Fe-Mn/ZrO2 catalysts: Sulfate-based-advanced oxidation process for the degradation of olive oil industry model pollutants

Autores
Loffredo, Camila Macarena; Dennehy, Mariana; Alvarez, Mariana
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Fe, Mn and a bimetallic Fe[sbnd]Mn catalysts supported on ZrO2 were synthesized and tested for the activation of persulfate (PS) and peroxymonosulfate (PMS) in the degradation reaction of three different organic compounds: cinnamic acid (CA), benzoic acid (BA), and catechol (C). The catalysts were prepared and tested in order to evaluate the effect of the metal and the metal combination on the generation of reactive oxygen species (ROS). The characterization of the catalysts was carried out by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and atomic absorption spectroscopy (AAS). The best degradation results were obtained when PMS was activated with the bimetallic Fe-Mn/ZrO2 catalyst in the CA degradation. Moreover, the Fe-Mn/ZrO2 catalyst reusability was tested for up to three consecutive cycles of reaction, with mineralization levels >90%. A synergistic effect between the Fe and Mn metal species, which increases the catalyst activity if compared to the monometallic catalysts, is postulated. Both sulfate and hydroxyl radicals were generated in the PMS activation process. The activation mechanisms of the oxidants were proposed.
Fil: Loffredo, Camila Macarena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Alvarez, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Materia
ADVANCED OXIDATION PROCESSES
IRON AND MANGANESE CATALYSTS
ORGANIC POLLUTANTS
SULFATE RADICALS
ZRO2
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/203959
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Fe-Mn/ZrO2 catalysts: Sulfate-based-advanced oxidation process for the degradation of olive oil industry model pollutantsLoffredo, Camila MacarenaDennehy, MarianaAlvarez, MarianaADVANCED OXIDATION PROCESSESIRON AND MANGANESE CATALYSTSORGANIC POLLUTANTSSULFATE RADICALSZRO2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Fe, Mn and a bimetallic Fe[sbnd]Mn catalysts supported on ZrO2 were synthesized and tested for the activation of persulfate (PS) and peroxymonosulfate (PMS) in the degradation reaction of three different organic compounds: cinnamic acid (CA), benzoic acid (BA), and catechol (C). The catalysts were prepared and tested in order to evaluate the effect of the metal and the metal combination on the generation of reactive oxygen species (ROS). The characterization of the catalysts was carried out by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and atomic absorption spectroscopy (AAS). The best degradation results were obtained when PMS was activated with the bimetallic Fe-Mn/ZrO2 catalyst in the CA degradation. Moreover, the Fe-Mn/ZrO2 catalyst reusability was tested for up to three consecutive cycles of reaction, with mineralization levels >90%. A synergistic effect between the Fe and Mn metal species, which increases the catalyst activity if compared to the monometallic catalysts, is postulated. Both sulfate and hydroxyl radicals were generated in the PMS activation process. The activation mechanisms of the oxidants were proposed.Fil: Loffredo, Camila Macarena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Alvarez, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaElsevier Science2022-12-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/203959Loffredo, Camila Macarena; Dennehy, Mariana; Alvarez, Mariana; Fe-Mn/ZrO2 catalysts: Sulfate-based-advanced oxidation process for the degradation of olive oil industry model pollutants; Elsevier Science; Catalysis Communications; 174; 106578; 5-12-2022; 1-91566-7367CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1566736722001832info:eu-repo/semantics/altIdentifier/doi/10.1016/j.catcom.2022.106578info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:05:56Zoai:ri.conicet.gov.ar:11336/203959instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:05:56.442CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Fe-Mn/ZrO2 catalysts: Sulfate-based-advanced oxidation process for the degradation of olive oil industry model pollutants
title Fe-Mn/ZrO2 catalysts: Sulfate-based-advanced oxidation process for the degradation of olive oil industry model pollutants
spellingShingle Fe-Mn/ZrO2 catalysts: Sulfate-based-advanced oxidation process for the degradation of olive oil industry model pollutants
Loffredo, Camila Macarena
ADVANCED OXIDATION PROCESSES
IRON AND MANGANESE CATALYSTS
ORGANIC POLLUTANTS
SULFATE RADICALS
ZRO2
