Synthesis and characterization of a mixture of CoFe2O4 and MgFe2O4 from layered double hydroxides: Band gap energy and magnetic responses

Autores
Marchetti, Sergio Gustavo; Casuscelli, Sandra Graciela; Heredia, Angelica Constanza; Crivello, Mónica Elsie; Oliva, Marcos Iván; Agú, Ulises Ariel
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A mixture of nanocrystals of cobalt ferrite and magnesium ferrite was obtained from Layered Double Hydroxides (LDH) through a co-precitation method with a theoretical molar ratio M2+:Fe3+=3:1, where M 2+represents Mg2+ and/or Co2+. The molar ratios between Co2+:Fe3+ were 0.0 (0Co), 0.2 (5Co), and 0.4 (10Co). In order to assess the effect on the properties of the LDH and their oxides, the molar percentages were 0, 5 and 10%. Two different synthesis methods were evaluated; (i) ageing at room temperature (rt), and (ii) hydrothermal ageing at 200 °C in autoclave (ht), both methods needed 15 h of ageing. Then, these LDH were calcined in air atmosphere at 550 °C for 10 h. The calcined materials were characterized by X-ray diffraction (XRD), thermogravymetric analysis (TGA), temperature-programmed reduction (TPR), infrared spectroscopy with Fourier transform (FTIR), Diffuse Reflectance UV-visible spectroscopy (UV-vis-DRS), Mössbauer spectroscopy and inductively coupled plasma optical emission spectroscopy (ICP-OES). The magnetic response was analyzed using a vibrating sample magnetometer (VSM). The band gap energy of the iron oxides was determined through the UV-vis-DRS analysis. Through these studies it was possible to identify the presence of a mixture of cobalt ferrite and magnesium ferrite. Samples did not show hematite and cobalt oxides, but the presence of MgO in the periclase phase was determined. This magnesium oxide promoted a good dispersion of the ferrites. Moreover, when a single ferrite phase of Co or Mg was formed, a diminution of the crystal size with consequent enlarged values of band gap energy was observed. Thus, materials synthesized by room temperature ageing promoted the superparamagnetic behaviour of samples, attributed to the content of the cobalt ferrite structure in nanocrystals. In regard to the estimated band gap energy, all samples exhibited low levels. These results indicate that these solids would be suitable for photocatalysts use in all visible light range, and that they could be easily removed from the reaction medium by a simple magnetic separation procedure.
Fil: Marchetti, Sergio Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Casuscelli, Sandra Graciela. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Cordoba. Centro de Investigacion y Tecnologia Quimica; Argentina. Universidad Tecnologica Nacional; Argentina
Fil: Heredia, Angelica Constanza. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Cordoba. Centro de Investigacion y Tecnologia Quimica; Argentina
Fil: Crivello, Mónica Elsie. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Cordoba. Centro de Investigacion y Tecnologia Quimica; Argentina
Fil: Oliva, Marcos Iván. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Física "Enrique Gaviola"; Argentina
Fil: Agú, Ulises Ariel. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Cordoba. Centro de Investigacion y Tecnologia Quimica; Argentina
Materia
Ferrites
Nanocrystals
Band Gap
Ldh
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/2989
Acceder
id CONICETDig_46cd5bf227f0bde5f9929e31fffefeea
oai_identifier_str oai:ri.conicet.gov.ar:11336/2989
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Synthesis and characterization of a mixture of CoFe2O4 and MgFe2O4 from layered double hydroxides: Band gap energy and magnetic responsesMarchetti, Sergio GustavoCasuscelli, Sandra GracielaHeredia, Angelica ConstanzaCrivello, Mónica ElsieOliva, Marcos IvánAgú, Ulises ArielFerritesNanocrystalsBand GapLdhhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A mixture of nanocrystals of cobalt ferrite and magnesium ferrite was obtained from Layered Double Hydroxides (LDH) through a co-precitation method with a theoretical molar ratio M2+:Fe3+=3:1, where M 2+represents Mg2+ and/or Co2+. The molar ratios between Co2+:Fe3+ were 0.0 (0Co), 0.2 (5Co), and 0.4 (10Co). In order to assess the effect on the properties of the LDH and their oxides, the molar percentages were 0, 5 and 10%. Two different synthesis methods were evaluated; (i) ageing at room temperature (rt), and (ii) hydrothermal ageing at 200 °C in autoclave (ht), both methods needed 15 h of ageing. Then, these LDH were calcined in air atmosphere at 550 °C for 10 h. The calcined materials were characterized by X-ray diffraction (XRD), thermogravymetric analysis (TGA), temperature-programmed reduction (TPR), infrared spectroscopy with Fourier transform (FTIR), Diffuse Reflectance UV-visible spectroscopy (UV-vis-DRS), Mössbauer spectroscopy and inductively coupled plasma optical emission spectroscopy (ICP-OES). The magnetic response was analyzed using a vibrating sample magnetometer (VSM). The band gap energy of the iron oxides was determined through the UV-vis-DRS analysis. Through these studies it was possible to identify the presence of a mixture of cobalt ferrite and magnesium ferrite. Samples did not show hematite and cobalt oxides, but the presence of MgO in the periclase phase was determined. This magnesium oxide promoted a good dispersion of the ferrites. Moreover, when a single ferrite phase of Co or Mg was formed, a diminution of the crystal size with consequent enlarged values of band gap energy was observed. Thus, materials synthesized by room temperature ageing promoted the superparamagnetic behaviour of samples, attributed to the content of the cobalt ferrite structure in nanocrystals. In regard to the estimated band gap energy, all samples exhibited low levels. These results indicate that these solids would be suitable for photocatalysts use in all visible light range, and that they could be easily removed from the reaction medium by a simple magnetic separation procedure.Fil: Marchetti, Sergio Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Casuscelli, Sandra Graciela. