Prepared over H2O2-Functionalized Carbon Supports for Direct Ethanol Fuel Cell (DEFC) Applications
title The Role of a Sn Promoter on an Anodic Pt Electrocatalyst Prepared over H2O2-Functionalized Carbon Supports for Direct Ethanol Fuel Cell (DEFC) Applications
spellingShingle The Role of a Sn Promoter on an Anodic Pt Electrocatalyst Prepared over H2O2-Functionalized Carbon Supports for Direct Ethanol Fuel Cell (DEFC) Applications
Azcoaga Chort, María Florencia
Electrocatalyst
Ethanol Fuel Cell
Sn Promoter
H2O2-Functionalized Carbon
title_short The Role of a Sn Promoter on an Anodic Pt Electrocatalyst Prepared over H2O2-Functionalized Carbon Supports for Direct Ethanol Fuel Cell (DEFC) Applications
title_full The Role of a Sn Promoter on an Anodic Pt Electrocatalyst Prepared over H2O2-Functionalized Carbon Supports for Direct Ethanol Fuel Cell (DEFC) Applications
title_fullStr The Role of a Sn Promoter on an Anodic Pt Electrocatalyst Prepared over H2O2-Functionalized Carbon Supports for Direct Ethanol Fuel Cell (DEFC) Applications
title_full_unstemmed The Role of a Sn Promoter on an Anodic Pt Electrocatalyst Prepared over H2O2-Functionalized Carbon Supports for Direct Ethanol Fuel Cell (DEFC) Applications
title_sort The Role of a Sn Promoter on an Anodic Pt Electrocatalyst Prepared over H2O2-Functionalized Carbon Supports for Direct Ethanol Fuel Cell (DEFC) Applications
dc.creator.none.fl_str_mv Azcoaga Chort, María Florencia
Stassi, Julieta Paola
de Miguel, Sergio Ruben
Veizaga, Natalia Soledad
Rodriguez, Virginia Ines
author Azcoaga Chort, María Florencia
author_facet Azcoaga Chort, María Florencia
Stassi, Julieta Paola
de Miguel, Sergio Ruben
Veizaga, Natalia Soledad
Rodriguez, Virginia Ines
author_role author
author2 Stassi, Julieta Paola
de Miguel, Sergio Ruben
Veizaga, Natalia Soledad
Rodriguez, Virginia Ines
author2_role author
author
author
author
dc.subject.none.fl_str_mv Electrocatalyst
Ethanol Fuel Cell
Sn Promoter
H2O2-Functionalized Carbon
topic Electrocatalyst
Ethanol Fuel Cell
Sn Promoter
H2O2-Functionalized Carbon
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Multiwalled carbon nanotubes and Vulcan carbon were functionalized with a 30 %v/v hydrogen peroxide solution and employed as supports for Pt and PtSn catalysts prepared by the polyol method. PtSn catalysts with a Pt loading of 20 wt.% and a Pt:Sn atomic ratio equal to 3:1 were evaluated in the ethanol electrooxidation reaction. The effects of the oxidizing treatment on the surface area and the surface chemical nature were analyzed through N2adsorption, isoelectric point, and temperature-programmed desorption measurements. Results showed that the H2O2treatment affects the surface area of the carbons to a great extent. Characterization results indicated that the performance of the electrocatalysts strongly depends both on the presence of Sn and on the support functionalization. PtSn/CNT-H2O2electrocatalyst displays a high electrochemical surface area and enhanced catalytic activity for ethanol oxidation in comparison to other catalysts in the present study.
Fil: Azcoaga Chort, María Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Stassi, Julieta Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: de Miguel, Sergio Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Veizaga, Natalia Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Rodriguez, Virginia Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description Multiwalled carbon nanotubes and Vulcan carbon were functionalized with a 30 %v/v hydrogen peroxide solution and employed as supports for Pt and PtSn catalysts prepared by the polyol method. PtSn catalysts with a Pt loading of 20 wt.% and a Pt:Sn atomic ratio equal to 3:1 were evaluated in the ethanol electrooxidation reaction. The effects of the oxidizing treatment on the surface area and the surface chemical nature were analyzed through N2adsorption, isoelectric point, and temperature-programmed desorption measurements. Results showed that the H2O2treatment affects the surface area of the carbons to a great extent. Characterization results indicated that the performance of the electrocatalysts strongly depends both on the presence of Sn and on the support functionalization. PtSn/CNT-H2O2electrocatalyst displays a high electrochemical surface area and enhanced catalytic activity for ethanol oxidation in comparison to other catalysts in the present study.
publishDate 2023
dc.date.none.fl_str_mv 2023-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/236197
Azcoaga Chort, María Florencia; Stassi, Julieta Paola; de Miguel, Sergio Ruben; Veizaga, Natalia Soledad; Rodriguez, Virginia Ines; The Role of a Sn Promoter on an Anodic Pt Electrocatalyst Prepared over H2O2-Functionalized Carbon Supports for Direct Ethanol Fuel Cell (DEFC) Applications; John Wiley & Sons; ChemPlusChem; 88; 5; 4-2023; 1-11
2192-6506
CONICET Digital
CONICET
url http://hdl.handle.net/11336/236197
identifier_str_mv Azcoaga Chort, María Florencia; Stassi, Julieta Paola; de Miguel, Sergio Ruben; Veizaga, Natalia Soledad; Rodriguez, Virginia Ines; The Role of a Sn Promoter on an Anodic Pt Electrocatalyst Prepared over H2O2-Functionalized Carbon Supports for Direct Ethanol Fuel Cell (DEFC) Applications; John Wiley & Sons; ChemPlusChem; 88; 5; 4-2023; 1-11
2192-6506
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cplu.202300089
info:eu-repo/semantics/altIdentifier/doi/10.1002/cplu.202300089
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons
publisher.none.fl_str_mv John Wiley & Sons
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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