Terminal alkynes hydroamination catalized by copper nanoparticles

Autores
Mancebo Aracil, Juan; Alonso, María Belén; Radivoy, Gabriel Eduardo
Año de publicación
2020
Idioma
inglés
Tipo de recurso
documento de conferencia
Estado
versión publicada
Descripción
The copper-catalyzed regioselective intermolecular hydroamination of terminal alkynes with amines was accomplished. The reaction was catalyzed by copper nanoparticles supported on montmorillonite K10 (CuNPs/MK10) and afforded the desired imines in good conversions. Then, imines were transformed into the corresponding amines after treatment with NaBH3CN. The catalyst could be recovered and reutilized in several cycles.
Fil: Mancebo Aracil, Juan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Alonso, María Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Radivoy, Gabriel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
The 24th International Electronic Conference on Synthetic Organic Chemistry. ECSOC-24
Santiago de Compostela
España
Academic open Access Publishing
Universidad de Santiago de Compostela
Materia
HYDROAMINATION
CATALYSIS
NANOPARTICLES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/231915
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Terminal alkynes hydroamination catalized by copper nanoparticlesMancebo Aracil, JuanAlonso, María BelénRadivoy, Gabriel EduardoHYDROAMINATIONCATALYSISNANOPARTICLEShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The copper-catalyzed regioselective intermolecular hydroamination of terminal alkynes with amines was accomplished. The reaction was catalyzed by copper nanoparticles supported on montmorillonite K10 (CuNPs/MK10) and afforded the desired imines in good conversions. Then, imines were transformed into the corresponding amines after treatment with NaBH3CN. The catalyst could be recovered and reutilized in several cycles.Fil: Mancebo Aracil, Juan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Alonso, María Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Radivoy, Gabriel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaThe 24th International Electronic Conference on Synthetic Organic Chemistry. ECSOC-24Santiago de CompostelaEspañaAcademic open Access PublishingUniversidad de Santiago de CompostelaMultidisciplinary Digital Publishing InstituteSeijas, Julio A.Vazquez Tato, Maria Pilar2020info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/conferenceObjectConferenciaJournalhttp://purl.org/coar/resource_type/c_5794info:ar-repo/semantics/documentoDeConferenciaapplication/pdfapplication/vnd.openxmlformats-officedocument.wordprocessingml.documentapplication/pdfhttp://hdl.handle.net/11336/231915Terminal alkynes hydroamination catalized by copper nanoparticles; The 24th International Electronic Conference on Synthetic Organic Chemistry. ECSOC-24; Santiago de Compostela; España; 2020; 1-82673-4583CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2673-4583/3/1/103info:eu-repo/semantics/altIdentifier/doi/10.3390/ecsoc-24-08452Internacionalinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:22:35Zoai:ri.conicet.gov.ar:11336/231915instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:22:35.961CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Terminal alkynes hydroamination catalized by copper nanoparticles
title Terminal alkynes hydroamination catalized by copper nanoparticles
spellingShingle Terminal alkynes hydroamination catalized by copper nanoparticles
Mancebo Aracil, Juan
HYDROAMINATION
CATALYSIS
NANOPARTICLES
title_short Terminal alkynes hydroamination catalized by copper nanoparticles
title_full Terminal alkynes hydroamination catalized by copper nanoparticles
title_fullStr Terminal alkynes hydroamination catalized by copper nanoparticles
title_full_unstemmed Terminal alkynes hydroamination catalized by copper nanoparticles
title_sort Terminal alkynes hydroamination catalized by copper nanoparticles
dc.creator.none.fl_str_mv Mancebo Aracil, Juan
Alonso, María Belén
Radivoy, Gabriel Eduardo
author Mancebo Aracil, Juan
author_facet Mancebo Aracil, Juan
Alonso, María Belén
Radivoy, Gabriel Eduardo
author_role author
author2 Alonso, María Belén
Radivoy, Gabriel Eduardo
author2_role author
author
dc.contributor.none.fl_str_mv Seijas, Julio A.
Vazquez Tato, Maria Pilar
dc.subject.none.fl_str_mv HYDROAMINATION
CATALYSIS
NANOPARTICLES
topic HYDROAMINATION
CATALYSIS
NANOPARTICLES
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The copper-catalyzed regioselective intermolecular hydroamination of terminal alkynes with amines was accomplished. The reaction was catalyzed by copper nanoparticles supported on montmorillonite K10 (CuNPs/MK10) and afforded the desired imines in good conversions. Then, imines were transformed into the corresponding amines after treatment with NaBH3CN. The catalyst could be recovered and reutilized in several cycles.
Fil: Mancebo Aracil, Juan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Alonso, María Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Radivoy, Gabriel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
The 24th International Electronic Conference on Synthetic Organic Chemistry. ECSOC-24
Santiago de Compostela
España
Academic open Access Publishing
Universidad de Santiago de Compostela
description The copper-catalyzed regioselective intermolecular hydroamination of terminal alkynes with amines was accomplished. The reaction was catalyzed by copper nanoparticles supported on montmorillonite K10 (CuNPs/MK10) and afforded the desired imines in good conversions. Then, imines were transformed into the corresponding amines after treatment with NaBH3CN. The catalyst could be recovered and reutilized in several cycles.
publishDate 2020
dc.date.none.fl_str_mv 2020
dc.type.none.fl_str_mv info:eu-repo/semantics/publishedVersion
info:eu-repo/semantics/conferenceObject
Conferencia
Journal
http://purl.org/coar/resource_type/c_5794
info:ar-repo/semantics/documentoDeConferencia
status_str publishedVersion
format conferenceObject
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/231915
Terminal alkynes hydroamination catalized by copper nanoparticles; The 24th International Electronic Conference on Synthetic Organic Chemistry. ECSOC-24; Santiago de Compostela; España; 2020; 1-8
2673-4583
CONICET Digital
CONICET
url http://hdl.handle.net/11336/231915
identifier_str_mv Terminal alkynes hydroamination catalized by copper nanoparticles; The 24th International Electronic Conference on Synthetic Organic Chemistry. ECSOC-24; Santiago de Compostela; España; 2020; 1-8
2673-4583
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2673-4583/3/1/103
info:eu-repo/semantics/altIdentifier/doi/10.3390/ecsoc-24-08452
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/vnd.openxmlformats-officedocument.wordprocessingml.document
application/pdf
dc.coverage.none.fl_str_mv Internacional
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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