Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: Products, effect of UV irradiation, water, and coadsorbed K +
- Autores
- Rosseler, Olivier; Sleiman, Mohamad; Montesinos, Victor Nahuel; Shavorskiy, Andrey; Keller, Valerie; Keller, Nicolas; Litter, Marta Irene; Bluhm, Hendrik; Salmeron, Miquel; Destaillats, Hugo
- Año de publicación
- 2013
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Self-cleaning surfaces containing TiO2 nanoparticles have been postulated to efficiently remove NOx from the atmosphere. However, UV irradiation of NOx adsorbed on TiO2 also was shown to form harmful gas-phase byproducts such as HONO and N2O that may limit their depolluting potential. Ambient pressure XPS was used to study surface and gas-phase species formed during adsorption of NO2 on TiO2 and subsequent UV irradiation at λ = 365 nm. It is shown here that NO3 -, adsorbed on TiO2 as a byproduct of NO2 disproportionation, was quantitatively converted to surface NO2 and other reduced nitrogenated species under UV irradiation in the absence of moisture. When water vapor was present, a faster NO 3 - conversion occurred, leading to a net loss of surface-bound nitrogenated species. Strongly adsorbed NO3 - in the vicinity of coadsorbed K+ cations was stable under UV light, leading to an efficient capture of nitrogenated compounds. © 2013 American Chemical Society.
Fil: Rosseler, Olivier. Chemical Sciences Division and Advanced Light Source; Estados Unidos. Université de Strasbourg; Francia
Fil: Sleiman, Mohamad. Chemical Sciences Division and Advanced Light Source; Estados Unidos
Fil: Montesinos, Victor Nahuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Comisión Nacional de Energía Atómica; Argentina
Fil: Shavorskiy, Andrey. Chemical Sciences Division and Advanced Light Source; Estados Unidos
Fil: Keller, Valerie. Université de Strasbourg; Francia
Fil: Keller, Nicolas. Université de Strasbourg; Francia
Fil: Litter, Marta Irene. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; Argentina
Fil: Bluhm, Hendrik. Chemical Sciences Division and Advanced Light Source; Estados Unidos
Fil: Salmeron, Miquel. Chemical Sciences Division and Advanced Light Source; Estados Unidos. University of California at Berkeley; Estados Unidos
Fil: Destaillats, Hugo. Chemical Sciences Division and Advanced Light Source; Estados Unidos - Materia
-
APXPS
DENOX
DEPOLLUTION
HONO
RENOXIFICATION - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/77866
Ver los metadatos del registro completo
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CONICET Digital (CONICET) |
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Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: Products, effect of UV irradiation, water, and coadsorbed K +Rosseler, OlivierSleiman, MohamadMontesinos, Victor NahuelShavorskiy, AndreyKeller, ValerieKeller, NicolasLitter, Marta IreneBluhm, HendrikSalmeron, MiquelDestaillats, HugoAPXPSDENOXDEPOLLUTIONHONORENOXIFICATIONhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Self-cleaning surfaces containing TiO2 nanoparticles have been postulated to efficiently remove NOx from the atmosphere. However, UV irradiation of NOx adsorbed on TiO2 also was shown to form harmful gas-phase byproducts such as HONO and N2O that may limit their depolluting potential. Ambient pressure XPS was used to study surface and gas-phase species formed during adsorption of NO2 on TiO2 and subsequent UV irradiation at λ = 365 nm. It is shown here that NO3 -, adsorbed on TiO2 as a byproduct of NO2 disproportionation, was quantitatively converted to surface NO2 and other reduced nitrogenated species under UV irradiation in the absence of moisture. When water vapor was present, a faster NO 3 - conversion occurred, leading to a net loss of surface-bound nitrogenated species. Strongly adsorbed NO3 - in the vicinity of coadsorbed K+ cations was stable under UV light, leading to an efficient capture of nitrogenated compounds. © 2013 American Chemical Society.Fil: Rosseler, Olivier. Chemical Sciences Division and Advanced Light Source; Estados Unidos. Université de Strasbourg; FranciaFil: Sleiman, Mohamad. Chemical Sciences Division and Advanced Light Source; Estados UnidosFil: Montesinos, Victor Nahuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Comisión Nacional de Energía Atómica; ArgentinaFil: Shavorskiy, Andrey. Chemical Sciences Division and Advanced Light Source; Estados UnidosFil: Keller, Valerie. Université de Strasbourg; FranciaFil: Keller, Nicolas. Université de Strasbourg; FranciaFil: Litter, Marta Irene. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; ArgentinaFil: Bluhm, Hendrik. Chemical Sciences Division and Advanced Light Source; Estados UnidosFil: Salmeron, Miquel. Chemical Sciences Division and Advanced Light Source; Estados Unidos. University of California at Berkeley; Estados UnidosFil: Destaillats, Hugo. Chemical Sciences Division and Advanced Light Source; Estados UnidosAmerican Chemical Society2013-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/77866Rosseler, Olivier; Sleiman, Mohamad; Montesinos, Victor Nahuel; Shavorskiy, Andrey; Keller, Valerie; et al.; Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: Products, effect of UV irradiation, water, and coadsorbed K +; American Chemical Society; Journal of Physical Chemistry Letters; 4; 3; 2-2013; 536-5411948-7185CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/jz302119ginfo:eu-repo/semantics/altIdentifier/doi/10.1021/jz302119ginfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:33:52Zoai:ri.conicet.gov.ar:11336/77866instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:33:53.034CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: Products, effect of UV irradiation, water, and coadsorbed K + |
title |
Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: Products, effect of UV irradiation, water, and coadsorbed K + |
