Excess molar volumes and excess viscosities of the 2,2,4-trimethylpentane (1) + 3-methyl-1-butanol (2) and propan-2-ol (3) ternary system at 298.15 K

Autores
Salas, J.A.; Pedrosa, G.C.; Acevedo, I.L.; Arancibia, Eleuterio Luis
Año de publicación
2006
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This paper reports experimental densities and viscosities of the ternary system 2-2-4-trimethylpentane + 3-methyl-1-butanol + propan-2-ol and the binary systems 2-2-4-trimethylpentane (isooctane) + 3-methyl-1-butanol (isoamyl alcohol), 2-2-4-trimethylpentane (isooctane) + propan-2-ol (isopropyl alcohol), and 3-methyl-1-butanol + propan-2-ol, over the entire range of composition at 298.15 K. Excess molar volume, excess viscosity and the excess energy of activation for viscous flow were evaluated from the experimental data obtained. These derived properties for binary and ternary systems were fitted to Redlich-Kister's and Cibulka's equations, respectively. Flory's statistical theory has been applied to predict excess molar volumes for ternary system. For viscosities we applied Grunberg and Nissan, Katti and Chaudhri, Bloomfield and Dewan and Wu equations and finally the GC-UNIMOD model. © 2005 Elsevier B.V. All rights reserved.
Fil: Salas, J.A.. Universidad Nacional de Tucumán; Argentina
Fil: Pedrosa, G.C.. Universidad Nacional de Tucumán; Argentina
Fil: Acevedo, I.L.. Universidad Nacional de Tucumán; Argentina
Fil: Arancibia, Eleuterio Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina. Universidad Nacional de Tucumán; Argentina
Materia
DENSITIES
DYNAMIC VISCOSITY
EXCESS VOLUMES
TERNARY SYSTEMS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/99534

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spelling Excess molar volumes and excess viscosities of the 2,2,4-trimethylpentane (1) + 3-methyl-1-butanol (2) and propan-2-ol (3) ternary system at 298.15 KSalas, J.A.Pedrosa, G.C.Acevedo, I.L.Arancibia, Eleuterio LuisDENSITIESDYNAMIC VISCOSITYEXCESS VOLUMESTERNARY SYSTEMShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1This paper reports experimental densities and viscosities of the ternary system 2-2-4-trimethylpentane + 3-methyl-1-butanol + propan-2-ol and the binary systems 2-2-4-trimethylpentane (isooctane) + 3-methyl-1-butanol (isoamyl alcohol), 2-2-4-trimethylpentane (isooctane) + propan-2-ol (isopropyl alcohol), and 3-methyl-1-butanol + propan-2-ol, over the entire range of composition at 298.15 K. Excess molar volume, excess viscosity and the excess energy of activation for viscous flow were evaluated from the experimental data obtained. These derived properties for binary and ternary systems were fitted to Redlich-Kister's and Cibulka's equations, respectively. Flory's statistical theory has been applied to predict excess molar volumes for ternary system. For viscosities we applied Grunberg and Nissan, Katti and Chaudhri, Bloomfield and Dewan and Wu equations and finally the GC-UNIMOD model. © 2005 Elsevier B.V. All rights reserved.Fil: Salas, J.A.. Universidad Nacional de Tucumán; ArgentinaFil: Pedrosa, G.C.. Universidad Nacional de Tucumán; ArgentinaFil: Acevedo, I.L.. Universidad Nacional de Tucumán; ArgentinaFil: Arancibia, Eleuterio Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina. Universidad Nacional de Tucumán; ArgentinaElsevier Science2006-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/99534Salas, J.A.; Pedrosa, G.C.; Acevedo, I.L.; Arancibia, Eleuterio Luis; Excess molar volumes and excess viscosities of the 2,2,4-trimethylpentane (1) + 3-methyl-1-butanol (2) and propan-2-ol (3) ternary system at 298.15 K; Elsevier Science; Journal of Molecular Liquids; 124; 1-3; 2-2006; 37-440167-7322CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.molliq.2005.08.002info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0167732205001327?via%3Dihubinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T12:00:49Zoai:ri.conicet.gov.ar:11336/99534instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 12:00:50.03CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Excess molar volumes and excess viscosities of the 2,2,4-trimethylpentane (1) + 3-methyl-1-butanol (2) and propan-2-ol (3) ternary system at 298.15 K
title Excess molar volumes and excess viscosities of the 2,2,4-trimethylpentane (1) + 3-methyl-1-butanol (2) and propan-2-ol (3) ternary system at 298.15 K
spellingShingle Excess molar volumes and excess viscosities of the 2,2,4-trimethylpentane (1) + 3-methyl-1-butanol (2) and propan-2-ol (3) ternary system at 298.15 K
Salas, J.A.
