La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study

Autores
López, C. A.; Viola, M. C.; Pedregosa, Jose Carmelo; Carbonio, Raul Ernesto; Sanchez, Rodolfo Daniel; Fernández Díaz, M. T.
Año de publicación
2008
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
La-doped Sr2CoWO6 double perovskites have been prepared in air in polycrystalline form by solid-state reaction. These materials have been studied by X-ray powder diffraction (XRPD), neutron powder diffraction (NPD) and magnetic susceptibility. The structural refinement was performed from combined XRPD and NPD data (D2B instrument, λ=1.594 Å). At room temperature, the replacement of Sr2+ by La3+ induces a change of the tetragonal structure, space group I4/m of the undoped Sr2CoWO6 into the distorted monoclinic crystal structure, space group P21/n, Z=2. The structure of La-doped phases contains alternating CoO6 and (Co/W)O6 octahedra, almost fully ordered. On the other hand, the replacement of Sr2+ by La3+ induces a partial replacement of W6+ by Co2+ into the B sites, i.e. Sr2-xLaxCoW1-yCoyO6 (y=x/4) with segregation of SrWO4. Magnetic and neutron diffraction measurements indicate an antiferromagnetic ordering below TN=24 K independently of the La-substitution.
Fil: López, C. A.. Universidad Nacional de San Luis; Argentina
Fil: Viola, M. C.. Universidad Nacional de San Luis; Argentina
Fil: Pedregosa, Jose Carmelo. Universidad Nacional de San Luis; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Carbonio, Raul Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Sanchez, Rodolfo Daniel. Universidad Nacional de Cuyo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina
Fil: Fernández Díaz, M. T.. Institut Laue Langevin; Francia
Materia
Double Perovskite
La Doped
Magnetic Behavior
Sr2cowo6
Structure
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/68570
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/68570
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic studyLópez, C. A.Viola, M. C.Pedregosa, Jose CarmeloCarbonio, Raul ErnestoSanchez, Rodolfo DanielFernández Díaz, M. T.Double PerovskiteLa DopedMagnetic BehaviorSr2cowo6Structurehttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1La-doped Sr2CoWO6 double perovskites have been prepared in air in polycrystalline form by solid-state reaction. These materials have been studied by X-ray powder diffraction (XRPD), neutron powder diffraction (NPD) and magnetic susceptibility. The structural refinement was performed from combined XRPD and NPD data (D2B instrument, λ=1.594 Å). At room temperature, the replacement of Sr2+ by La3+ induces a change of the tetragonal structure, space group I4/m of the undoped Sr2CoWO6 into the distorted monoclinic crystal structure, space group P21/n, Z=2. The structure of La-doped phases contains alternating CoO6 and (Co/W)O6 octahedra, almost fully ordered. On the other hand, the replacement of Sr2+ by La3+ induces a partial replacement of W6+ by Co2+ into the B sites, i.e. Sr2-xLaxCoW1-yCoyO6 (y=x/4) with segregation of SrWO4. Magnetic and neutron diffraction measurements indicate an antiferromagnetic ordering below TN=24 K independently of the La-substitution.Fil: López, C. A.. Universidad Nacional de San Luis; ArgentinaFil: Viola, M. C.. Universidad Nacional de San Luis; ArgentinaFil: Pedregosa, Jose Carmelo. Universidad Nacional de San Luis; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Carbonio, Raul Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Sanchez, Rodolfo Daniel. Universidad Nacional de Cuyo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; ArgentinaFil: Fernández Díaz, M. T.. Institut Laue Langevin; FranciaAcademic Press Inc Elsevier Science2008-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/68570López, C. A.; Viola, M. C.; Pedregosa, Jose Carmelo; Carbonio, Raul Ernesto; Sanchez, Rodolfo Daniel; et al.; La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study; Academic Press Inc Elsevier Science; Journal of Solid State Chemistry; 181; 11; 11-2008; 3095-31020022-4596CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0022459608004350info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jssc.2008.08.007info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T12:18:24Zoai:ri.conicet.gov.ar:11336/68570instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 12:18:25.05CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study
title La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study
spellingShingle La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study
López, C. A.
Double Perovskite
La Doped
Magnetic Behavior
Sr2cowo6
Structure
title_short La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study
title_full La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study
title_fullStr La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study
title_full_unstemmed La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study
title_sort La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study
dc.creator.none.fl_str_mv López, C. A.
