Synthesis and characterization of novel polyampholyte and polyelectrolyte polymers containing imidazole, triazole or pyrazole

Autores
Lazaro Martinez, Juan Manuel; Chattah, Ana Karina; Torres Sanchez, Rosa Maria; Buldain, Graciela Yolanda; Campodallorto, Viviana
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Novel soluble and non-soluble polymers based on methacrylic acid, ethylene glycol diglycidyl ether and pyrazole, triazole or imidazole were obtained by a one-spot synthetic strategy. The new materials were characterized by spectroscopic techniques (FT-IR, and solution- and solid-state NMR). Evidence on the covalent binding of the different heterocycles to the non-soluble matrix was given by the unequivocal assignment of the 13C solid-state NMR spectra. Proton relaxation times in the rotating frame and twodimensional wideline separation (1H-13C WISE) NMR spectra were used to assess their molecular dynamics. The higher synthetic yield of polyampholytes bearing triazole or pyrazole correlated with a lower molecular motion and a higher cross-linking degree. The polyelectrolyte effect of these materials was exhaustively explored through the acid-base properties, swelling and zeta potential. The quaternization of heterocyclic residues, responsible for adsorptive properties, was studied taking into account that these materials are attractive for analytical, environmental and biotechnological processes.
Fil: Lazaro Martinez, Juan Manuel. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Chattah, Ana Karina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomia y Física. Sección Física. Grupo de Resonancia Magnética Nuclear; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Torres Sanchez, Rosa Maria. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Buldain, Graciela Yolanda. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
Fil: Campodallorto, Viviana. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Analítica y Fisicoquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
Materia
NON SOLUBLE MATERIALS
POLYMERS
NMR
CHARACTERIZATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/269087
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/269087
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Synthesis and characterization of novel polyampholyte and polyelectrolyte polymers containing imidazole, triazole or pyrazoleLazaro Martinez, Juan ManuelChattah, Ana KarinaTorres Sanchez, Rosa MariaBuldain, Graciela YolandaCampodallorto, VivianaNON SOLUBLE MATERIALSPOLYMERSNMRCHARACTERIZATIONhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Novel soluble and non-soluble polymers based on methacrylic acid, ethylene glycol diglycidyl ether and pyrazole, triazole or imidazole were obtained by a one-spot synthetic strategy. The new materials were characterized by spectroscopic techniques (FT-IR, and solution- and solid-state NMR). Evidence on the covalent binding of the different heterocycles to the non-soluble matrix was given by the unequivocal assignment of the 13C solid-state NMR spectra. Proton relaxation times in the rotating frame and twodimensional wideline separation (1H-13C WISE) NMR spectra were used to assess their molecular dynamics. The higher synthetic yield of polyampholytes bearing triazole or pyrazole correlated with a lower molecular motion and a higher cross-linking degree. The polyelectrolyte effect of these materials was exhaustively explored through the acid-base properties, swelling and zeta potential. The quaternization of heterocyclic residues, responsible for adsorptive properties, was studied taking into account that these materials are attractive for analytical, environmental and biotechnological processes.Fil: Lazaro Martinez, Juan Manuel. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; ArgentinaFil: Chattah, Ana Karina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomia y Física. Sección Física. Grupo de Resonancia Magnética Nuclear; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; ArgentinaFil: Torres Sanchez, Rosa Maria. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaFil: Buldain, Graciela Yolanda. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; ArgentinaFil: Campodallorto, Viviana. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Analítica y Fisicoquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; ArgentinaElsevier2012-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/269087Lazaro Martinez, Juan Manuel; Chattah, Ana Karina; Torres Sanchez, Rosa Maria; Buldain, Graciela Yolanda; Campodallorto, Viviana; Synthesis and characterization of novel polyampholyte and polyelectrolyte polymers containing imidazole, triazole or pyrazole; Elsevier; Polymer; 53; 6; 3-2012; 1288-12970032-3861CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0032386112000584info:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymer.2012.01.031info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:08:29Zoai:ri.conicet.gov.ar:11336/269087instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:08:30.165CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis and characterization of novel polyampholyte and polyelectrolyte polymers containing imidazole, triazole or pyrazole
title Synthesis and characterization of novel polyampholyte and polyelectrolyte polymers containing imidazole, triazole or pyrazole
