Biomass valorization derivatives: Clean esterification of 2-furoic acid using tungstophosphoric acid/zirconia composites as recyclable catalyst
- Autores
- Escobar Caicedo, Angélica María; Sathicq, Angel Gabriel; Blanco, Mirta Noemi; Pizzio, Luis Rene; Romanelli, Gustavo Pablo
- Año de publicación
- 2015
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- 2-Furoic acid esters, which are biomass derived, are used in the flavoring and fragrance industry or as synthesis intermediates in the pharmaceutical industry. A series of zirconia samples modified with different contents of tungstophosphoric acid (TPA) and two different preparation methods (ZrPEGTPA30T100, ZrPEGTPA60T100, ZrTPA30PEGT100, andZrTPA60PEGT100) were synthesized from zirconium propoxide via sol?gel reactions using polyethylene glycol as template. They were characterized by different physicochemical techniques (BET, FT-IR,31P MAS NMR and potentiometric titration), and their activities were tested in the synthesis of n-butyl-2-furoate as the model compound, among which ZrTPA30PEGT100, (mesoporous acid zirconia modified catalyst) was the most active catalyst.The effect of various parameters such as catalyst loading, mole ratio of 2-furoic acid ton-butanol, and temperature was studied under optimized conditions. Several other alkyl 2-furoates were produced from esterification of 2-furoic acid with different alcohols using these catalysts, and the effect of alcohol structure over the conversion reaction was considered. The use of a solid acid catalyst made the procedure environmentally benign. The catalysts ZrPEGTPA30T100 and ZrTPA30PEGT100 were reused without appreciable loss of the catalytic activity (three runs). The methodology represents a green and efficient alternative for the conversion of bio-based 2-furoic acid into valuable esters.
Fil: Escobar Caicedo, Angélica María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Sathicq, Angel Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Blanco, Mirta Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina - Materia
-
2-Furoic Acid
Alkyl-2-Furoates
Heteropolyacids/Zirconiacomposites
Biomass Valorization
Fragances
Flavors
Composites - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/5560
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Biomass valorization derivatives: Clean esterification of 2-furoic acid using tungstophosphoric acid/zirconia composites as recyclable catalystEscobar Caicedo, Angélica MaríaSathicq, Angel GabrielBlanco, Mirta NoemiPizzio, Luis ReneRomanelli, Gustavo Pablo2-Furoic AcidAlkyl-2-FuroatesHeteropolyacids/ZirconiacompositesBiomass ValorizationFragancesFlavorsCompositeshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/12-Furoic acid esters, which are biomass derived, are used in the flavoring and fragrance industry or as synthesis intermediates in the pharmaceutical industry. A series of zirconia samples modified with different contents of tungstophosphoric acid (TPA) and two different preparation methods (ZrPEGTPA30T100, ZrPEGTPA60T100, ZrTPA30PEGT100, andZrTPA60PEGT100) were synthesized from zirconium propoxide via sol?gel reactions using polyethylene glycol as template. They were characterized by different physicochemical techniques (BET, FT-IR,31P MAS NMR and potentiometric titration), and their activities were tested in the synthesis of n-butyl-2-furoate as the model compound, among which ZrTPA30PEGT100, (mesoporous acid zirconia modified catalyst) was the most active catalyst.The effect of various parameters such as catalyst loading, mole ratio of 2-furoic acid ton-butanol, and temperature was studied under optimized conditions. Several other alkyl 2-furoates were produced from esterification of 2-furoic acid with different alcohols using these catalysts, and the effect of alcohol structure over the conversion reaction was considered. The use of a solid acid catalyst made the procedure environmentally benign. The catalysts ZrPEGTPA30T100 and ZrTPA30PEGT100 were reused without appreciable loss of the catalytic activity (three runs). The methodology represents a green and efficient alternative for the conversion of bio-based 2-furoic acid into valuable esters.Fil: Escobar Caicedo, Angélica María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Sathicq, Angel Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Blanco, Mirta Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaElsevier2015-07-17info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5560Escobar Caicedo, Angélica María; Sathicq, Angel Gabriel; Blanco, Mirta Noemi; Pizzio, Luis Rene; Romanelli, Gustavo Pablo; Biomass valorization derivatives: Clean esterification of 2-furoic acid using tungstophosphoric acid/zirconia composites as recyclable catalyst; Elsevier; Process Safety and Environmental Protection; 98; 17-7-2015; 176-1860957-5820enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0957582015001317info:eu-repo/semantics/altIdentifier/doi/10.1016/j.psep.2015.07.008info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:43:47Zoai:ri.conicet.gov.ar:11336/5560instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:43:47.702CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Biomass valorization derivatives: Clean esterification of 2-furoic acid using tungstophosphoric acid/zirconia composites as recyclable catalyst |
title |
Biomass valorization derivatives: Clean esterification of 2-furoic acid using tungstophosphoric acid/zirconia composites as recyclable catalyst |
spellingShingle |
Biomass valorization derivatives: Clean esterification of 2-furoic acid using tungstophosphoric acid/zirconia composites as recyclable catalyst Escobar Caicedo, Angélica María 2-Furoic Acid Alkyl-2-Furoates Heteropolyacids/Zirconiacomposites Biomass Valorization Fragances Flavors Composites |
title_short |
Biomass valorization derivatives: Clean esterification of 2-furoic acid using tungstophosphoric acid/zirconia composites as recyclable catalyst |