Viola, M. C.
Pedregosa, Jose Carmelo
Carbonio, Raul Ernesto
Sanchez, Rodolfo Daniel
Fernández Díaz, M. T.
author López, C. A.
author_facet López, C. A.
Viola, M. C.
Pedregosa, Jose Carmelo
Carbonio, Raul Ernesto
Sanchez, Rodolfo Daniel
Fernández Díaz, M. T.
author_role author
author2 Viola, M. C.
Pedregosa, Jose Carmelo
Carbonio, Raul Ernesto
Sanchez, Rodolfo Daniel
Fernández Díaz, M. T.
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Double Perovskite
La Doped
Magnetic Behavior
Sr2cowo6
Structure
topic Double Perovskite
La Doped
Magnetic Behavior
Sr2cowo6
Structure
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv La-doped Sr2CoWO6 double perovskites have been prepared in air in polycrystalline form by solid-state reaction. These materials have been studied by X-ray powder diffraction (XRPD), neutron powder diffraction (NPD) and magnetic susceptibility. The structural refinement was performed from combined XRPD and NPD data (D2B instrument, λ=1.594 Å). At room temperature, the replacement of Sr2+ by La3+ induces a change of the tetragonal structure, space group I4/m of the undoped Sr2CoWO6 into the distorted monoclinic crystal structure, space group P21/n, Z=2. The structure of La-doped phases contains alternating CoO6 and (Co/W)O6 octahedra, almost fully ordered. On the other hand, the replacement of Sr2+ by La3+ induces a partial replacement of W6+ by Co2+ into the B sites, i.e. Sr2-xLaxCoW1-yCoyO6 (y=x/4) with segregation of SrWO4. Magnetic and neutron diffraction measurements indicate an antiferromagnetic ordering below TN=24 K independently of the La-substitution.
Fil: López, C. A.. Universidad Nacional de San Luis; Argentina
Fil: Viola, M. C.. Universidad Nacional de San Luis; Argentina
Fil: Pedregosa, Jose Carmelo. Universidad Nacional de San Luis; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Carbonio, Raul Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Sanchez, Rodolfo Daniel. Universidad Nacional de Cuyo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina
Fil: Fernández Díaz, M. T.. Institut Laue Langevin; Francia
description La-doped Sr2CoWO6 double perovskites have been prepared in air in polycrystalline form by solid-state reaction. These materials have been studied by X-ray powder diffraction (XRPD), neutron powder diffraction (NPD) and magnetic susceptibility. The structural refinement was performed from combined XRPD and NPD data (D2B instrument, λ=1.594 Å). At room temperature, the replacement of Sr2+ by La3+ induces a change of the tetragonal structure, space group I4/m of the undoped Sr2CoWO6 into the distorted monoclinic crystal structure, space group P21/n, Z=2. The structure of La-doped phases contains alternating CoO6 and (Co/W)O6 octahedra, almost fully ordered. On the other hand, the replacement of Sr2+ by La3+ induces a partial replacement of W6+ by Co2+ into the B sites, i.e. Sr2-xLaxCoW1-yCoyO6 (y=x/4) with segregation of SrWO4. Magnetic and neutron diffraction measurements indicate an antiferromagnetic ordering below TN=24 K independently of the La-substitution.
publishDate 2008
dc.date.none.fl_str_mv 2008-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/68570
López, C. A.; Viola, M. C.; Pedregosa, Jose Carmelo; Carbonio, Raul Ernesto; Sanchez, Rodolfo Daniel; et al.; La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study; Academic Press Inc Elsevier Science; Journal of Solid State Chemistry; 181; 11; 11-2008; 3095-3102
0022-4596
CONICET Digital
CONICET
url http://hdl.handle.net/11336/68570
identifier_str_mv López, C. A.; Viola, M. C.; Pedregosa, Jose Carmelo; Carbonio, Raul Ernesto; Sanchez, Rodolfo Daniel; et al.; La3+ doping of the Sr2CoWO6 double perovskite: A structural and magnetic study; Academic Press Inc Elsevier Science; Journal of Solid State Chemistry; 181; 11; 11-2008; 3095-3102
0022-4596
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0022459608004350
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jssc.2008.08.007
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Academic Press Inc Elsevier Science
publisher.none.fl_str_mv Academic Press Inc Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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