Analysis of electron correlation effects and contributions of NMR J-couplings from occupied localized molecular orbitals
- Autores
- Zarycz, Maria Natalia Cristina; Aucar, Gustavo Adolfo
- Año de publicación
- 2012
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- NMR J-coupling calculations at the secondorder of polarization propagator approach, SOPPA, are among the most reliable. They include a high percentage of the total electron correlation effects in saturated and unsaturated molecular systems. Furthermore, J-couplings are quite sensitive to the whole electronic molecular framework. We present in this article the first study of all three response mechanisms, Fermi contact, FC, spin-dipolar, SD and paramagnetic spin−orbital, PSO, for J-couplings with occupied localized molecular orbitals at the SOPPA level of approach. Even though SOPPA results are not invariant under unitary transformations, the difference between results obtained with canonical and localized molecular orbitals, LMOs, are small enough to permit its application with confidence. The following small-size saturated and unsaturated compounds were analyzed: CH4, CH3F, C2H6, NH3, C2H4, CH2NH, H2CCHF, and FHCCHF. The local character of the FC mechanism that appears in J-couplings of these molecular models is shown through the analysis of contributions from LMOs. The importance of including the electron correlation on the engaged bonding orbitals for one-bond couplings is emphasized. Almost all electron correlation effects are included in such orbitals. Interesting findings were the large contributions by s-type LMOs to the C−H and C−C J-couplings; they are responsible for the variation of 1J(C−C) when going from ethane to ethene and to 1,2-difluoroethene. The previously proposed hyperconjugative transfer mechanism has been tested. Among other tests we found the difference anti-syn of one-bond 1J(C−H) in imine as due to both the corresponding σ(C−H) and the lone-pair, LP, contribution. Geminal and vicinal J-couplings were also analyzed. Our findings are in accord with a previous work by Pople and Bothner-by, who considered results taken from calculations or empirical data. For all geminal couplings the pattern of J-couplings, like the change of sign, is originated in the main bondings that participate in the coupling pathways. The finding of asymmetric contributions of LP to vicinal H−H couplings in imine is highlighted. The analysis of J-couplings by contributions from LMOs to the noncontact mechanisms, SD and PSO, show that the π electronic framework makes both terms grow in the specific case of the model compounds studied here. The PSO mechanism is more efficient when a σ bond is vicinal to a π bond. We found in this way an efficient and powerful scheme to get a deeper insight on the electronic molecular framework on which J-couplings are transmitted.
Fil: Zarycz, Maria Natalia Cristina. Universidad Nacional del Nordeste; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste; Argentina
Fil: Aucar, Gustavo Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Modelado e Innovación Tecnológica. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Modelado e Innovación Tecnológica; Argentina - Materia
-
NMR
POLARIZATION PROPAGATORS
LOC-SOPPA - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/149283
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Analysis of electron correlation effects and contributions of NMR J-couplings from occupied localized molecular orbitalsZarycz, Maria Natalia CristinaAucar, Gustavo AdolfoNMRPOLARIZATION PROPAGATORSLOC-SOPPAhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1NMR J-coupling calculations at the secondorder of polarization propagator approach, SOPPA, are among the most reliable. They include a high percentage of the total electron correlation effects in saturated and unsaturated molecular systems. Furthermore, J-couplings are quite sensitive to the whole electronic molecular framework. We present in this article the first study of all three response mechanisms, Fermi contact, FC, spin-dipolar, SD and paramagnetic spin−orbital, PSO, for J-couplings with occupied localized molecular orbitals at the SOPPA level of approach. Even though SOPPA results are not invariant under unitary transformations, the difference between results obtained with canonical and localized molecular orbitals, LMOs, are small enough to permit its application with confidence. The following small-size saturated and unsaturated compounds were analyzed: CH4, CH3F, C2H6, NH3, C2H4, CH2NH, H2CCHF, and FHCCHF. The local character of the FC mechanism that appears in J-couplings of these molecular models is shown through the analysis of contributions from LMOs. The importance of including the electron correlation on the engaged bonding orbitals for one-bond couplings is emphasized. Almost all electron correlation effects are included in such orbitals. Interesting findings were the large contributions by s-type LMOs to the C−H and C−C J-couplings; they are responsible for the variation of 1J(C−C) when going from ethane to ethene and to 1,2-difluoroethene. The