Single-wall carbon nanotubes/epoxy elastomers exhibiting high damping capacity in an extended temperature range

Autores
Auad, Maria L.; Mosiewicki, Mirna Alejandra; Uzunpinar, Cihan; Williams, Roberto Juan Jose
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In nanocomposites containing single-wall or multi-wall carbon nanotubes (SWCNT and MWCNT) high damping can be achieved by taking advantage of the weak bonding and interfacial friction between individual nanotubes and the matrix. The increase in damping capacity has already been proved for stiff epoxies and in this study it is extended to epoxy elastomers. Variable amounts (0.5–3 wt%) of oxidized SWCNT were dispersed by ultrasonication in precursors of an epoxy elastomer based on the reaction of diglycidylether of bisphenol A (DGEBA) and a polyoxypropylene with average molar mass of 2000, end-capped with primary amine groups. The quality of the initial dispersion was assessed by the constancy of the storage modulus with frequency in the low-frequency range. A rheological percolation threshold of 0.41 wt% SWCNT was found. Cured elastomers exhibited a large increase of the loss modulus with increasing amounts of SWCNT. For 3 wt% SWCNT, the increase in loss modulus was 1400% at room temperature. When temperature was increased up to 140 °C the loss modulus of the nanocomposite was practically constant while the one of the matrix dropped to a negligible value. The damping capacity at high temperatures opens important practical applications.
Fil: Auad, Maria L.. Auburn University; Estados Unidos
Fil: Mosiewicki, Mirna Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina. Auburn University; Estados Unidos
Fil: Uzunpinar, Cihan. Auburn University; Estados Unidos
Fil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
A. Carbon Nanotubes
A. Nanocomposites
A. Functional Composites
B. Mechanical Properties
B. Interfacial Strength
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/35012
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Single-wall carbon nanotubes/epoxy elastomers exhibiting high damping capacity in an extended temperature rangeAuad, Maria L.Mosiewicki, Mirna AlejandraUzunpinar, CihanWilliams, Roberto Juan JoseA. Carbon NanotubesA. NanocompositesA. Functional CompositesB. Mechanical PropertiesB. Interfacial Strengthhttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2In nanocomposites containing single-wall or multi-wall carbon nanotubes (SWCNT and MWCNT) high damping can be achieved by taking advantage of the weak bonding and interfacial friction between individual nanotubes and the matrix. The increase in damping capacity has already been proved for stiff epoxies and in this study it is extended to epoxy elastomers. Variable amounts (0.5–3 wt%) of oxidized SWCNT were dispersed by ultrasonication in precursors of an epoxy elastomer based on the reaction of diglycidylether of bisphenol A (DGEBA) and a polyoxypropylene with average molar mass of 2000, end-capped with primary amine groups. The quality of the initial dispersion was assessed by the constancy of the storage modulus with frequency in the low-frequency range. A rheological percolation threshold of 0.41 wt% SWCNT was found. Cured elastomers exhibited a large increase of the loss modulus with increasing amounts of SWCNT. For 3 wt% SWCNT, the increase in loss modulus was 1400% at room temperature. When temperature was increased up to 140 °C the loss modulus of the nanocomposite was practically constant while the one of the matrix dropped to a negligible value. The damping capacity at high temperatures opens important practical applications.Fil: Auad, Maria L.. Auburn University; Estados UnidosFil: Mosiewicki, Mirna Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina. Auburn University; Estados UnidosFil: Uzunpinar, Cihan. Auburn University; Estados UnidosFil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaElsevier2009-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/35012Auad, Maria L.; Mosiewicki, Mirna Alejandra; Uzunpinar, Cihan; Williams, Roberto Juan Jose; Single-wall carbon nanotubes/epoxy elastomers exhibiting high damping capacity in an extended temperature range; Elsevier; Composite Science And Technology; 69; 7-8; 7-2009; 1088-10920266-3538CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.compscitech.2009.01.030info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0266353809000335info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:17:48Zoai:ri.conicet.gov.ar:11336/35012instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:17:49.216CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Single-wall carbon nanotubes/epoxy elastomers exhibiting high damping capacity in an extended temperature range
title Single-wall carbon nanotubes/epoxy elastomers exhibiting high damping capacity in an extended temperature range
spellingShingle Single-wall carbon nanotubes/epoxy elastomers exhibiting high damping capacity in an extended temperature range
Auad, Maria L.