title_full |
Biomass valorization derivatives: Clean esterification of 2-furoic acid using tungstophosphoric acid/zirconia composites as recyclable catalyst |
title_fullStr |
Biomass valorization derivatives: Clean esterification of 2-furoic acid using tungstophosphoric acid/zirconia composites as recyclable catalyst |
title_full_unstemmed |
Biomass valorization derivatives: Clean esterification of 2-furoic acid using tungstophosphoric acid/zirconia composites as recyclable catalyst |
title_sort |
Biomass valorization derivatives: Clean esterification of 2-furoic acid using tungstophosphoric acid/zirconia composites as recyclable catalyst |
dc.creator.none.fl_str_mv |
Escobar Caicedo, Angélica María Sathicq, Angel Gabriel Blanco, Mirta Noemi Pizzio, Luis Rene Romanelli, Gustavo Pablo |
author |
Escobar Caicedo, Angélica María |
author_facet |
Escobar Caicedo, Angélica María Sathicq, Angel Gabriel Blanco, Mirta Noemi Pizzio, Luis Rene Romanelli, Gustavo Pablo |
author_role |
author |
author2 |
Sathicq, Angel Gabriel Blanco, Mirta Noemi Pizzio, Luis Rene Romanelli, Gustavo Pablo |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
2-Furoic Acid Alkyl-2-Furoates Heteropolyacids/Zirconiacomposites Biomass Valorization Fragances Flavors Composites |
topic |
2-Furoic Acid Alkyl-2-Furoates Heteropolyacids/Zirconiacomposites Biomass Valorization Fragances Flavors Composites |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
2-Furoic acid esters, which are biomass derived, are used in the flavoring and fragrance industry or as synthesis intermediates in the pharmaceutical industry. A series of zirconia samples modified with different contents of tungstophosphoric acid (TPA) and two different preparation methods (ZrPEGTPA30T100, ZrPEGTPA60T100, ZrTPA30PEGT100, andZrTPA60PEGT100) were synthesized from zirconium propoxide via sol?gel reactions using polyethylene glycol as template. They were characterized by different physicochemical techniques (BET, FT-IR,31P MAS NMR and potentiometric titration), and their activities were tested in the synthesis of n-butyl-2-furoate as the model compound, among which ZrTPA30PEGT100, (mesoporous acid zirconia modified catalyst) was the most active catalyst.The effect of various parameters such as catalyst loading, mole ratio of 2-furoic acid ton-butanol, and temperature was studied under optimized conditions. Several other alkyl 2-furoates were produced from esterification of 2-furoic acid with different alcohols using these catalysts, and the effect of alcohol structure over the conversion reaction was considered. The use of a solid acid catalyst made the procedure environmentally benign. The catalysts ZrPEGTPA30T100 and ZrTPA30PEGT100 were reused without appreciable loss of the catalytic activity (three runs). The methodology represents a green and efficient alternative for the conversion of bio-based 2-furoic acid into valuable esters. Fil: Escobar Caicedo, Angélica María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina Fil: Sathicq, Angel Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina Fil: Blanco, Mirta Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina Fil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina |
description |
2-Furoic acid esters, which are biomass derived, are used in the flavoring and fragrance industry or as synthesis intermediates in the pharmaceutical industry. A series of zirconia samples modified with different contents of tungstophosphoric acid (TPA) and two different preparation methods (ZrPEGTPA30T100, ZrPEGTPA60T100, ZrTPA30PEGT100, andZrTPA60PEGT100) were synthesized from zirconium propoxide via sol?gel reactions using polyethylene glycol as template. They were characterized by different physicochemical techniques (BET, FT-IR,31P MAS NMR and potentiometric titration), and their activities were tested in the synthesis of n-butyl-2-furoate as the model compound, among which ZrTPA30PEGT100, (mesoporous acid zirconia modified catalyst) was the most active catalyst.The effect of various parameters such as catalyst loading, mole ratio of 2-furoic acid ton-butanol, and temperature was studied under optimized conditions. Several other alkyl 2-furoates were produced from esterification of 2-furoic acid with different alcohols using these catalysts, and the effect of alcohol structure over the conversion reaction was considered. The use of a solid acid catalyst made the procedure environmentally benign. The catalysts ZrPEGTPA30T100 and ZrTPA30PEGT100 were reused without appreciable loss of the catalytic activity (three runs). The methodology represents a green and efficient alternative for the conversion of bio-based 2-furoic acid into valuable esters. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-07-17 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/5560 Escobar Caicedo, Angélica María; Sathicq, Angel Gabriel; Blanco, Mirta Noemi; Pizzio, Luis Rene; Romanelli, Gustavo Pablo; Biomass valorization derivatives: Clean esterification of 2-furoic acid using tungstophosphoric acid/zirconia composites as recyclable catalyst; Elsevier; Process Safety and Environmental Protection; 98; 17-7-2015; 176-186 0957-5820 |
url |
http://hdl.handle.net/11336/5560 |
identifier_str_mv |
Escobar Caicedo, Angélica María; Sathicq, Angel Gabriel; Blanco, Mirta Noemi; Pizzio, Luis Rene; Romanelli, Gustavo Pablo; Biomass valorization derivatives: Clean esterification of 2-furoic acid using tungstophosphoric acid/zirconia composites as recyclable catalyst; Elsevier; Process Safety and Environmental Protection; 98; 17-7-2015; 176-186 0957-5820 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0957582015001317 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.psep.2015.07.008 info:eu-repo/semantics/altIdentifier/doi/ |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613378088108032 |
score |
13.070432 |