DENSITIES
DYNAMIC VISCOSITY
EXCESS VOLUMES
TERNARY SYSTEMS
title_short Excess molar volumes and excess viscosities of the 2,2,4-trimethylpentane (1) + 3-methyl-1-butanol (2) and propan-2-ol (3) ternary system at 298.15 K
title_full Excess molar volumes and excess viscosities of the 2,2,4-trimethylpentane (1) + 3-methyl-1-butanol (2) and propan-2-ol (3) ternary system at 298.15 K
title_fullStr Excess molar volumes and excess viscosities of the 2,2,4-trimethylpentane (1) + 3-methyl-1-butanol (2) and propan-2-ol (3) ternary system at 298.15 K
title_full_unstemmed Excess molar volumes and excess viscosities of the 2,2,4-trimethylpentane (1) + 3-methyl-1-butanol (2) and propan-2-ol (3) ternary system at 298.15 K
title_sort Excess molar volumes and excess viscosities of the 2,2,4-trimethylpentane (1) + 3-methyl-1-butanol (2) and propan-2-ol (3) ternary system at 298.15 K
dc.creator.none.fl_str_mv Salas, J.A.
Pedrosa, G.C.
Acevedo, I.L.
Arancibia, Eleuterio Luis
author Salas, J.A.
author_facet Salas, J.A.
Pedrosa, G.C.
Acevedo, I.L.
Arancibia, Eleuterio Luis
author_role author
author2 Pedrosa, G.C.
Acevedo, I.L.
Arancibia, Eleuterio Luis
author2_role author
author
author
dc.subject.none.fl_str_mv DENSITIES
DYNAMIC VISCOSITY
EXCESS VOLUMES
TERNARY SYSTEMS
topic DENSITIES
DYNAMIC VISCOSITY
EXCESS VOLUMES
TERNARY SYSTEMS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv This paper reports experimental densities and viscosities of the ternary system 2-2-4-trimethylpentane + 3-methyl-1-butanol + propan-2-ol and the binary systems 2-2-4-trimethylpentane (isooctane) + 3-methyl-1-butanol (isoamyl alcohol), 2-2-4-trimethylpentane (isooctane) + propan-2-ol (isopropyl alcohol), and 3-methyl-1-butanol + propan-2-ol, over the entire range of composition at 298.15 K. Excess molar volume, excess viscosity and the excess energy of activation for viscous flow were evaluated from the experimental data obtained. These derived properties for binary and ternary systems were fitted to Redlich-Kister's and Cibulka's equations, respectively. Flory's statistical theory has been applied to predict excess molar volumes for ternary system. For viscosities we applied Grunberg and Nissan, Katti and Chaudhri, Bloomfield and Dewan and Wu equations and finally the GC-UNIMOD model. © 2005 Elsevier B.V. All rights reserved.
Fil: Salas, J.A.. Universidad Nacional de Tucumán; Argentina
Fil: Pedrosa, G.C.. Universidad Nacional de Tucumán; Argentina
Fil: Acevedo, I.L.. Universidad Nacional de Tucumán; Argentina
Fil: Arancibia, Eleuterio Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina. Universidad Nacional de Tucumán; Argentina
description This paper reports experimental densities and viscosities of the ternary system 2-2-4-trimethylpentane + 3-methyl-1-butanol + propan-2-ol and the binary systems 2-2-4-trimethylpentane (isooctane) + 3-methyl-1-butanol (isoamyl alcohol), 2-2-4-trimethylpentane (isooctane) + propan-2-ol (isopropyl alcohol), and 3-methyl-1-butanol + propan-2-ol, over the entire range of composition at 298.15 K. Excess molar volume, excess viscosity and the excess energy of activation for viscous flow were evaluated from the experimental data obtained. These derived properties for binary and ternary systems were fitted to Redlich-Kister's and Cibulka's equations, respectively. Flory's statistical theory has been applied to predict excess molar volumes for ternary system. For viscosities we applied Grunberg and Nissan, Katti and Chaudhri, Bloomfield and Dewan and Wu equations and finally the GC-UNIMOD model. © 2005 Elsevier B.V. All rights reserved.
publishDate 2006
dc.date.none.fl_str_mv 2006-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/99534
Salas, J.A.; Pedrosa, G.C.; Acevedo, I.L.; Arancibia, Eleuterio Luis; Excess molar volumes and excess viscosities of the 2,2,4-trimethylpentane (1) + 3-methyl-1-butanol (2) and propan-2-ol (3) ternary system at 298.15 K; Elsevier Science; Journal of Molecular Liquids; 124; 1-3; 2-2006; 37-44
0167-7322
CONICET Digital
CONICET
url http://hdl.handle.net/11336/99534
identifier_str_mv Salas, J.A.; Pedrosa, G.C.; Acevedo, I.L.; Arancibia, Eleuterio Luis; Excess molar volumes and excess viscosities of the 2,2,4-trimethylpentane (1) + 3-methyl-1-butanol (2) and propan-2-ol (3) ternary system at 298.15 K; Elsevier Science; Journal of Molecular Liquids; 124; 1-3; 2-2006; 37-44
0167-7322
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.molliq.2005.08.002
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0167732205001327?via%3Dihub
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
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instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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