title_short Fe-Mn/ZrO2 catalysts: Sulfate-based-advanced oxidation process for the degradation of olive oil industry model pollutants
title_full Fe-Mn/ZrO2 catalysts: Sulfate-based-advanced oxidation process for the degradation of olive oil industry model pollutants
title_fullStr Fe-Mn/ZrO2 catalysts: Sulfate-based-advanced oxidation process for the degradation of olive oil industry model pollutants
title_full_unstemmed Fe-Mn/ZrO2 catalysts: Sulfate-based-advanced oxidation process for the degradation of olive oil industry model pollutants
title_sort Fe-Mn/ZrO2 catalysts: Sulfate-based-advanced oxidation process for the degradation of olive oil industry model pollutants
dc.creator.none.fl_str_mv Loffredo, Camila Macarena
Dennehy, Mariana
Alvarez, Mariana
author Loffredo, Camila Macarena
author_facet Loffredo, Camila Macarena
Dennehy, Mariana
Alvarez, Mariana
author_role author
author2 Dennehy, Mariana
Alvarez, Mariana
author2_role author
author
dc.subject.none.fl_str_mv ADVANCED OXIDATION PROCESSES
IRON AND MANGANESE CATALYSTS
ORGANIC POLLUTANTS
SULFATE RADICALS
ZRO2
topic ADVANCED OXIDATION PROCESSES
IRON AND MANGANESE CATALYSTS
ORGANIC POLLUTANTS
SULFATE RADICALS
ZRO2
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Fe, Mn and a bimetallic Fe[sbnd]Mn catalysts supported on ZrO2 were synthesized and tested for the activation of persulfate (PS) and peroxymonosulfate (PMS) in the degradation reaction of three different organic compounds: cinnamic acid (CA), benzoic acid (BA), and catechol (C). The catalysts were prepared and tested in order to evaluate the effect of the metal and the metal combination on the generation of reactive oxygen species (ROS). The characterization of the catalysts was carried out by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and atomic absorption spectroscopy (AAS). The best degradation results were obtained when PMS was activated with the bimetallic Fe-Mn/ZrO2 catalyst in the CA degradation. Moreover, the Fe-Mn/ZrO2 catalyst reusability was tested for up to three consecutive cycles of reaction, with mineralization levels >90%. A synergistic effect between the Fe and Mn metal species, which increases the catalyst activity if compared to the monometallic catalysts, is postulated. Both sulfate and hydroxyl radicals were generated in the PMS activation process. The activation mechanisms of the oxidants were proposed.
Fil: Loffredo, Camila Macarena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Alvarez, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
description Fe, Mn and a bimetallic Fe[sbnd]Mn catalysts supported on ZrO2 were synthesized and tested for the activation of persulfate (PS) and peroxymonosulfate (PMS) in the degradation reaction of three different organic compounds: cinnamic acid (CA), benzoic acid (BA), and catechol (C). The catalysts were prepared and tested in order to evaluate the effect of the metal and the metal combination on the generation of reactive oxygen species (ROS). The characterization of the catalysts was carried out by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and atomic absorption spectroscopy (AAS). The best degradation results were obtained when PMS was activated with the bimetallic Fe-Mn/ZrO2 catalyst in the CA degradation. Moreover, the Fe-Mn/ZrO2 catalyst reusability was tested for up to three consecutive cycles of reaction, with mineralization levels >90%. A synergistic effect between the Fe and Mn metal species, which increases the catalyst activity if compared to the monometallic catalysts, is postulated. Both sulfate and hydroxyl radicals were generated in the PMS activation process. The activation mechanisms of the oxidants were proposed.
publishDate 2022
dc.date.none.fl_str_mv 2022-12-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/203959
Loffredo, Camila Macarena; Dennehy, Mariana; Alvarez, Mariana; Fe-Mn/ZrO2 catalysts: Sulfate-based-advanced oxidation process for the degradation of olive oil industry model pollutants; Elsevier Science; Catalysis Communications; 174; 106578; 5-12-2022; 1-9
1566-7367
CONICET Digital
CONICET
url http://hdl.handle.net/11336/203959
identifier_str_mv Loffredo, Camila Macarena; Dennehy, Mariana; Alvarez, Mariana; Fe-Mn/ZrO2 catalysts: Sulfate-based-advanced oxidation process for the degradation of olive oil industry model pollutants; Elsevier Science; Catalysis Communications; 174; 106578; 5-12-2022; 1-9
1566-7367
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1566736722001832
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.catcom.2022.106578
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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