Influence of processing conditions on morphological, thermal and degradative behavior of nanocomposites based on plasticized poly(3-hydroxybutyrate) and organo-modified clay

Autores
Puglia, D.; Fortunati, E.; D'amico, David Alberto; Miri, Valérie; Stoclet, Grégory; Manfredi, Liliana Beatriz; Cyras, Viviana Paola; Kenny, J.
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The effect of processing conditions (casting and extrusion) and plasticization on the disintegrability in compost of organically modified clay poly(3-hydroxybutyrate) nanocomposites was studied. Tributylhexadecylphosphonium bromide was used as organic modifier. As revealed by WAXS and TEM observations, Intercalated nano-biocomposites with clay stacks and some individually dispersed platelets were obtained. The melting temperature of the neat PHB diminished with the addition of plasticizer broadening the processing window.Biodegradation test revealed that while the clay slows down the degradation rate, the plasticizer increases the degradation of the samples, reaching a similar final percentage of disintegrability when both plasticizer and clay were added in the formulation.
Fil: Puglia, D.. Universita Di Perugia; Italia
Fil: Fortunati, E.. Universita Di Perugia; Italia
Fil: D'amico, David Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Miri, Valérie. Centre National de la Recherche Scientifique; Francia
Fil: Stoclet, Grégory. Centre National de la Recherche Scientifique; Francia
Fil: Manfredi, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Cyras, Viviana Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Kenny, J.. Universita Di Perugia; Italia
Materia
Phb
Nanoclay
Nanocomposite
Poly(3-Ydroxybutyrate)
Plasticizer
Disintegrability Compost
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/10141
Acceder
id CONICETDig_49dc9ec2ef206b37096477622485519a
oai_identifier_str oai:ri.conicet.gov.ar:11336/10141
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Influence of processing conditions on morphological, thermal and degradative behavior of nanocomposites based on plasticized poly(3-hydroxybutyrate) and organo-modified clayPuglia, D.Fortunati, E.D'amico, David AlbertoMiri, ValérieStoclet, GrégoryManfredi, Liliana BeatrizCyras, Viviana PaolaKenny, J.PhbNanoclayNanocompositePoly(3-Ydroxybutyrate)PlasticizerDisintegrability Composthttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The effect of processing conditions (casting and extrusion) and plasticization on the disintegrability in compost of organically modified clay poly(3-hydroxybutyrate) nanocomposites was studied. Tributylhexadecylphosphonium bromide was used as organic modifier. As revealed by WAXS and TEM observations, Intercalated nano-biocomposites with clay stacks and some individually dispersed platelets were obtained. The melting temperature of the neat PHB diminished with the addition of plasticizer broadening the processing window.Biodegradation test revealed that while the clay slows down the degradation rate, the plasticizer increases the degradation of the samples, reaching a similar final percentage of disintegrability when both plasticizer and clay were added in the formulation.Fil: Puglia, D.. Universita Di Perugia; ItaliaFil: Fortunati, E.. Universita Di Perugia; ItaliaFil: D'amico, David Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Miri, Valérie. Centre National de la Recherche Scientifique; FranciaFil: Stoclet, Grégory. Centre National de la Recherche Scientifique; FranciaFil: Manfredi, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Cyras, Viviana Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Kenny, J.. Universita Di Perugia; ItaliaSpringer2015-10-26info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/10141Puglia, D.; Fortunati, E.; D'amico, David Alberto; Miri, Valérie; Stoclet, Grégory; et al.; Influence of processing conditions on morphological, thermal and degradative behavior of nanocomposites based on plasticized poly(3-hydroxybutyrate) and organo-modified clay; Springer; Journal Of Polymers And The Environment; 24; 1; 26-10-2015; 12-221566-2543enginfo:eu-repo/semantics/altIdentifier/url/http://link.springer.com/article/10.1007/s10924-015-0744-5info:eu-repo/semantics/altIdentifier/doi/10.1007/s10924-015-0744-5info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:06:02Zoai:ri.conicet.gov.ar:11336/10141instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:06:02.421CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Influence of processing conditions on morphological, thermal and degradative behavior of nanocomposites based on plasticized poly(3-hydroxybutyrate) and organo-modified clay
title Influence of processing conditions on morphological, thermal and degradative behavior of nanocomposites based on plasticized poly(3-hydroxybutyrate) and organo-modified clay
spellingShingle Influence of processing conditions on morphological, thermal and degradative behavior of nanocomposites based on plasticized poly(3-hydroxybutyrate) and organo-modified clay
Puglia, D.