spellingShingle Synthesis and characterization of novel polyampholyte and polyelectrolyte polymers containing imidazole, triazole or pyrazole
Lazaro Martinez, Juan Manuel
NON SOLUBLE MATERIALS
POLYMERS
NMR
CHARACTERIZATION
title_short Synthesis and characterization of novel polyampholyte and polyelectrolyte polymers containing imidazole, triazole or pyrazole
title_full Synthesis and characterization of novel polyampholyte and polyelectrolyte polymers containing imidazole, triazole or pyrazole
title_fullStr Synthesis and characterization of novel polyampholyte and polyelectrolyte polymers containing imidazole, triazole or pyrazole
title_full_unstemmed Synthesis and characterization of novel polyampholyte and polyelectrolyte polymers containing imidazole, triazole or pyrazole
title_sort Synthesis and characterization of novel polyampholyte and polyelectrolyte polymers containing imidazole, triazole or pyrazole
dc.creator.none.fl_str_mv Lazaro Martinez, Juan Manuel
Chattah, Ana Karina
Torres Sanchez, Rosa Maria
Buldain, Graciela Yolanda
Campodallorto, Viviana
author Lazaro Martinez, Juan Manuel
author_facet Lazaro Martinez, Juan Manuel
Chattah, Ana Karina
Torres Sanchez, Rosa Maria
Buldain, Graciela Yolanda
Campodallorto, Viviana
author_role author
author2 Chattah, Ana Karina
Torres Sanchez, Rosa Maria
Buldain, Graciela Yolanda
Campodallorto, Viviana
author2_role author
author
author
author
dc.subject.none.fl_str_mv NON SOLUBLE MATERIALS
POLYMERS
NMR
CHARACTERIZATION
topic NON SOLUBLE MATERIALS
POLYMERS
NMR
CHARACTERIZATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Novel soluble and non-soluble polymers based on methacrylic acid, ethylene glycol diglycidyl ether and pyrazole, triazole or imidazole were obtained by a one-spot synthetic strategy. The new materials were characterized by spectroscopic techniques (FT-IR, and solution- and solid-state NMR). Evidence on the covalent binding of the different heterocycles to the non-soluble matrix was given by the unequivocal assignment of the 13C solid-state NMR spectra. Proton relaxation times in the rotating frame and twodimensional wideline separation (1H-13C WISE) NMR spectra were used to assess their molecular dynamics. The higher synthetic yield of polyampholytes bearing triazole or pyrazole correlated with a lower molecular motion and a higher cross-linking degree. The polyelectrolyte effect of these materials was exhaustively explored through the acid-base properties, swelling and zeta potential. The quaternization of heterocyclic residues, responsible for adsorptive properties, was studied taking into account that these materials are attractive for analytical, environmental and biotechnological processes.
Fil: Lazaro Martinez, Juan Manuel. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Chattah, Ana Karina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomia y Física. Sección Física. Grupo de Resonancia Magnética Nuclear; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Torres Sanchez, Rosa Maria. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Buldain, Graciela Yolanda. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
Fil: Campodallorto, Viviana. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Analítica y Fisicoquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
description Novel soluble and non-soluble polymers based on methacrylic acid, ethylene glycol diglycidyl ether and pyrazole, triazole or imidazole were obtained by a one-spot synthetic strategy. The new materials were characterized by spectroscopic techniques (FT-IR, and solution- and solid-state NMR). Evidence on the covalent binding of the different heterocycles to the non-soluble matrix was given by the unequivocal assignment of the 13C solid-state NMR spectra. Proton relaxation times in the rotating frame and twodimensional wideline separation (1H-13C WISE) NMR spectra were used to assess their molecular dynamics. The higher synthetic yield of polyampholytes bearing triazole or pyrazole correlated with a lower molecular motion and a higher cross-linking degree. The polyelectrolyte effect of these materials was exhaustively explored through the acid-base properties, swelling and zeta potential. The quaternization of heterocyclic residues, responsible for adsorptive properties, was studied taking into account that these materials are attractive for analytical, environmental and biotechnological processes.
publishDate 2012
dc.date.none.fl_str_mv 2012-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/269087
Lazaro Martinez, Juan Manuel; Chattah, Ana Karina; Torres Sanchez, Rosa Maria; Buldain, Graciela Yolanda; Campodallorto, Viviana; Synthesis and characterization of novel polyampholyte and polyelectrolyte polymers containing imidazole, triazole or pyrazole; Elsevier; Polymer; 53; 6; 3-2012; 1288-1297
0032-3861
CONICET Digital
CONICET
url http://hdl.handle.net/11336/269087
identifier_str_mv Lazaro Martinez, Juan Manuel; Chattah, Ana Karina; Torres Sanchez, Rosa Maria; Buldain, Graciela Yolanda; Campodallorto, Viviana; Synthesis and characterization of novel polyampholyte and polyelectrolyte polymers containing imidazole, triazole or pyrazole; Elsevier; Polymer; 53; 6; 3-2012; 1288-1297
0032-3861
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0032386112000584
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymer.2012.01.031
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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