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Cordoba. Centro de Investigacion y Tecnologia Quimica; Argentina. Universidad Tecnologica Nacional; ArgentinaFil: Heredia, Angelica Constanza. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Cordoba. Centro de Investigacion y Tecnologia Quimica; ArgentinaFil: Crivello, Mónica Elsie. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Cordoba. Centro de Investigacion y Tecnologia Quimica; ArgentinaFil: Oliva, Marcos Iván. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Física "Enrique Gaviola"; ArgentinaFil: Agú, Ulises Ariel. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Cordoba. Centro de Investigacion y Tecnologia Quimica; ArgentinaElsevier Science2014-06-21info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/2989Marchetti, Sergio Gustavo; Casuscelli, Sandra Graciela; Heredia, Angelica Constanza; Crivello, Mónica Elsie; Oliva, Marcos Iván; et al.; Synthesis and characterization of a mixture of CoFe2O4 and MgFe2O4 from layered double hydroxides: Band gap energy and magnetic responses; Elsevier Science; Journal of Magnetism and Magnetic Materials; 369; 21-6-2014; 249-2590304-8853enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jmmm.2014.06.046info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S030488531400568Xinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:59:21Zoai:ri.conicet.gov.ar:11336/2989instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:59:21.916CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis and characterization of a mixture of CoFe2O4 and MgFe2O4 from layered double hydroxides: Band gap energy and magnetic responses
title Synthesis and characterization of a mixture of CoFe2O4 and MgFe2O4 from layered double hydroxides: Band gap energy and magnetic responses
spellingShingle Synthesis and characterization of a mixture of CoFe2O4 and MgFe2O4 from layered double hydroxides: Band gap energy and magnetic responses
Marchetti, Sergio Gustavo
Ferrites
Nanocrystals
Band Gap
Ldh
title_short Synthesis and characterization of a mixture of CoFe2O4 and MgFe2O4 from layered double hydroxides: Band gap energy and magnetic responses
title_full Synthesis and characterization of a mixture of CoFe2O4 and MgFe2O4 from layered double hydroxides: Band gap energy and magnetic responses
title_fullStr Synthesis and characterization of a mixture of CoFe2O4 and MgFe2O4 from layered double hydroxides: Band gap energy and magnetic responses
title_full_unstemmed Synthesis and characterization of a mixture of CoFe2O4 and MgFe2O4 from layered double hydroxides: Band gap energy and magnetic responses
title_sort Synthesis and characterization of a mixture of CoFe2O4 and MgFe2O4 from layered double hydroxides: Band gap energy and magnetic responses
dc.creator.none.fl_str_mv Marchetti, Sergio Gustavo
Casuscelli, Sandra Graciela
Heredia, Angelica Constanza
Crivello, Mónica Elsie
Oliva, Marcos Iván
Agú, Ulises Ariel
author Marchetti, Sergio Gustavo
author_facet Marchetti, Sergio Gustavo
Casuscelli, Sandra Graciela
Heredia, Angelica Constanza
Crivello, Mónica Elsie
Oliva, Marcos Iván
Agú, Ulises Ariel
author_role author
author2 Casuscelli, Sandra Graciela
Heredia, Angelica Constanza
Crivello, Mónica Elsie
Oliva, Marcos Iván
Agú, Ulises Ariel
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Ferrites
Nanocrystals
Band Gap
Ldh
topic Ferrites
Nanocrystals
Band Gap
Ldh
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A mixture of nanocrystals of cobalt ferrite and magnesium ferrite was obtained from Layered Double Hydroxides (LDH) through a co-precitation method with a theoretical molar ratio M2+:Fe3+=3:1, where M 2+represents Mg2+ and/or Co2+. The molar ratios between Co2+:Fe3+ were 0.0 (0Co), 0.2 (5Co), and 0.4 (10Co). In order to assess the effect on the properties of the LDH and their oxides, the molar percentages were 0, 5 and 10%. Two different synthesis methods were evaluated; (i) ageing at room temperature (rt), and (ii) hydrothermal ageing at 200 °C in autoclave (ht), both methods needed 15 h of ageing. Then, these LDH were calcined in air atmosphere at 550 °C for 10 h. The calcined materials were characterized by X-ray diffraction (XRD), thermogravymetric analysis (TGA), temperature-programmed reduction (TPR), infrared spectroscopy with Fourier transform (FTIR), Diffuse Reflectance UV-visible spectroscopy (UV-vis-DRS), Mössbauer spectroscopy and inductively coupled plasma optical emission spectroscopy (ICP-OES). The magnetic response was analyzed using a vibrating sample magnetometer (VSM). The band gap energy of the iron oxides was determined through the UV-vis-DRS analysis. Through these studies it was possible to identify the presence of a mixture of cobalt ferrite and magnesium ferrite. Samples did not show hematite and cobalt oxides, but the presence of MgO in the periclase phase was determined. This magnesium oxide promoted a good dispersion of the ferrites. Moreover, when a single ferrite phase of Co or Mg was formed, a diminution of the crystal size with consequent enlarged values of band gap energy was observed. Thus, materials synthesized by room temperature ageing promoted the superparamagnetic behaviour of samples, attributed to the content of the cobalt ferrite structure in nanocrystals. In regard to the estimated band gap energy, all samples exhibited low levels. These results indicate that these solids would be suitable for photocatalysts use in all visible light range, and that they could be easily removed from the reaction medium by a simple magnetic separation procedure.
