La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study
- Autores
- López, C. A.; Viola, M. C.; Pedregosa, Jose Carmelo; Carbonio, Raul Ernesto; Sanchez, Rodolfo Daniel; Fernández Díaz, M. T.
- Año de publicación
- 2008
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- La-doped Sr2CoWO6 double perovskites have been prepared in air in polycrystalline form by solid-state reaction. These materials have been studied by X-ray powder diffraction (XRPD), neutron powder diffraction (NPD) and magnetic susceptibility. The structural refinement was performed from combined XRPD and NPD data (D2B instrument, λ=1.594 Å). At room temperature, the replacement of Sr2+ by La3+ induces a change of the tetragonal structure, space group I4/m of the undoped Sr2CoWO6 into the distorted monoclinic crystal structure, space group P21/n, Z=2. The structure of La-doped phases contains alternating CoO6 and (Co/W)O6 octahedra, almost fully ordered. On the other hand, the replacement of Sr2+ by La3+ induces a partial replacement of W6+ by Co2+ into the B sites, i.e. Sr2-xLaxCoW1-yCoyO6 (y=x/4) with segregation of SrWO4. Magnetic and neutron diffraction measurements indicate an antiferromagnetic ordering below TN=24 K independently of the La-substitution.
Fil: López, C. A.. Universidad Nacional de San Luis; Argentina
Fil: Viola, M. C.. Universidad Nacional de San Luis; Argentina
Fil: Pedregosa, Jose Carmelo. Universidad Nacional de San Luis; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Carbonio, Raul Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Sanchez, Rodolfo Daniel. Universidad Nacional de Cuyo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina
Fil: Fernández Díaz, M. T.. Institut Laue Langevin; Francia - Materia
-
Double Perovskite
La Doped
Magnetic Behavior
Sr2cowo6
Structure - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/68570
Ver los metadatos del registro completo
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La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic studyLópez, C. A.Viola, M. C.Pedregosa, Jose CarmeloCarbonio, Raul ErnestoSanchez, Rodolfo DanielFernández Díaz, M. T.Double PerovskiteLa DopedMagnetic BehaviorSr2cowo6Structurehttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1La-doped Sr2CoWO6 double perovskites have been prepared in air in polycrystalline form by solid-state reaction. These materials have been studied by X-ray powder diffraction (XRPD), neutron powder diffraction (NPD) and magnetic susceptibility. The structural refinement was performed from combined XRPD and NPD data (D2B instrument, λ=1.594 Å). At room temperature, the replacement of Sr2+ by La3+ induces a change of the tetragonal structure, space group I4/m of the undoped Sr2CoWO6 into the distorted monoclinic crystal structure, space group P21/n, Z=2. The structure of La-doped phases contains alternating CoO6 and (Co/W)O6 octahedra, almost fully ordered. On the other hand, the replacement of Sr2+ by La3+ induces a partial replacement of W6+ by Co2+ into the B sites, i.e. Sr2-xLaxCoW1-yCoyO6 (y=x/4) with segregation of SrWO4. Magnetic and neutron diffraction measurements indicate an antiferromagnetic ordering below TN=24 K independently of the La-substitution.Fil: López, C. A.. Universidad Nacional de San Luis; ArgentinaFil: Viola, M. C.. Universidad Nacional de San Luis; ArgentinaFil: Pedregosa, Jose Carmelo. Universidad Nacional de San Luis; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Carbonio, Raul Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Sanchez, Rodolfo Daniel. Universidad Nacional de Cuyo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; ArgentinaFil: Fernández Díaz, M. T.. Institut Laue Langevin; FranciaAcademic Press Inc Elsevier Science2008-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/68570López, C. A.; Viola, M. C.; Pedregosa, Jose Carmelo; Carbonio, Raul Ernesto; Sanchez, Rodolfo Daniel; et al.; La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study; Academic Press Inc Elsevier Science; Journal of Solid State Chemistry; 181; 11; 11-2008; 3095-31020022-4596CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0022459608004350info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jssc.2008.08.007info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:45:08Zoai:ri.conicet.gov.ar:11336/68570instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:45:09.188CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study |
title |
La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study |
spellingShingle |
La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study López, C. A. Double Perovskite La Doped Magnetic Behavior Sr2cowo6 Structure |
title_short |
La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study |