Phb
Nanoclay
Nanocomposite
Poly(3-Ydroxybutyrate)
Plasticizer
Disintegrability Compost
title_short Influence of processing conditions on morphological, thermal and degradative behavior of nanocomposites based on plasticized poly(3-hydroxybutyrate) and organo-modified clay
title_full Influence of processing conditions on morphological, thermal and degradative behavior of nanocomposites based on plasticized poly(3-hydroxybutyrate) and organo-modified clay
title_fullStr Influence of processing conditions on morphological, thermal and degradative behavior of nanocomposites based on plasticized poly(3-hydroxybutyrate) and organo-modified clay
title_full_unstemmed Influence of processing conditions on morphological, thermal and degradative behavior of nanocomposites based on plasticized poly(3-hydroxybutyrate) and organo-modified clay
title_sort Influence of processing conditions on morphological, thermal and degradative behavior of nanocomposites based on plasticized poly(3-hydroxybutyrate) and organo-modified clay
dc.creator.none.fl_str_mv Puglia, D.
Fortunati, E.
D'amico, David Alberto
Miri, Valérie
Stoclet, Grégory
Manfredi, Liliana Beatriz
Cyras, Viviana Paola
Kenny, J.
author Puglia, D.
author_facet Puglia, D.
Fortunati, E.
D'amico, David Alberto
Miri, Valérie
Stoclet, Grégory
Manfredi, Liliana Beatriz
Cyras, Viviana Paola
Kenny, J.
author_role author
author2 Fortunati, E.
D'amico, David Alberto
Miri, Valérie
Stoclet, Grégory
Manfredi, Liliana Beatriz
Cyras, Viviana Paola
Kenny, J.
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Phb
Nanoclay
Nanocomposite
Poly(3-Ydroxybutyrate)
Plasticizer
Disintegrability Compost
topic Phb
Nanoclay
Nanocomposite
Poly(3-Ydroxybutyrate)
Plasticizer
Disintegrability Compost
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The effect of processing conditions (casting and extrusion) and plasticization on the disintegrability in compost of organically modified clay poly(3-hydroxybutyrate) nanocomposites was studied. Tributylhexadecylphosphonium bromide was used as organic modifier. As revealed by WAXS and TEM observations, Intercalated nano-biocomposites with clay stacks and some individually dispersed platelets were obtained. The melting temperature of the neat PHB diminished with the addition of plasticizer broadening the processing window.Biodegradation test revealed that while the clay slows down the degradation rate, the plasticizer increases the degradation of the samples, reaching a similar final percentage of disintegrability when both plasticizer and clay were added in the formulation.
Fil: Puglia, D.. Universita Di Perugia; Italia
Fil: Fortunati, E.. Universita Di Perugia; Italia
Fil: D'amico, David Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Miri, Valérie. Centre National de la Recherche Scientifique; Francia
Fil: Stoclet, Grégory. Centre National de la Recherche Scientifique; Francia
Fil: Manfredi, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Cyras, Viviana Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Kenny, J.. Universita Di Perugia; Italia
description The effect of processing conditions (casting and extrusion) and plasticization on the disintegrability in compost of organically modified clay poly(3-hydroxybutyrate) nanocomposites was studied. Tributylhexadecylphosphonium bromide was used as organic modifier. As revealed by WAXS and TEM observations, Intercalated nano-biocomposites with clay stacks and some individually dispersed platelets were obtained. The melting temperature of the neat PHB diminished with the addition of plasticizer broadening the processing window.Biodegradation test revealed that while the clay slows down the degradation rate, the plasticizer increases the degradation of the samples, reaching a similar final percentage of disintegrability when both plasticizer and clay were added in the formulation.
publishDate 2015
dc.date.none.fl_str_mv 2015-10-26
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/10141
Puglia, D.; Fortunati, E.; D'amico, David Alberto; Miri, Valérie; Stoclet, Grégory; et al.; Influence of processing conditions on morphological, thermal and degradative behavior of nanocomposites based on plasticized poly(3-hydroxybutyrate) and organo-modified clay; Springer; Journal Of Polymers And The Environment; 24; 1; 26-10-2015; 12-22
1566-2543
url http://hdl.handle.net/11336/10141
identifier_str_mv Puglia, D.; Fortunati, E.; D'amico, David Alberto; Miri, Valérie; Stoclet, Grégory; et al.; Influence of processing conditions on morphological, thermal and degradative behavior of nanocomposites based on plasticized poly(3-hydroxybutyrate) and organo-modified clay; Springer; Journal Of Polymers And The Environment; 24; 1; 26-10-2015; 12-22
1566-2543
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://link.springer.com/article/10.1007/s10924-015-0744-5
info:eu-repo/semantics/altIdentifier/doi/10.1007/s10924-015-0744-5
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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