previously proposed hyperconjugative transfer mechanism has been tested. Among other tests we found the difference anti-syn of one-bond 1J(C−H) in imine as due to both the corresponding σ(C−H) and the lone-pair, LP, contribution. Geminal and vicinal J-couplings were also analyzed. Our findings are in accord with a previous work by Pople and Bothner-by, who considered results taken from calculations or empirical data. For all geminal couplings the pattern of J-couplings, like the change of sign, is originated in the main bondings that participate in the coupling pathways. The finding of asymmetric contributions of LP to vicinal H−H couplings in imine is highlighted. The analysis of J-couplings by contributions from LMOs to the noncontact mechanisms, SD and PSO, show that the π electronic framework makes both terms grow in the specific case of the model compounds studied here. The PSO mechanism is more efficient when a σ bond is vicinal to a π bond. We found in this way an efficient and powerful scheme to get a deeper insight on the electronic molecular framework on which J-couplings are transmitted.Fil: Zarycz, Maria Natalia Cristina. Universidad Nacional del Nordeste; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste; ArgentinaFil: Aucar, Gustavo Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Modelado e Innovación Tecnológica. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Modelado e Innovación Tecnológica; ArgentinaAmerican Chemical Society2012-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/149283Zarycz, Maria Natalia Cristina; Aucar, Gustavo Adolfo; Analysis of electron correlation effects and contributions of NMR J-couplings from occupied localized molecular orbitals; American Chemical Society; Journal of Physical Chemistry A; 116; 4; 1-2012; 1272-12821089-5639CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/jp209850zinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:16:32Zoai:ri.conicet.gov.ar:11336/149283instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:16:32.738CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Analysis of electron correlation effects and contributions of NMR J-couplings from occupied localized molecular orbitals |
title |
Analysis of electron correlation effects and contributions of NMR J-couplings from occupied localized molecular orbitals |
spellingShingle |
Analysis of electron correlation effects and contributions of NMR J-couplings from occupied localized molecular orbitals Zarycz, Maria Natalia Cristina NMR POLARIZATION PROPAGATORS LOC-SOPPA |
title_short |
Analysis of electron correlation effects and contributions of NMR J-couplings from occupied localized molecular orbitals |
title_full |
Analysis of electron correlation effects and contributions of NMR J-couplings from occupied localized molecular orbitals |
title_fullStr |
Analysis of electron correlation effects and contributions of NMR J-couplings from occupied localized molecular orbitals |
title_full_unstemmed |
Analysis of electron correlation effects and contributions of NMR J-couplings from occupied localized molecular orbitals |
title_sort |
Analysis of electron correlation effects and contributions of NMR J-couplings from occupied localized molecular orbitals |
dc.creator.none.fl_str_mv |
Zarycz, Maria Natalia Cristina Aucar, Gustavo Adolfo |
author |
Zarycz, Maria Natalia Cristina |
author_facet |
Zarycz, Maria Natalia Cristina Aucar, Gustavo Adolfo |
author_role |
author |
author2 |
Aucar, Gustavo Adolfo |
author2_role |
author |
dc.subject.none.fl_str_mv |
NMR POLARIZATION PROPAGATORS LOC-SOPPA |
topic |
NMR POLARIZATION PROPAGATORS LOC-SOPPA |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.3 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
NMR J-coupling calculations at the secondorder of polarization propagator approach, SOPPA, are among the most reliable. They include a high percentage of the total electron correlation effects in saturated and unsaturated molecular systems. Furthermore, J-couplings are quite sensitive to the whole electronic molecular framework. We present in this article the first study of all three response mechanisms, Fermi contact, FC, spin-dipolar, SD and paramagnetic spin−orbital, PSO, for J-couplings with occupied localized molecular orbitals at the SOPPA level of approach. Even though SOPPA results are not invariant under unitary transformations, the difference between results obtained with canonical and localized molecular orbitals, LMOs, are small enough to permit its application with confidence. The following small-size saturated and unsaturated compounds were analyzed: CH4, CH3F, C2H6, NH3, C2H4, CH2NH, H2CCHF, and FHCCHF. The local character of the FC mechanism that appears in J-couplings of these molecular models is shown through the analysis of contributions from LMOs. The importance of including the electron correlation on the engaged bonding orbitals for one-bond couplings is emphasized. Almost all electron correlation effects are included in such orbitals. Interesting findings were the large contributions by s-type LMOs to the C−H and C−C