title_full |
La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study |
title_fullStr |
La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study |
title_full_unstemmed |
La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study |
title_sort |
La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study |
dc.creator.none.fl_str_mv |
López, C. A. Viola, M. C. Pedregosa, Jose Carmelo Carbonio, Raul Ernesto Sanchez, Rodolfo Daniel Fernández Díaz, M. T. |
author |
López, C. A. |
author_facet |
López, C. A. Viola, M. C. Pedregosa, Jose Carmelo Carbonio, Raul Ernesto Sanchez, Rodolfo Daniel Fernández Díaz, M. T. |
author_role |
author |
author2 |
Viola, M. C. Pedregosa, Jose Carmelo Carbonio, Raul Ernesto Sanchez, Rodolfo Daniel Fernández Díaz, M. T. |
author2_role |
author author author author author |
dc.subject.none.fl_str_mv |
Double Perovskite La Doped Magnetic Behavior Sr2cowo6 Structure |
topic |
Double Perovskite La Doped Magnetic Behavior Sr2cowo6 Structure |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.3 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
La-doped Sr2CoWO6 double perovskites have been prepared in air in polycrystalline form by solid-state reaction. These materials have been studied by X-ray powder diffraction (XRPD), neutron powder diffraction (NPD) and magnetic susceptibility. The structural refinement was performed from combined XRPD and NPD data (D2B instrument, λ=1.594 Å). At room temperature, the replacement of Sr2+ by La3+ induces a change of the tetragonal structure, space group I4/m of the undoped Sr2CoWO6 into the distorted monoclinic crystal structure, space group P21/n, Z=2. The structure of La-doped phases contains alternating CoO6 and (Co/W)O6 octahedra, almost fully ordered. On the other hand, the replacement of Sr2+ by La3+ induces a partial replacement of W6+ by Co2+ into the B sites, i.e. Sr2-xLaxCoW1-yCoyO6 (y=x/4) with segregation of SrWO4. Magnetic and neutron diffraction measurements indicate an antiferromagnetic ordering below TN=24 K independently of the La-substitution. Fil: López, C. A.. Universidad Nacional de San Luis; Argentina Fil: Viola, M. C.. Universidad Nacional de San Luis; Argentina Fil: Pedregosa, Jose Carmelo. Universidad Nacional de San Luis; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Carbonio, Raul Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina Fil: Sanchez, Rodolfo Daniel. Universidad Nacional de Cuyo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina Fil: Fernández Díaz, M. T.. Institut Laue Langevin; Francia |
description |
La-doped Sr2CoWO6 double perovskites have been prepared in air in polycrystalline form by solid-state reaction. These materials have been studied by X-ray powder diffraction (XRPD), neutron powder diffraction (NPD) and magnetic susceptibility. The structural refinement was performed from combined XRPD and NPD data (D2B instrument, λ=1.594 Å). At room temperature, the replacement of Sr2+ by La3+ induces a change of the tetragonal structure, space group I4/m of the undoped Sr2CoWO6 into the distorted monoclinic crystal structure, space group P21/n, Z=2. The structure of La-doped phases contains alternating CoO6 and (Co/W)O6 octahedra, almost fully ordered. On the other hand, the replacement of Sr2+ by La3+ induces a partial replacement of W6+ by Co2+ into the B sites, i.e. Sr2-xLaxCoW1-yCoyO6 (y=x/4) with segregation of SrWO4. Magnetic and neutron diffraction measurements indicate an antiferromagnetic ordering below TN=24 K independently of the La-substitution. |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008-11 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/68570 López, C. A.; Viola, M. C.; Pedregosa, Jose Carmelo; Carbonio, Raul Ernesto; Sanchez, Rodolfo Daniel; et al.; La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study; Academic Press Inc Elsevier Science; Journal of Solid State Chemistry; 181; 11; 11-2008; 3095-3102 0022-4596 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/68570 |
identifier_str_mv |
López, C. A.; Viola, M. C.; Pedregosa, Jose Carmelo; Carbonio, Raul Ernesto; Sanchez, Rodolfo Daniel; et al.; La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study; Academic Press Inc Elsevier Science; Journal of Solid State Chemistry; 181; 11; 11-2008; 3095-3102 0022-4596 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0022459608004350 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jssc.2008.08.007 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Academic Press Inc Elsevier Science |
publisher.none.fl_str_mv |
Academic Press Inc Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844614490281213952 |
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13.070432 |