spellingShingle |
Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: Products, effect of UV irradiation, water, and coadsorbed K + Rosseler, Olivier APXPS DENOX DEPOLLUTION HONO RENOXIFICATION |
title_short |
Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: Products, effect of UV irradiation, water, and coadsorbed K + |
title_full |
Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: Products, effect of UV irradiation, water, and coadsorbed K + |
title_fullStr |
Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: Products, effect of UV irradiation, water, and coadsorbed K + |
title_full_unstemmed |
Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: Products, effect of UV irradiation, water, and coadsorbed K + |
title_sort |
Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: Products, effect of UV irradiation, water, and coadsorbed K + |
dc.creator.none.fl_str_mv |
Rosseler, Olivier Sleiman, Mohamad Montesinos, Victor Nahuel Shavorskiy, Andrey Keller, Valerie Keller, Nicolas Litter, Marta Irene Bluhm, Hendrik Salmeron, Miquel Destaillats, Hugo |
author |
Rosseler, Olivier |
author_facet |
Rosseler, Olivier Sleiman, Mohamad Montesinos, Victor Nahuel Shavorskiy, Andrey Keller, Valerie Keller, Nicolas Litter, Marta Irene Bluhm, Hendrik Salmeron, Miquel Destaillats, Hugo |
author_role |
author |
author2 |
Sleiman, Mohamad Montesinos, Victor Nahuel Shavorskiy, Andrey Keller, Valerie Keller, Nicolas Litter, Marta Irene Bluhm, Hendrik Salmeron, Miquel Destaillats, Hugo |
author2_role |
author author author author author author author author author |
dc.subject.none.fl_str_mv |
APXPS DENOX DEPOLLUTION HONO RENOXIFICATION |
topic |
APXPS DENOX DEPOLLUTION HONO RENOXIFICATION |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Self-cleaning surfaces containing TiO2 nanoparticles have been postulated to efficiently remove NOx from the atmosphere. However, UV irradiation of NOx adsorbed on TiO2 also was shown to form harmful gas-phase byproducts such as HONO and N2O that may limit their depolluting potential. Ambient pressure XPS was used to study surface and gas-phase species formed during adsorption of NO2 on TiO2 and subsequent UV irradiation at λ = 365 nm. It is shown here that NO3 -, adsorbed on TiO2 as a byproduct of NO2 disproportionation, was quantitatively converted to surface NO2 and other reduced nitrogenated species under UV irradiation in the absence of moisture. When water vapor was present, a faster NO 3 - conversion occurred, leading to a net loss of surface-bound nitrogenated species. Strongly adsorbed NO3 - in the vicinity of coadsorbed K+ cations was stable under UV light, leading to an efficient capture of nitrogenated compounds. © 2013 American Chemical Society. Fil: Rosseler, Olivier. Chemical Sciences Division and Advanced Light Source; Estados Unidos. Université de Strasbourg; Francia Fil: Sleiman, Mohamad. Chemical Sciences Division and Advanced Light Source; Estados Unidos Fil: Montesinos, Victor Nahuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Comisión Nacional de Energía Atómica; Argentina Fil: Shavorskiy, Andrey. Chemical Sciences Division and Advanced Light Source; Estados Unidos Fil: Keller, Valerie. Université de Strasbourg; Francia Fil: Keller, Nicolas. Université de Strasbourg; Francia Fil: Litter, Marta Irene. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; Argentina Fil: Bluhm, Hendrik. Chemical Sciences Division and Advanced Light Source; Estados Unidos Fil: Salmeron, Miquel. Chemical Sciences Division and Advanced Light Source; Estados Unidos. University of California at Berkeley; Estados Unidos Fil: Destaillats, Hugo. Chemical Sciences Division and Advanced Light Source; Estados Unidos |
description |
Self-cleaning surfaces containing TiO2 nanoparticles have been postulated to efficiently remove NOx from the atmosphere. However, UV irradiation of NOx adsorbed on TiO2 also was shown to form harmful gas-phase byproducts such as HONO and N2O that may limit their depolluting potential. Ambient pressure XPS was used to study surface and gas-phase species formed during adsorption of NO2 on TiO2 and subsequent UV irradiation at λ = 365 nm. It is shown here that NO3 -, adsorbed on TiO2 as a byproduct of NO2 disproportionation, was quantitatively converted to surface NO2 and other reduced nitrogenated species under UV irradiation in the absence of moisture. When water vapor was present, a faster NO 3 - conversion occurred, leading to a net loss of surface-bound nitrogenated species. Strongly adsorbed NO3 - in the vicinity of coadsorbed K+ cations was stable under UV light, leading to an efficient capture of nitrogenated compounds. © 2013 American Chemical Society. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-02 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/77866 Rosseler, Olivier; Sleiman, Mohamad; Montesinos, Victor Nahuel; Shavorskiy, Andrey; Keller, Valerie; et al.; Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: Products, effect of UV irradiation, water, and coadsorbed K +; American Chemical Society; Journal of Physical Chemistry Letters; 4; 3; 2-2013; 536-541 1948-7185 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/77866 |
identifier_str_mv |
Rosseler, Olivier; Sleiman, Mohamad; Montesinos, Victor Nahuel; Shavorskiy, Andrey; Keller, Valerie; et al.; Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: Products, effect of UV irradiation, water, and coadsorbed K +; American Chemical Society; Journal of Physical Chemistry Letters; 4; 3; 2-2013; 536-541 1948-7185 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/jz302119g info:eu-repo/semantics/altIdentifier/doi/10.1021/jz302119g |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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score |
13.070432 |