A. Carbon Nanotubes
A. Nanocomposites
A. Functional Composites
B. Mechanical Properties
B. Interfacial Strength
title_short Single-wall carbon nanotubes/epoxy elastomers exhibiting high damping capacity in an extended temperature range
title_full Single-wall carbon nanotubes/epoxy elastomers exhibiting high damping capacity in an extended temperature range
title_fullStr Single-wall carbon nanotubes/epoxy elastomers exhibiting high damping capacity in an extended temperature range
title_full_unstemmed Single-wall carbon nanotubes/epoxy elastomers exhibiting high damping capacity in an extended temperature range
title_sort Single-wall carbon nanotubes/epoxy elastomers exhibiting high damping capacity in an extended temperature range
dc.creator.none.fl_str_mv Auad, Maria L.
Mosiewicki, Mirna Alejandra
Uzunpinar, Cihan
Williams, Roberto Juan Jose
author Auad, Maria L.
author_facet Auad, Maria L.
Mosiewicki, Mirna Alejandra
Uzunpinar, Cihan
Williams, Roberto Juan Jose
author_role author
author2 Mosiewicki, Mirna Alejandra
Uzunpinar, Cihan
Williams, Roberto Juan Jose
author2_role author
author
author
dc.subject.none.fl_str_mv A. Carbon Nanotubes
A. Nanocomposites
A. Functional Composites
B. Mechanical Properties
B. Interfacial Strength
topic A. Carbon Nanotubes
A. Nanocomposites
A. Functional Composites
B. Mechanical Properties
B. Interfacial Strength
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In nanocomposites containing single-wall or multi-wall carbon nanotubes (SWCNT and MWCNT) high damping can be achieved by taking advantage of the weak bonding and interfacial friction between individual nanotubes and the matrix. The increase in damping capacity has already been proved for stiff epoxies and in this study it is extended to epoxy elastomers. Variable amounts (0.5–3 wt%) of oxidized SWCNT were dispersed by ultrasonication in precursors of an epoxy elastomer based on the reaction of diglycidylether of bisphenol A (DGEBA) and a polyoxypropylene with average molar mass of 2000, end-capped with primary amine groups. The quality of the initial dispersion was assessed by the constancy of the storage modulus with frequency in the low-frequency range. A rheological percolation threshold of 0.41 wt% SWCNT was found. Cured elastomers exhibited a large increase of the loss modulus with increasing amounts of SWCNT. For 3 wt% SWCNT, the increase in loss modulus was 1400% at room temperature. When temperature was increased up to 140 °C the loss modulus of the nanocomposite was practically constant while the one of the matrix dropped to a negligible value. The damping capacity at high temperatures opens important practical applications.
Fil: Auad, Maria L.. Auburn University; Estados Unidos
Fil: Mosiewicki, Mirna Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina. Auburn University; Estados Unidos
Fil: Uzunpinar, Cihan. Auburn University; Estados Unidos
Fil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description In nanocomposites containing single-wall or multi-wall carbon nanotubes (SWCNT and MWCNT) high damping can be achieved by taking advantage of the weak bonding and interfacial friction between individual nanotubes and the matrix. The increase in damping capacity has already been proved for stiff epoxies and in this study it is extended to epoxy elastomers. Variable amounts (0.5–3 wt%) of oxidized SWCNT were dispersed by ultrasonication in precursors of an epoxy elastomer based on the reaction of diglycidylether of bisphenol A (DGEBA) and a polyoxypropylene with average molar mass of 2000, end-capped with primary amine groups. The quality of the initial dispersion was assessed by the constancy of the storage modulus with frequency in the low-frequency range. A rheological percolation threshold of 0.41 wt% SWCNT was found. Cured elastomers exhibited a large increase of the loss modulus with increasing amounts of SWCNT. For 3 wt% SWCNT, the increase in loss modulus was 1400% at room temperature. When temperature was increased up to 140 °C the loss modulus of the nanocomposite was practically constant while the one of the matrix dropped to a negligible value. The damping capacity at high temperatures opens important practical applications.
publishDate 2009
dc.date.none.fl_str_mv 2009-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/35012
Auad, Maria L.; Mosiewicki, Mirna Alejandra; Uzunpinar, Cihan; Williams, Roberto Juan Jose; Single-wall carbon nanotubes/epoxy elastomers exhibiting high damping capacity in an extended temperature range; Elsevier; Composite Science And Technology; 69; 7-8; 7-2009; 1088-1092
0266-3538
CONICET Digital
CONICET
url http://hdl.handle.net/11336/35012
identifier_str_mv Auad, Maria L.; Mosiewicki, Mirna Alejandra; Uzunpinar, Cihan; Williams, Roberto Juan Jose; Single-wall carbon nanotubes/epoxy elastomers exhibiting high damping capacity in an extended temperature range; Elsevier; Composite Science And Technology; 69; 7-8; 7-2009; 1088-1092
0266-3538
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.compscitech.2009.01.030
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0266353809000335
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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