J-couplings; they are responsible for the variation of 1J(C−C) when going from ethane to ethene and to 1,2-difluoroethene. The previously proposed hyperconjugative transfer mechanism has been tested. Among other tests we found the difference anti-syn of one-bond 1J(C−H) in imine as due to both the corresponding σ(C−H) and the lone-pair, LP, contribution. Geminal and vicinal J-couplings were also analyzed. Our findings are in accord with a previous work by Pople and Bothner-by, who considered results taken from calculations or empirical data. For all geminal couplings the pattern of J-couplings, like the change of sign, is originated in the main bondings that participate in the coupling pathways. The finding of asymmetric contributions of LP to vicinal H−H couplings in imine is highlighted. The analysis of J-couplings by contributions from LMOs to the noncontact mechanisms, SD and PSO, show that the π electronic framework makes both terms grow in the specific case of the model compounds studied here. The PSO mechanism is more efficient when a σ bond is vicinal to a π bond. We found in this way an efficient and powerful scheme to get a deeper insight on the electronic molecular framework on which J-couplings are transmitted. Fil: Zarycz, Maria Natalia Cristina. Universidad Nacional del Nordeste; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste; Argentina Fil: Aucar, Gustavo Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Modelado e Innovación Tecnológica. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Modelado e Innovación Tecnológica; Argentina |
description |
NMR J-coupling calculations at the secondorder of polarization propagator approach, SOPPA, are among the most reliable. They include a high percentage of the total electron correlation effects in saturated and unsaturated molecular systems. Furthermore, J-couplings are quite sensitive to the whole electronic molecular framework. We present in this article the first study of all three response mechanisms, Fermi contact, FC, spin-dipolar, SD and paramagnetic spin−orbital, PSO, for J-couplings with occupied localized molecular orbitals at the SOPPA level of approach. Even though SOPPA results are not invariant under unitary transformations, the difference between results obtained with canonical and localized molecular orbitals, LMOs, are small enough to permit its application with confidence. The following small-size saturated and unsaturated compounds were analyzed: CH4, CH3F, C2H6, NH3, C2H4, CH2NH, H2CCHF, and FHCCHF. The local character of the FC mechanism that appears in J-couplings of these molecular models is shown through the analysis of contributions from LMOs. The importance of including the electron correlation on the engaged bonding orbitals for one-bond couplings is emphasized. Almost all electron correlation effects are included in such orbitals. Interesting findings were the large contributions by s-type LMOs to the C−H and C−C J-couplings; they are responsible for the variation of 1J(C−C) when going from ethane to ethene and to 1,2-difluoroethene. The previously proposed hyperconjugative transfer mechanism has been tested. Among other tests we found the difference anti-syn of one-bond 1J(C−H) in imine as due to both the corresponding σ(C−H) and the lone-pair, LP, contribution. Geminal and vicinal J-couplings were also analyzed. Our findings are in accord with a previous work by Pople and Bothner-by, who considered results taken from calculations or empirical data. For all geminal couplings the pattern of J-couplings, like the change of sign, is originated in the main bondings that participate in the coupling pathways. The finding of asymmetric contributions of LP to vicinal H−H couplings in imine is highlighted. The analysis of J-couplings by contributions from LMOs to the noncontact mechanisms, SD and PSO, show that the π electronic framework makes both terms grow in the specific case of the model compounds studied here. The PSO mechanism is more efficient when a σ bond is vicinal to a π bond. We found in this way an efficient and powerful scheme to get a deeper insight on the electronic molecular framework on which J-couplings are transmitted. |
publishDate |
2012 |
dc.date.none.fl_str_mv |
2012-01 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/149283 Zarycz, Maria Natalia Cristina; Aucar, Gustavo Adolfo; Analysis of electron correlation effects and contributions of NMR J-couplings from occupied localized molecular orbitals; American Chemical Society; Journal of Physical Chemistry A; 116; 4; 1-2012; 1272-1282 1089-5639 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/149283 |
identifier_str_mv |
Zarycz, Maria Natalia Cristina; Aucar, Gustavo Adolfo; Analysis of electron correlation effects and contributions of NMR J-couplings from occupied localized molecular orbitals; American Chemical Society; Journal of Physical Chemistry A; 116; 4; 1-2012; 1272-1282 1089-5639 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1021/jp209850z |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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12.982451 |