Fil: Marchetti, Sergio Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Casuscelli, Sandra Graciela. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Cordoba. Centro de Investigacion y Tecnologia Quimica; Argentina. Universidad Tecnologica Nacional; Argentina
Fil: Heredia, Angelica Constanza. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Cordoba. Centro de Investigacion y Tecnologia Quimica; Argentina
Fil: Crivello, Mónica Elsie. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Cordoba. Centro de Investigacion y Tecnologia Quimica; Argentina
Fil: Oliva, Marcos Iván. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Física "Enrique Gaviola"; Argentina
Fil: Agú, Ulises Ariel. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Cordoba. Centro de Investigacion y Tecnologia Quimica; Argentina
description A mixture of nanocrystals of cobalt ferrite and magnesium ferrite was obtained from Layered Double Hydroxides (LDH) through a co-precitation method with a theoretical molar ratio M2+:Fe3+=3:1, where M 2+represents Mg2+ and/or Co2+. The molar ratios between Co2+:Fe3+ were 0.0 (0Co), 0.2 (5Co), and 0.4 (10Co). In order to assess the effect on the properties of the LDH and their oxides, the molar percentages were 0, 5 and 10%. Two different synthesis methods were evaluated; (i) ageing at room temperature (rt), and (ii) hydrothermal ageing at 200 °C in autoclave (ht), both methods needed 15 h of ageing. Then, these LDH were calcined in air atmosphere at 550 °C for 10 h. The calcined materials were characterized by X-ray diffraction (XRD), thermogravymetric analysis (TGA), temperature-programmed reduction (TPR), infrared spectroscopy with Fourier transform (FTIR), Diffuse Reflectance UV-visible spectroscopy (UV-vis-DRS), Mössbauer spectroscopy and inductively coupled plasma optical emission spectroscopy (ICP-OES). The magnetic response was analyzed using a vibrating sample magnetometer (VSM). The band gap energy of the iron oxides was determined through the UV-vis-DRS analysis. Through these studies it was possible to identify the presence of a mixture of cobalt ferrite and magnesium ferrite. Samples did not show hematite and cobalt oxides, but the presence of MgO in the periclase phase was determined. This magnesium oxide promoted a good dispersion of the ferrites. Moreover, when a single ferrite phase of Co or Mg was formed, a diminution of the crystal size with consequent enlarged values of band gap energy was observed. Thus, materials synthesized by room temperature ageing promoted the superparamagnetic behaviour of samples, attributed to the content of the cobalt ferrite structure in nanocrystals. In regard to the estimated band gap energy, all samples exhibited low levels. These results indicate that these solids would be suitable for photocatalysts use in all visible light range, and that they could be easily removed from the reaction medium by a simple magnetic separation procedure.
publishDate 2014
dc.date.none.fl_str_mv 2014-06-21
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/2989
Marchetti, Sergio Gustavo; Casuscelli, Sandra Graciela; Heredia, Angelica Constanza; Crivello, Mónica Elsie; Oliva, Marcos Iván; et al.; Synthesis and characterization of a mixture of CoFe2O4 and MgFe2O4 from layered double hydroxides: Band gap energy and magnetic responses; Elsevier Science; Journal of Magnetism and Magnetic Materials; 369; 21-6-2014; 249-259
0304-8853
url http://hdl.handle.net/11336/2989
identifier_str_mv Marchetti, Sergio Gustavo; Casuscelli, Sandra Graciela; Heredia, Angelica Constanza; Crivello, Mónica Elsie; Oliva, Marcos Iván; et al.; Synthesis and characterization of a mixture of CoFe2O4 and MgFe2O4 from layered double hydroxides: Band gap energy and magnetic responses; Elsevier Science; Journal of Magnetism and Magnetic Materials; 369; 21-6-2014; 249-259
0304-8853
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jmmm.2014.06.046
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S030488531400568X
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613761819738112
score 13.070432

Publicaciones similares